Standard enthalpy change of formation and Hess's Law Flashcards
what is the standard enthalpy change of formation?
the enthalpy change measured at 100kPa and a specific temperature, usually 298K, when one mole of a substance is formed from its elements in their standard states.
what is Hess’ Law
Hess’s Law states that the enthalpy change of a reaction is independent of the path taken in converting reactants into products, provided the initial and final conditions are identical.
the standard state of an element is the form in which it exists at the
specified temperature, usually 298K and a pressure of 100kPa
the equation which shows the standard enthalpy change of formation of gaseous carbon dioxide is
C(s, graphite) + O2(g) = CO2(g)
the equation which shows the standard enthalpy change for the formation of liquid ethanol is
2C(s, graphite) + 3H2(g) + 1/2 O2(g) = C2H5OH(l)
most standard enthalpy changes of formation are
impossible to determine experimentally
in general terms, the enthalpy cycle which is used to calculate enthalpy change of formation of a compound from the relevant enthalpy changes of combustion is:
ΔfH
component elements → compound
→ →
sum of ΔcH of elements sum of ΔcH of compound
combustion products