structure and bonding-c3 Flashcards

1
Q

three states of matter(read bc idk how to make question)

A

Materials come in different forms-solid, liquid and gas. These are the three states of matter. Which state something is at a certain temperature depends on how strong the forces of attraction are between the particles of the material. How strong the forces are depends on three things:

  • the material
  • the temperature
  • the pressure
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2
Q

What does particle theory show?

A

You can use a model called particle theory to explain how the particles in a material behave in each of the three states of matter by considering each particle as a small, solid, inelastic shape.

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3
Q

Facts about solids?

A

-In solids, there are strong forces of attraction between particles, which holds them close together in fixed positions to form a very regular lattice arrangement.
The particles don’t move from their positions, so all solids keep a definite shape and volume and don’t flow like liquids.
-The particles vibrate about their positions- the hotter the solid becomes, the more they vibrate(causing solids to expand slightly when heated.

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4
Q

Facts about liquids?

A
  • In liquids there is a weak force of attraction between the particles. They’re randomly arranged and free to move past each other, but they tend to stick closely together.
  • Liquids have a definite volume but don’t keep a definite shape, and will flow to fill the bottom of the container.
  • The particles are constantly moving with random motion. The hotter the liquid gets, the faster they move. This causes liquids to expand slightly when heated.
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5
Q

Facts about gases?

A

In gases, the force of attraction between the particles is very weak-they’re free to move and are far apart. The particles in gases travel in straight lines.

  • Gases don’t keep a definite shape or volume and will always fill any container.
  • The particles move constantly with random motion. The hotter the gas gets, the faster they move. Gases either expand when heated or their pressure increases.
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6
Q

What are the limitations of the particle theory?

A

Particle theory is a great model for explaining the three states of matter, but it isn’t perfect. In reality, the particles aren’t solid or inelastic and they aren’t spheres- they’re atoms, ions or molecules. Also, the model doesn’t show the forces between the particles, so there’s no way of knowing how strong they are.

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7
Q

Explain the process of melting?

A

When a solid is heated, it’s particles gain more energy. This makes the particles vibrate more, which weakens the forces that hold the solid together. At a certain temperature, called the melting point, the particles have enough energy to break free from their positions. This is called melting and the solid turns into a liquid.

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8
Q

Explain the process of boiling?

A

When a liquid is heated, the particles gain a lot of energy. This makes the particles move faster which weakens breaks the bonds holding the liquid together. At a certain called the boiling point, the particles have enough energy to break their bonds. This is boiling(or evaporating). The liquid becomes a gas.

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9
Q

Explain the process of condensing?

A

As a gas cools, the particles no longer have enough energy to overcome the forces of attraction between them. Bonds form between the particles. At the boiling point, so many bonds have been formed between the gas molecules that the gas becomes a liquid. This is called condensing.

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10
Q

Explain the process of freezing?

A

When a liquid cools, the particles have less energy, so move around less. There is not enough energy to overcome the attraction between the particles, so more bonds form between them. At the melting point, so many bonds have formed between the particles that they are held in place. The liquid becomes a solid. This is freezing.

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11
Q

What does the amount of energy needed for a substance to change state depend on?

A

The amount of energy needed for a substance to change state depends on how strong the forces between the particles are. The stronger the forces, the more energy is needed to break them, and so the higher the melting and boiling points of the substance.

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12
Q

How to predict the state of a substance in a exam?

A

If the temperature is below the melting point of the substance, it will be a solid. If it is above the boiling point, it will be a gas. If it’s in between the two points, then it’s a liquid.

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13
Q

What are ions?

A

Ions are charged particles

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14
Q

How do ions form?

A

When atoms lose or gain electrons to form ions, all they are doing is trying to get a full outer shell like a noble gas. Atoms with full outer shells are very stable.

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15
Q

Do metals form positive ions?

A

Yes, when metals form ions, they lose electrons from their outer shell to form positive ions.

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16
Q

Do non metals form negative ions?

A

Yes, when non metals form ions, they gain electrons into their outer shell to form negative ions.

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17
Q

If 2 electrons are lost, what is the charge of the ion?

If 3 electrons are gained what is the charge of the ion?

A

2+

3-

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18
Q

Explain ionic bonding?

A

When a metal and non metal react together, the metal atom loses electrons to form a positively charged ion and the non metal gains these electrons to form a negatively charged ion.
These oppositely charged ions are strongly attracted to one another by electrostatic forces. This attraction is called an ionic bond.

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19
Q

What groups are most likely to form ions?

A

Groups 1,2,6 and 7

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20
Q

What ions do group 1 and 2 form?

A

Group 1 and 2 are metals and they form positive ions bc they lose electrons

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21
Q

What ions do group 6 and 7 form?

A

Group 6 and 7 are non metals, they form negative ions bc they gain electrons

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22
Q

What are dot and cross diagrams?

A

They show the arrangement of electrons in an atom or ion. Dot and cross diagrams are useful for showing how ionic compounds are formed, but they don’t show the structure of the compound, the size of the ions or how they are arranged.

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23
Q

What is an ionic compound?

A

An ionic compound is any compound that only contains ionic bonds.

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24
Q

What structure do ionic compounds have?

A

Ionic compounds have a structure called a giant ionic lattice. The ions form a closely packed regular lattice arrangement and there are very strong electrostatic forces of attraction between oppositely charged ions, in all directions in the lattice.

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25
Q

What are the advs and disadvs of a 3d model?

A

The model shows the relative sizes of the ions, as well as the regular pattern of an ionic crystal, but it only lets you see the outer layer of the compound.

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26
Q

What are the advs and disadvs of a ball and stick model?

A

It shows the regular pattern of an ionic crystal and shows how all the ions are arranged. It also suggests the crystal extends beyond what is shown in the diagram. The model isn’t to scale, so the relative sizes of the atom may not be shown. Also, in reality, there are no gaps between the ions.

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27
Q

Why do ionic compounds have high melting and boiling points?

A

They all have high melting points and high boiling points due to many strong bonds between the ions. It takes lots of energy to overcome this attraction.

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28
Q

What are some properties of ionic compounds?

A

When they are solid, the ions are held in place, so the compounds can’t conduct electricity. When ionic compounds melt, the ions are free to move and they will carry electric current.
Some ionic compounds also dissolve easily in water. The ions separate and are all free to move in the solution, so they’ll carry electric current.

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29
Q

What is covalent bonding?

A

This is where atoms share electrons with each other so that they have got full outer shells.

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30
Q

Explain covalent bonding?

A

When non metal atoms bond together, they share pairs of electrons to make covalent bonds. The positively charged nuclei of the bonded atoms are attracted to the shared pair of electrons by electrostatic forces, making covalent bonds very strong.

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31
Q

advs and disadvs of dot and cross diagrams for covalent bonds?

A

Dot and cross diagrams are useful for showing which atoms the electrons in a covalent bond come from, but they don’t show the relative sizes of the atoms, or how the atoms are arranged in space.

32
Q

advs and disadvs of displayed formula for covalent bonds?

A

This is a great way of showing how atoms are connected in large molecules. However they don’t show the 3d structure of the molecule, or which atoms the electrons in the covalent bond have come from.

33
Q

advs and isadvs for 3D model for covalent bonds?

A

can get confusing for large molecules where there are lots of atoms to include. They don’t show where the electrons in the bonds have come from

34
Q

Do covalent bonds have high or low melting/boiling point?

A

Low

35
Q

Why do covalent bonds have low melting/boiling points?

A

To melt or boil a simple molecular compound, you only need to break these feeble inter molecular forces and not the covalent bonds. So the melting/boiling points are low because the molecules are easily parted from each other.

36
Q

Why don’t covalent bonds conduct electricity?

A

Molecular compounds don’t conduct electricity because they are not charged, so there are no free electrons or ions.

37
Q

properties of covalent bonds?

A
  • The atoms within the molecules are held together by very strong covalent bonds. By contrast, the forces of attraction between these molecules are very weak.
  • Most molecular substances are gases or liquids at room temperature.
  • As molecules get bigger, the strength of the inter molecular forces increases, so more energy is needed to break them, and the melting and boiling points increase.
38
Q

What are polymers?

A

Polymers are long chains of repeating units. In a polymer, lots of small units are linked together to form a long molecule that has repeating sections. All the atoms in a polymer are joined by strong covalent bonds.

39
Q

Do polymers have high or low melting/boiling points?

A

The inter molecular forces between polymer molecules are larger than simple covalent molecules, so more energy is needed to break them. This means most polymers are solid at room temperature.
The inter molecular forces are still weaker than ionic or covalent bonds, so they generally have lower boiling points than ionic or giant molecular compounds.

40
Q

What are simple molecular substances?

A

Simple molecular substances are made up of molecules containing a few atoms joined together by covalent bonds.

41
Q

What are examples of some simple molecular substances?

A

Hydrogen, chlorine, oxygen nitrogen, hydrogen chloride, methane, water

42
Q

What are the properties of giant covalent structures?

A
  • In giant covalent structures, all the atoms are bonded to each other by strong covalent bonds
  • They have very high melting and boiling points as lots of energy is needed to break the covalent bonds between the atoms.
  • They don’t contain charged particles, so they don’t conduct electricity- not even when molten
  • The main examples are diamond and graphite, which are both made from carbon atoms only, and silicon dioxide.
43
Q

What is silicon dioxide?

A

Sometimes called silica, this is what sand is made of. Each grain of sand is one giant structure of silicon and oxygen.

44
Q

What are allotropes?

A

Allotropes are just different structural forms of the same element in the same physical state e.g they are all solids. Carbon has quite a few allotropes with lots of different properties.

45
Q

Why is diamond hard?

A

Diamond has a giant covalent structure, made up of carbon atoms that each form four covalent bonds. This makes diamond really hard.

46
Q

Does diamond have a high or low melting point?

A

High

47
Q

Why does diamond have a high melting point?

A

It has very strong covalent bonds that take a lot of energy to break so it has a very high melting point.

48
Q

Does diamond conduct electricity?

A

No

49
Q

Why does diamond not conduct electricity?

A

It doesn’t conduct electricity because it has no free electrons or ions.

50
Q

What is graphite?

A

An allotrope of carbon

51
Q

What is the structure of graphite?

A

In graphite, each carbon atom only forms three covalent bonds, creating sheets of carbon atoms arranged in hexagons.

52
Q

Why is graphite an ideal lubricating material?

A

There are not any covalent bonds between the layers- they are only held weakly, so they are free to move over each other. This makes graphite soft and slippery, so it is an ideal lubricating material.

53
Q

Does graphite have a high melting point and why?

A

Graphite’s got a high melting point- the covalent bonds in the layers need loads of energy to break.

54
Q

Does graphite conduct electricity?

A

Yes

55
Q

Why can graphite conduct electricity?

A

Only three out of each of carbon’s four outer electrons are used in bonds, so each carbon atom has one electron that delocalised(free) and can move. So graphite conducts electricity.

56
Q

What is graphene?

A

An allotrope of carbon

57
Q

What is the structure of graphene?

A

Graphene is a sheet of carbon atoms joined together in hexagons. The sheet is just one atom thick, making it a two dimensional compound.

58
Q

What are some properties and uses of graphene?

A

The network of covalent bonds makes it very strong. It is also incredibly light, so it can be added to composite materials to improve their strength without adding too much weight.

59
Q

Does graphene conduct electricity and why?

A

Like graphite, it contains delocalised electrons so can conduct electricity through the whole structure. This means it has the potential to be used in electronics.

60
Q

What are fullerenes?

A

Fullerenes are molecules of carbon, shaped like closed tubes or hollow balls.
They are mainly made up of carbon atoms arranged in hexagons, but can also contain pentagons or heptagons.

61
Q

What is buckministerfullerene?

A

It was the first fullerene to be discovered. It’s got the molecular formula C60 and forms a hollow sphere containing 20 hexagons and 12 pentagons.

62
Q

What are the uses of fullerenes?

A
  • Fullerenes can be used to cage other molecules. The fullerenes structure forms around another atom or molecule, which is then trapped inside. This could be sued to deliver a drug into the body.
  • Fullerenes have a huge surface area, so they could help make great industrial catalysts- individual catalysts molecules could be attached to the fullerens.
  • Fullerenes also make great lubricants
  • They can be used in nanotechnology
63
Q

How can fullerenes be used in nanotechnology?

A
  • Fullerenes can form nanotubes- tiny carbon cylinders
  • The ratio between the length and the diameter of nanotubes is very high
  • Nanotubes can conduct both electricity and thermal energy
  • They also have a high tensile strength(they don’t break when stretched)
  • Technology that uses very small particles such as nanotubes is called nanotechnology. Nanotubes can be used in electronics or to strengthen materials without adding too much weight such as in tennis racket frames.
64
Q

What is metallic bonding?

A

-Metals also consist of a giant structure
-The electrons in the outer shell of the metal atoms are delocalised(free to move around). There are strong forces of electrostatic attraction between the positive metal ions and the shared negative electrons.
-The forces of attraction hold the atoms together ina regular structure and are known as metallic bonding. Metallic bonding is very strong.
Substances that are held together by metallic bonding include metallic elements and alloys.
Its the delocalised electrons in the metallic bonds which produce all the properties of metals.

65
Q

Do compounds with metallic bonding have high or low melting/boiling points?

A

High

66
Q

Why do compounds with metallic bonding have high melting and boiling points?

A

The electrostatic forces between the metal atoms and the delocalised sea of electrons are very strong, so need lots of energy to be broken. So they have high melting/boiling points.

67
Q

Why are compounds with metallic bonding generally solid at room temperature?

A

bc they have high melting/boiling points due to the strong electrostatic forces.

68
Q

Why are metals good conductors of heat and electricity?

A

The delocalsied electrons carry electrical current and thermal energy through the whole structure, so metals are good conductors of electricity and heat.

69
Q

Are most metals malleable?

A

Yes, the layers of the atoms in a metal can slide over each other, making metals malleable- this means that they can be bent or hammered or rolled into flat sheets.

70
Q

What are alloys?

A

Most of the metals we use everyday are alloys.
An alloy is a mixture of two or more metals or a metal and another element. Alloys are harder, so more useful than pure metals.

71
Q

Why are pure metals usually not used in many things?

A

Pure metals are often not right for certain jobs- they are often too soft when they are pure so they are mixed with other elements to make them harder.

72
Q

Why are alloys harder than pure metals?

A

Different elements have different sized atoms. So when another element is mixed with a pure metal, the new metal atoms will distort the layers of the metal atoms, making it more difficult for them to slide over each other. This makes alloys harder than pure metals.

73
Q

What are the 3 categories of particles?

A

Coarse particles
Fine particles
Nano particles

74
Q

info about nanoparticles and bulk(you are doing great, you got this!!)

A

Nanoparticles have a high surface area to volume ratio- this means that the surface area is very large compared to the volume.
This causes the properties of a material to be different depending on whether it’s in bulk. For example you will often need less of a material that’s made of nanoparticles to work as an effective catalyst compared to a material made up of normal sized particles.

75
Q

What are the uses of nano particles?

A
  • They have a huge surface area to volume ratio, so they could help make new catalysts.
  • Nanomedicine. The idea is that tiny particles(like fullerenes) are absorbed more easily by the body than most particles. This means they can deliver drugs right into the cells where it is needed.
  • Some nanoparticles conduct electricty, so they can be used in tiny electric circuits for computer chips.
  • Silver nanoparticles have antibacterial propeties. They can be added to polymer fibres that are then used to make surgical masks and wound dressings and they can also be added to deodrants.
  • Nanoparticles are also being used in cosmetics. For example, they’re used to improve moisturizes without making them really oily.
76
Q

What are the problems with nanoparticles?

A
  • Although nanoparticles are useful, the way they effect the body isn’t fully understood, so it is important that any new products are tested thoroughly to mimimise the risks.
  • Some people are worried that products containing nanoparticles have been made available before the effects on human health have been investigated properly, and that we don’t know what the long term impacts on health will be.
  • As the long term impacts are not known, many people believe that products containing nanoscale particles should be clearly labelled, so consumers can choose whether or not to use them.
  • Nanoparticles are being used in sun creams as they have shown to be better than the material in the traditional sun cream at protecting skin from harmful UV rays. They also give better skin coverage.
  • But it is not yet clear whether the nanoparticles can get into your body, and, if they do, whether they might damage cells.
  • It is also possible that when they are washed away, they might damage the environment.