Stereoisomers Flashcards

1
Q

Cis

A

Compounds around double bond that are the same and on same side

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Trans

A

Compounds around Double bond with that are the same but on opposite sides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Chiral molecules

A

Compound contains at least one chiral center

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Achiral

A

2 mirror images forms are superimpossible

Has a plane of symmetry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Chiral center

A

Carbon with 4 different atoms or compounds attached to it (asymmetric center)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Enantiomers

A

Differ at all chiral centers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Cahn ingold prelog rules

A
  1. Rank substituents at chirality Centers according to atomic number
  2. Orient molecule so lowest ranked substituent points away from u
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

R

A

Clockwise order of ranking

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

S

A

Counterclockwise order of ranking

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Two groups have same atom when figuring out absolute configuration

A

Move out to another bond attached to it and compare atomic numbers of those numbers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

How many stereoisomers

A

2^n

n= chiral centers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Diastereoisomers

A

Differ to at least 1 or more chiral centers but not all (must have at least 2 chiral centers)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Meso

A

Have a plane of symmetry and could or couldn’t have chiral centers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Racemic mixtures

A

Containing equal amounts of Enantiomers which is optically inactive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Optically active

A

Not meso and not racemic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly