Stereoisomerism Flashcards

1
Q

Stereoisomerism

A

Have the same structural formula but a different arrangement of atoms in space

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2
Q

Why E/Z isomerism occurs in alkenes

A

No rotation around the C=C double bond

Thus, have to have diff arrangement for isomerism

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3
Q

E/Z isomerism

A

stereoisomerism around the double bond arises as rotation about double bond is restricted
groups attached to each C is fixed relative to each other

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4
Q

Conditions for E/Z isomerism

A

=> a C=C double

=> Diff group attached to each carbon atom of the double atom

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5
Q

Cis - Trans (a type of E/Z isomerism) Isomerism

A

=> a C=C double bond
=> Diff. groups attached to each C atom of the double bond
=> Each C in double bond has a H bonded to it

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6
Q

Z isomerism

A

If the group of higher priority are on the same side of double bond

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7
Q

E isomerism

A

If groups of higher priority are diagonal

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8
Q

E

A

Entengen = Opposite

REMEMBER Epposite

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9
Q

Z

A

Zusamen = Same side

REMEMBER Zame Zide

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10
Q

Assigning Priority

A

The higher the atomic (proton) number of what’s bonded to the double bonded C
=> the higher the priority

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