Structural Fire Fighting Flashcards
Fire Dynamics
Energy is the capacity to perform work in the case of heat work means increasing a substance temperature
Kinetic energy
When heat is introduced to an object the molecules within the fuel begin to vibrate as the heat thermal energy increases these molecules vibrate more and more rapidly the fuse kinetic energy is the result of these vibrations in the molecules
Energy
Is measured in joules the unit of measurement for heat is the British thermal unit BTU a British thermal unit is the amount of heat required to raise the temperature of 1 pound of water by 1 degree Fahrenheit
Exothermic reactions
Reactions that emit energy as they occur
Endothermic reactions
Reactions that absorb energy as they occur
Fire triangle and tetrahedron
Fire triangle is oxygen fuel Heat
Fire tetrahedron is reducing agent fuel, oxidizing agent, Heat, chemical chain reaction
Ignition
Fuels must be in a gaseous state to burn there for solids and liquids must become gaseous in order for ignition to occur
Piloted ignition
Most common form of ignition and occurs when a mixture of fuel and oxygen encounter in external heat source with sufficient heat or thermal energy to start the combustion reaction
Auto ignition
Occurs without any external Flame or spark to ignite the fuel gases or Vapors
Auto ignition temperature
Is the minimum temperature at which a fuel in the air must be heated in order to start self sustain combustion the auto ignition temperature of a substance is always higher than its piloted ignition temperature
Products of combustion
Describe this heat and smoke while the heat from a fire is a danger to anyone directly exposed to it supposed to toxic gases found in Smoke and or lack of oxygen cause most fire Death smoke is an aerosol comprised of gases vapor in solid particles
Carbon monoxide
Is toxic flammable product of incomplete combustion of organic carbon containing material it’s colorless odorless gas present in almost every fire it is released when an organic material Burns in an atmosphere with limited supply of oxygen
Co combines with hemoglobin about 200 times more effectively than oxygen
Hydrogen cyanide
Toxic and flammable substance produced in the combustion of materials containing nitrogen also found in Smoke
The following materials produced hcn these materials are found in upholstered furniture, bedding, insulation, carpet, clothing
Hcn is 35 times more toxic than Co hcn is significant by product of the combustion of polyurethane foam used in many household furnishings
Carbon dioxide
Is is a product of complete combustion of organic materials it’s not toxic in the manner of Co + hcn but it displaces existing oxygen which creates an oxygen deficient atmosphere
Chemical energy
Chemical energy is the most common source of heat in combustion reactions
Mechanical energy
Friction or compression generates mechanical energy the movement of two surfaces against each other heat of friction that generates heat and or Sparks heat is generated when a gas is compressed
Radiation
Radiation is the transmission of energy as electromagnetic waves such as light waves radio waves or x-rays without an intervening medium
Radiant heat transfer primarily depends on the temperature of the heat source
Fuel known as the reducing agent
Most common fuels are organic containing carbon and other elements organic fuels can be divided into hydrocarbon best fuel such as gasoline fuel oil plastic cellulose-based materials wood in paper
Power
Is the rate at which energy transfers power is the heat release rate during combustion
Heat release rate
Is the energy released per unit of time as fuel Burns and is usually expressed in kilowatts heat release rate depends on the type quantity in orientation of the fuel
Gases
Gaseous fuels such as methane natural gas hydrogen and acetylene can be the most dangerous of all fuel types because they are already in the physical state required for ignition
Characteristics of common flammable gases
Methane natural gas ignition temperature 1004 degrees Fahrenheit
Propane 842 degrees Fahrenheit
Carbon monoxide 1128 degrees Fahrenheit
Flashpoint
Is the minimum temperature at which a liquid gives off sufficient Vapors to ignite but not sustain combustion in the presence of a piloted ignition source
Firepoint
Is the temperature at which a pilot ignition of sufficient Vapors will begin is sustain combustion reaction Flashpoint is commonly used to indicate the flammability Hazard of liquid fuels
Oxygen
Normally air consists of about 21% oxygen that energy release in fire is directly proportional to the amount of oxygen available for combustion
At normal ambient temperatures 68° Fahrenheit materials can ignite and burn at oxygen concentrations as low as 15%
Oxygen concentrations
Atmosphere having less than 19.5% oxygen is considered oxygen-deficient
In the atmosphere exceeds 23.5% that mysterious consider oxygen-rich represents an increase fire risk
Compartment fire development
All compartment fires begin in the incipient Stage is fuel limited fires once the fire reaches the growth stage the fire will either remain fuel limited if there is enough oxygen to support continued growth or the fire will consume all available oxygen and become ventilation Limited
Incipient stage
Test answer the High Castle is in the plume rise until they encountered the ceiling and then began to spread horizontally this flow of fire gases is called the ceiling jet
Incipient stage transition
A visual indicator that he fire is leave in the incipient stage is flame height when flames reached 2.5’ high radiated heat begins to transfer more heat then convection the fire will then entered the growth stage
Combustion Zone
Therefore when the fuel package is not in the middle of the room the combustion Zone the area where sufficient are is available to feed the fire expand vertically Andy higher plume results a higher Plumb increases the temperatures in the developing Hot Gas layer at ceiling level in increases the speed of fire development
Isolated flames
May move through the hot gas layer combustion of hot gases in the case that portions of the hot gas layer are within their flammable range and there is significant heat to cause ignition
The appearance of isolated flame is sometimes an immediate indicator of flashover
Rapid fire development
Refers to the rapid transition from the growth stage or early Decay stage to a ventilation limited fully develop stage among these events are flash over and Backdraft
Flashover rapid transition from the growth stage to the fully developed stage is known as flash over
FLASHOVER OCCURS DURING GROWTH STAGE
TEMP OVER 1100 DEGREES F
Significant indicator of flashover is ROLLOVER- where unburned fire gases that I have accumulated at the top of the compartment ignite and Flames propagate through the hot gas layer or across the ceiling
CO
The auto ignition temperature of CEO the most abundant fuel gas created in most fires is approximately 1100 degrees Fahrenheit