Structure and Bonding Flashcards
In a periodic table, what is a:
- Group?
- Period?
- A column
2. A row
What are the three main components of an atom?
- Protons
- Neutrons
- Electrons
What is in the nucleus of an atom?
- Protons
2. Neutrons
What is the formula for the maximum number of electrons that can occupy an atom’s nth shell?
Electron capacity = 2n²
What does the group number of an atom tell you?
The number of electrons in the outer shell
What does the period number of an atom tell you?
The number of shells the atom has
Why do groups have similar properties?
They have the same number of electrons in the outer shell
Why are noble gases inert?
They have stable electronic arrangements i.e. they have 8 atoms in their outer shell
How can atoms of elements other than noble gases achieve stable electronic structures?
- Gaining or losing electrons to form ions
2. Sharing electrons to form covalent bonds
How does ionic bonding work?
Electrons transfer from metal to non-metal, forming two oppositely charged ions. The ions are held together by strong electrostatic forces
How does electron transfer affect the electronic structure of an ion?
The ion has a complete highest energy level, so the electronic structure of an ion is the same as that of a noble gas
What are the four steps of ion formation?
- Electron transfer
- Formation of ions
- Electrostatic attraction
- Formation of lattice
How is an ionic lattice formed?
- Oppositely charged ions attract each other
- Each ion attracts oppositely charged ions from all directions
- Each of these ions attract more ions in turn
- A giant ionic structure made up of millions of ions is formed, making a crystal
Ionic bond
A strong electrostatic attraction between two oppositely charged ions. Ionic bonds always produce giant ionic structures, and occur only between metals and non-metals
Ionic compounds:
- Melting and boiling points
- Conductivity as solid
- Conductivity when melted
- Solubility in water
- Conductivity of solution
- Type of substances
- High
- Do not conduct
- Conducts
- Soluble (usually)
- Conducts
- Metal and non-metal
How do different charges affect the strength of the ionic bond?
The bigger the charges, the stronger the bonds. This is because there is a stronger electrostatic attraction between the ions
Covalent bond
A chemical bond that involves the sharing of pairs of electrons between atoms. Occurs mainly between non-metal elements
Giant covalent macromolecules
Giant lattices of covalent bonds
Examples of giant covalent compounds
- Diamond
2. Graphite
Giant covalent compounds:
- Melting and boiling points
- Conductivity as solid
- Conductivity when melted
- Solubility in water
- Conductivity of solution
- Type of substances
- Very high
- Do not conduct (except for graphite)
- Do not conduct
- Insoluble
- Insoluble
- Non-metal
Why do giant covalent compounds have such high melting points?
The covalent bonds between the atoms are very strong, and there are many of them. This means that a lot of energy is needed to separate them
Arrangement of atoms in graphite
- Three covalent bonds to each carbon atom
- Weak intermolecular forces between layers
- Covalent lattice - lots of strong covalent bonds
- Why do layers of graphite slide over each other?
2. What is graphite used in as a result of this property?
- The weak forces between the layers of graphite make them slippery
- Lubricant and pencil lead
- Why does graphite conduct electricity?
2. What is graphite used in as a result of this property?
- As each carbon atom is only bonded to three others, graphite contains delocalised electrons. These can carry charge
- Electrodes
Arrangement of atoms in diamonds
- Four covalent bonds to each carbon atom
- Lots of strong covalent bonds
- Atoms arranged in a tetrahedral arrangement
- Why doesn’t diamond conduct electricity?
2. What are diamonds used in as a result of this property?
- Each carbon atom is bonded to four others, so there are no delocalised electrons to carry charge
- Insulating material
- Why is diamond one of the hardest materials known?
2. What are diamonds used in as a result of this property?
- Its arrangement means that it has a lot of strong covalent bonds
- Cutting tools and drills
What are graphite and diamond used in due to their high melting points?
Graphite: crucibles to hold molten metal
Diamond: jewellery
Simple molecular substances
Molecules in which the atoms are joined by covalent bonds, but the molecules themselves have much weaker intermolecular forces between them
Simple molecular substances:
- Melting and boiling points
- Conductivity as solid
- Conductivity when melted
- Solubility in water
- Conductivity of solution
- Type of substances
- Low
- Do not conduct
- Do not conduct
- Insoluble (usually)
- Insoluble (usually)
- Non-metal
What state of matter do simple molecular substances tend to be?
Gases, liquids or solids with low boiling points
What happens when simple molecular substances are heated?
The weak intermolecular forces are overcome - no covalent bonds are broken!
Why don’t simple molecular substances conduct electricity?
- No delocalised electrons
2. No overall charge
Differences between ionic and covalent bonds
- No electron transfer in covalent bonding
- The same type of atom can be held together by covalent bonds
- No charges involved in covalent compounds
- Covalent bonds are usually between two non-metals, while ionic bonds are between metals and non-metals
Metallic bond
The strong force of attraction between closely packed positive metal ions and a ‘sea’ of delocalised electrons
Metallic bonds:
- Melting and boiling points
- Conductivity as solid
- Conductivity when melted
- Solubility in water
- Conductivity of solution
- Type of substances
- High
- Conducts
- Conducts
- Insoluble
- Insoluble
- Metal
Properties of metallic bonding
- High melting and boiling points
- Conduct electricity
- Malleable: easy to bend into shape
- Ductile: can be constructed into wires
Why do metals have high melting points?
There are strong electrostatic forces between the positive ions and negative electrons
Why do metals conduct electricity?
Delocalised electrons are free to move and pass charges
Why are metals malleable and ductile?
The layers of atoms are able to move over each other, allowing them to be bent or shaped
Oxidation
Loss of electrons
Reduction
Gain of electrons
Metal
A giant structure of positive ions surrounded by a sea of delocalised electrons