STRUCTURE OF ATOM Flashcards

questions

1
Q

give any two characteristic properties of cathode rays.

A

(i) They are negatively charged particles.
(ii) They can produce x–rays

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2
Q

Write any two characteristic properties of canal rays (anode rays).

A

: (i) They are positively charged particles.
(ii) Their properties depend on the nature of gas present in the cathode ray tube.

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3
Q

What are the important observations and conclusions made by Rutherford in his α–
particle scattering experiment ?

A

: The important observations are:
i. Most of the α– particles passed through the gold foil without any deviation.
ii. A small fraction of the α–particles was deflected by small angles.
iii. A very few α– particles were rebounded (Or, deflected by nearly 180°).
Conclusions:
i. Since most of the α–particles passed through the foil without any deviation, most
space in the atom is empty.
ii. In an atom, there is a positively charged centre called nucleus.
iii. The volume of the nucleus is negligibly small as compared to the total volume of the
atom.

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4
Q

What are the postulates of Rutherford atom model (Planetary model of atom)?

A

The important postulates are:
i. All the positive charge and most of the mass of the atom are concentrated at the centre
called nucleus.
ii. Electrons are revolving round the nucleus with a very high speed in circular paths called
orbits.
iii. Electrons and the nucleus are held together by electrostatic forces of attraction.

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5
Q

What are the drawbacks of Rutherford atom model?

A

: (i) He could not explain the stability of the atom.
(ii) He could not explain the electronic structure of atom

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6
Q

What is photoelectric effect?

A

: It is the phenomenon of ejection of electrons by certain metals (like potassium,
rubidium, caesium etc.) when light of suitable frequency incident on them. The electrons
ejected are called photoelectrons.

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7
Q

What are the important characteristics of photoelectric effect? [Write the important
results observed during photoelectric effect].

A

The important characteristics of photoelectric effect are:
i. The electrons are ejected from the metal surface as soon as the beam of light strikes the
surface.
ii. The number of electrons ejected is proportional to the intensity or brightness of light.
iii. For each metal, there is a minimum frequency (known as threshold frequency [ν0])
below which photoelectric effect is not observed.
iv. The kinetic energy of the ejected electrons is directly proportional to the frequency of
the incident light.

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8
Q

Give the different series of lines present in the line spectrum of hydrogen atom.

A

: The hydrogen spectrum consists of mainly five series of lines which are Lyman,
Balmer, Paschen, Brackett and Pfund series.

Series Spectral region

Lyman Ultra violet
Balmer Visible
Paschen Infra red
Brackett Infra red
Pfund Infra red

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9
Q

The series of lines in hydrogen spectrum that is visible to our naked eye is …………

A

Balmer series

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10
Q

Give the important postulates of Bohr Atom model.

A

i. The electron in the hydrogen atom can move around the nucleus in a circular path of
fixed radius and energy. These paths are called orbits or stationary states or allowed
energy states.
ii. The energy of an electron in the orbit does not change with time.
iii. The frequency of radiation absorbed or emitted when transition occurs between two
stationary states that differ in energy by ΔE, is given by:
ν = ΔE/h = (E2 – E1)/h
iv.The angular momentum of an electron is an integral multiple of h/2π.

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11
Q

Write any 3 limitations of Bohr atom model?

A

: (i) It could not explain the fine spectrum of hydrogen atom.
(ii) It could not explain the spectrum of atoms other than hydrogen.
(iii) It could not explain Stark effect and Zeeman effect.

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12
Q

What do you mean by the dual nature of matter?

A

: Matter has two types of nature – particle nature and wave nature. This is known as the dual nature of matter.

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13
Q

. Give the de Broglies equation and explain the terms?

A

: de Broglies equation is λ = h/p
Or, λ = h/mv , Where
λ is the wavelength,
m is the mass,
v is the velocity
p is the momentum of the particle

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14
Q

What will be the wavelength of a ball of mass 0.1 kg moving with a velocity of 10 m/s ? (h =6.626 x 10–34 Js)

A

Here m = 0.1 kg and v = 10 m/s
From the de Broglie’s equation, λ = h
mv
= (6.626 x 10^–34)/(0.1 x 10) = 6.626 x 10^–34 m

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15
Q

State Heisenberg’s uncertainty principle. Give its mathematical form

A

It states that “it is impossible to determine simultaneously, the exact position and
exact momentum (or velocity) of an electron”.
Mathematically,
Δx. Δp ≥ h/4π
OR, Δx. mΔv ≥ h/4π
Where Δx is the uncertainty in position, Δp is the uncertainty in momentum, Δv is the
uncertainty in velocity and m is the mass of electron.

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16
Q

What are Quantum numbers? Explain the different quantum numbers.

A

These are certain numbers used to explain the size, shape and orientation of orbitals.
Or, Quantum numbers are the address of an electron.
There are four quantum numbers:
1. Principal Quantum Number (n): It gives the size the orbit, the energy of electron in an orbit, the shell in which the electron is found and the average distance between the electron and the nucleus.
The possible values of n are 1, 2, 3, 4, 5 etc.
2. Azimuthal Quantum Number (Ɩ): It gives the shape of the orbital, the sub shell in which the electron is found and the orbital angular momentum of the electron.
The possible values of Ɩ are: Ɩ = 0,1,2…(n–1).
3. Magnetic Quantum Number (m or mƖ): It gives the orientation of orbitals in space.
For a given ‘Ɩ’ value, there are 2Ɩ+1 possible values for m and these values are given by m = – Ɩ to 0 to + Ɩ
4. Spin Quantum Number (s or ms): It gives the spin of electrons. The values for s may be +½ or –½. +½ represents clock–wise spin and –½ represents anticlock–wise spin.

17
Q

Represent the orbital with the following quantum numbers:
(i) n = 4 and l = 0 (ii) n = 5, l = 3
(iii) n = 3, l =2

A

(i) 4s (ii) 5f (iii) 3d

18
Q

.Which of the following set of quantum numbers are not allowed?
(i) n = 3, l = 3, m = –3, s = +½
(ii) n = 2, l = 1, m = 0, s = –½
(iii) n = 1, l = 0, m = 0, s = +½
(iv) n = 0, l = 0, m = 0, s = +½

A

: Here (i) and (iv) are not allowed. (i) is not possible, since the value of l cannot be equal
to n. (iv) is not possible, because the values of n cannot be equal to zero.

19
Q

Draw the shapes of 1s and 2s orbitals.

A
20
Q

Draw the shapes of different p–orbitals.

A

There are 3 types of p–orbitals – px, py and pz. Each p–orbitals has a dumb–bell shape.

21
Q

There are 3 types of p–orbitals – px, py and pz. Each p–orbitals has a dumb–bell shape.

A
22
Q

Which are the different rules for filling electrons in orbitals? State them

A

The filling of electrons in different orbitals takes place according to the 3 rules – Aufbau
principle, Pauli’s exclusion principle and the Hund’s rule of maximum multiplicity.
1. Aufbau principle:
It states that the orbitals are filled in order of their increasing energies or (n + l) values.
2. Pauli’s Exclusion Principle
It states that no two electrons in an atom can have the same set of 4 quantum numbers. i.e.
an orbital can accommodate a maximum of only 2 electrons with opposite spin.
3. Hund’s rule of maximum multiplicity
It states that electron pairing takes place only after partially filling all the degenerate
orbitals.

23
Q

Write the number of radial nodes and angular nodes for 5f orbital.

A

Radial nodes = 1 [Equation for radial nodes = n – l – 1 = 5–3–1 = 1
Angular nodes = 3 [Equation for angular nodes = l]

24
Q

Write the subshell electronic configurations of Cu (Z = 29) and Cr (Z = 24). Give
reason for their extra stability.

A

29Cu: [Ar] 3d104s1
OR, 1s2 2s2 2p6 3s2 3p6 3d10 4s1
24Cr: [Ar] 3d54s1
OR, 1s2 2s2 2p6 3s2 3p6 3d5 4s1
Half–filled and completely filled electronic configurations have extra stability due to the symmetrical arrangement of electrons and greater exchange energy