Structure Of Water And Hydrogen Bonding Flashcards

1
Q

What is water made from

A

2 hydrogen and 1 oxygen

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2
Q

What is more electronegative in water?

A

Oxygen

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3
Q

What kind of bonds does water have?

A

Polar covalent between hydrogen and oxygen. Hydrogen bond between water molecules.

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4
Q

What is a polar covalent bond?

A

A chemical bond where a pair of electrons are unequally shared.

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5
Q

How much of the human body is made from water?

A

60-70%

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6
Q

What is key to the existence of life?

A

Water

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7
Q

What is the base of cytosol in a cell?

A

Cytosol is water based.

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8
Q

What are some of the properties of water?

A

Solvent
Cohesion and adhesion
High specific heat and vaporization
Low density when frozen
Polarity

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9
Q

What creates surface tension in water?

A

Hydrogen bonding. Cohesion of water molecules.

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10
Q

What are intermolecular forces?

A

Forces of attraction or repulsion between neighboring particles (atoms, molecules, or ions).

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11
Q

True or False: Intermolecular forces are generally weaker than intramolecular forces.

A

True

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12
Q

Name the four main types of intermolecular forces.

A

Dispersion forces, dipole-dipole forces, hydrogen bonds, and ion-dipole forces.

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13
Q

Fill in the blank: London dispersion forces are also known as __________ forces.

A

van der Waals

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14
Q

Which type of intermolecular force is the strongest?

A

Hydrogen bonds

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15
Q

What is the primary cause of dipole-dipole interactions?

A

The presence of permanent dipoles in polar molecules.

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16
Q

True or False: Hydrogen bonds can only occur between hydrogen and oxygen.

A

False

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17
Q

What type of molecules exhibit London dispersion forces?

A

All molecules, regardless of polarity.

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18
Q

Multiple Choice: Which of the following molecules would likely exhibit the strongest hydrogen bonding? A) H2O B) CH4 C) NH3 D) HF

A

A) H2O

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19
Q

What factors affect the strength of London dispersion forces?

A

Molecular size and shape.

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20
Q

Fill in the blank: Ion-dipole forces are particularly important in __________.

A

solutions of ionic compounds

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21
Q

True or False: The boiling point of a substance is influenced by the strength of its intermolecular forces.

A

True

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22
Q

What is the relationship between intermolecular forces and volatility?

A

Stronger intermolecular forces lead to lower volatility.

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23
Q

Define hydrogen bond.

A

A strong dipole-dipole interaction between a hydrogen atom bonded to a highly electronegative atom and another electronegative atom.

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24
Q

Multiple Choice: Which of the following is NOT a characteristic of dipole-dipole interactions? A) Occur in polar molecules B) Weaker than hydrogen bonds C) Stronger than London dispersion forces D) Occur in nonpolar molecules

A

D) Occur in nonpolar molecules

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25
What type of intermolecular force is present in nonpolar molecules?
London dispersion forces
26
True or False: Larger atoms generally have stronger London dispersion forces.
True
27
What is the effect of temperature on intermolecular forces?
Increasing temperature generally weakens intermolecular forces.
28
Name a property of water that is largely due to hydrogen bonding.
High surface tension
29
What determines the polarity of a molecule?
The difference in electronegativity between the atoms and the molecular geometry.
30
Multiple Choice: Which compound would have the highest boiling point? A) CH4 B) H2O C) C2H6 D) CO2
B) H2O
31
Fill in the blank: The strength of intermolecular forces is generally __________ related to the size of the molecule.
directly
32
What are dipole-induced dipole forces?
Forces that occur when a polar molecule induces a dipole in a nonpolar molecule.
33
True or False: All intermolecular forces are attractive.
False
34
What is the role of intermolecular forces in solubility?
Intermolecular forces determine whether substances can mix or dissolve in each other.
35
What is surface tension?
Surface tension is the property of a liquid's surface that allows it to resist an external force, due to the cohesive nature of its molecules.
36
True or False: Surface tension is only present in liquids.
True
37
What unit is surface tension commonly measured in?
Surface tension is commonly measured in dynes per centimeter (dyn/cm) or newtons per meter (N/m).
38
Fill in the blank: The molecules at the surface of a liquid experience _____ forces compared to those in the bulk of the liquid.
unequal
39
Which of the following liquids generally has the highest surface tension? (a) Water (b) Mercury (c) Oil
b) Mercury
40
What phenomenon allows small insects to walk on water?
Surface tension
41
True or False: Increasing temperature generally decreases surface tension.
True
42
What is the effect of surfactants on surface tension?
Surfactants lower surface tension.
43
What is the term for the curved surface of a liquid in a container?
Meniscus
44
Short answer: Name one application of surface tension in everyday life.
Soap bubbles or the ability of water to form droplets.
45
Fill in the blank: Surface tension is caused by the _____ forces between liquid molecules.
cohesive
46
What is the relationship between surface area and surface tension?
Surface tension acts to minimize the surface area of a liquid.
47
True or False: Surface tension can be observed in gases.
False
48
What is the significance of the Young-Laplace equation in relation to surface tension?
It describes the pressure difference across the interface of a curved liquid surface due to surface tension.
49
What does the term 'capillarity' refer to?
Capillarity refers to the ability of a liquid to flow in narrow spaces without the assistance of external forces, influenced by surface tension.
50
Short answer: How does surface tension affect the shape of liquid droplets?
Surface tension causes liquid droplets to form a spherical shape.
51
What is the critical surface tension?
The critical surface tension is the minimum surface tension at which a liquid can wet a solid surface.
52
True or False: Surface tension is a result of adhesive forces between different substances.
False
53
What role does surface tension play in the formation of bubbles?
Surface tension creates a skin around the bubble, maintaining its shape and structure.
54
Fill in the blank: The balance of cohesive and adhesive forces determines the _____ of a liquid.
wetting behavior
55
What is the relationship between molecular size and surface tension?
Generally, larger molecules can lead to higher surface tension due to increased cohesive forces.
56
Short answer: Describe one method to measure surface tension.
One method is the drop weight method, where the weight of a droplet is measured before it detaches.
57
What is the effect of impurities on surface tension?
Impurities can either increase or decrease surface tension depending on their nature.
58
True or False: Surface tension is a static property and does not change over time.
False
59
What is a common example of a surfactant?
Soap
60
Fill in the blank: Surface tension is crucial for the phenomenon of _____ in plants.
transpiration
61
_________ forces are responsible for surface tension.
Cohesion/cohesive
62
True or False Hydroxyl groups are polar
True
63
What are two things hydroxyl groups can do?
-turn molecules into alcohols -allow molecules to dissolve in water
64
What can carboxyl groups do?
Carboxyl groups can donate hydrogen ions, so they make molecules acidic.
65
What do amino functional groups do?
Amino groups can pick up hydrogen ions from the surroundings, so they make molecules basic.
66
What are 7 functional groups commonly attached to hydrocarbons?
-hydroxyl -carboxyl -amino -sulfhydryl -carbonyl -methyl -phosphate