Structure and Bonding Flashcards

1
Q

What is ionic bonding?

A

Transfer of electrons from metallic and non-metallic

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2
Q

What is a cation and anion

A

Cation = lose e-, positively charged ion
Anion = gain e-, negatively charged ion

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3
Q

What type of force does an ionic bond have

A

Electrostatic attractions between oppositely charged ions forming ionic compounds

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4
Q

What do the strong electrostatic forces between ions mean

A

Lots of energy
High melting and boiling points

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5
Q

Electrical conductivity of ionic compounds

A

Molten or dissolved
Ions free to move

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6
Q

Solubility ionic bonding

A

Dissolve in water, water molecules are polar so pull ions away from lattice so it dissolves

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7
Q

Giant ionic lattices structure

A

Arranged in regular repeating pattern so positive charged cancel out negative charges
Overall electrically neutral

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8
Q

Covalent bond electrons

A

Sharing between a pair of electrons between two non-metals

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9
Q

Forces in covalent bonding

A

Electrostatic attraction between nuclei of two atoms and bonding electrons of outer shells

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10
Q

Type of bonds in covalent bonding

A

Single - both molecules overlap in dot and cross diagram
Double = O=C=O
Triple = N=-N

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11
Q

Forces in simple covalent bonding of molecule

A

Van der waals
Strong covalent bonds and intermolecular forces

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12
Q

Giant covalent Graphite

A

Weak bonds easily broken so slide over each other, delocalised electrons for electrical conductivity, low density because layers are far apart, soluble

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13
Q

Giant covalent diamond

A

High melting point, hard, vibrations travel easily so good thermal conductor, cant conduct electricity, wont dissolve in solvent

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14
Q

Why does HCl conduct electricity

A

HCl is an acid so it dissociates into H+ and Cl- which are ions, so can carry charge

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15
Q

What is a dipole

A

Unequal distribution of electronegativity between two atoms
(one partially positive other partially negative)

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16
Q

What’s a dipole moment

A

Looking at whole molecule not just two atoms within molecule

17
Q

What if a molecule is symmetrical

A

Dipoles cancel out and there is no overall dipole moment

18
Q

How to draw dipole

A

arrow with line in it
-/->

19
Q

What is a co-ordinate bond

A

Both electrons shared come from same atom

20
Q

Example of dative bond

A

NH4

21
Q

What’s a lone pair

A

unshared electron pair

22
Q

Why do lone pairs repulse the most

A

more concentrated electron cloud than other bonding pairs of electrons
Cloud charges are wider and closer to central atom’s nucleus

23
Q

Order of repulsion

A

lone pair to lone pair > lone pair to bind pair > bond pair to bond pair

24
Q

What molecules are van der waal forces in

A

all molecules

25
Q

How do van der waals forces act

A

Electron charge cloud in non-polar molecules constantly moving. Electron cloud can be more one side of the atom than the other, causing a temporary dipole which induces neighbouring molecules. This causes one atom to be partially positive and the neighbouring molecules atom partially negative, attracting them. Clouds constantly moving so only temporary dipole.

26
Q
A