Stoich Flashcards

1
Q

What are the steps in determination of limiting reactants or reagents

A
  1. Write a blanced chemical equation
  2. Caclulate the amount(moles) of both reactants
    3.Using mole ratio, identify the limiting reagent reactant
  3. Use the amount ( moles) of the limiting reagent and the mole ratio to determine the amount (moles) of the product
  4. Conver the amount (moles) of the product back to the desired units
  5. Check sig figs.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is formula for volume not in slc

A

V= nRT/p

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is Specific heat capacity

A

Specific heat capacity of a substance is the amount of energy needed to raise the temperature of 1g of the substance by 1°C

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What units is SPECIFIC Heat capacity in?

A

J g-1 °C-1 or J g-1 °K-1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Why does water have a high specific heat capacity than oil

A

Because the hydrogen bonds between water moldecules are STRONGER than the dispersion forces between oil molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Ways to reduce heat loss during calorimetry experiments

A

1.Putting a lid on the calorimeter
2.Insulating the beaker of water with flameproof material
3.Placing insulation around burning food, but maintaining sufficient oxygen supply for burning the food
4.Reduce the distance of the flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What type of error would the factor of heat loss from calorimetry be

A

Systematic error as it affects accuracy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what is the formula for energy released per gram

A

qtotal= m x energy per gram

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what is the energy released in combustion per mole

A

q total = n x AH (heat of combuhhh)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is a calorimeter

A

A thermal insulated containter that tries to minimise the heatloss

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Almost all heat transfers are to or from the measured volume of water

true or false

A

true

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What are the main steps of calorimetry

A
  1. Calibration
  2. Experiment
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is the calibration of calorimeter

A

Hoe much energy is required to raise the tempreature of the whole system(as all parts of the system will absorb energy) by 1*C for THAT calorimeter used in the experiment

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is the eq for CF

and its units

A

CF= E(cal)/ delta T(cal)

E is the amount of energy to the CM during calib

The units for CF- JC-1 or kJC-1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Whats in a solution calorimetry

A

Thermometer
Mechanical or noram stirrer
Electic heater for calibrating the calorimeter
Insulated container
Glass bulb contating second reactant
Solution of one reactant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is the point of the stirrer in calorimetry

A

Uniform distrubtion of heat and allows for reactants to mix evenly

17
Q

if i put 100j of energy into the calorimeter and the change in tempreature is 5 degress. whats the CF

A

20j/c

meaning for every 1 degree, 20 j of energy is required

18
Q

What are the two main ways of calibrating a calorimeter

A

1.Electrical calibration
2.Chemical calibration

19
Q

what cant the solution calorimeter measure?

A

energy of content of food or a fuel as the reaction is combustion and requires to burn in oxygen.

20
Q

What is the solution calorimeter used for

A

Ussed to measure enthalpy changes in chemical reactions such as dissolving or acid-base reactions while minimsing heat loss

21
Q

Why is calibration of a calorimeter required?

A

So that the data supplied is more accurate and the heat loss is minimised

22
Q

What is electircal calibration

A

Supplying a measured amount of electircal energy to the calorimeter system to increase the thermal energy and asssuming that all of the energy is converted to heat energy

23
Q

What is the electircal calibration energy formula ( include units)

A

Energy (Joules) = voltage (volts) × current(amperes) × time(seconds)

E = V × I × t

24
Q

Why after the calorimeter heater is turnt off or even during the tempreature may drop?

A

As there is heat loss occuring due to the calorimeter not being properly insulated.

25
How can we check the accuracy and see if the calorimeter is well insulated or not
Tempreture-time graph
26
due to constant heat loss, the most accurate way is to record the temp change thru a temp time graph, what do u do then
Extrapolate backwords to find the change in tempreature up to the moment where the current was turned on
27
What is chemical calibration
Reacting **known amounts** of substance in a reaction for which delta H is accurately known.
28
whats eq for chemical calibration energy
E= detla H x n | then put it into cf= e/deta t
29
What are the full steps of the whole application of calibration facotr calorimeter to find enthalpy. | include equations
1. **Find energy(chemical/electrical)** (E = Vit or E= AH x n) 1. **Find the CF** ( CF= E/AT) 3. **Use calibration factor** (E *exp* = CF x AT exp) 4. **Find the change in enthalpy** ( AH= q/m or q/n depends)
30
When energy transformations occur, the total amount of energy is unchanged because....... however not all energy is converted....
energy cannot be created or destroyed .However, not all of the energy is converted to one specific form
31
what is the energy efficeny equation
(usefull energy/energy input) X 100
32
what two things to the body provide no energy value
Water and cellulose ( fibre)
33