Standard enthalpy change of formation and Hess's Law Flashcards

1
Q

what is the standard enthalpy change of formation?

A

the enthalpy change measured at 100kPa and a specific temperature, usually 298K, when one mole of a substance is formed from its elements in their standard states.

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2
Q

what is Hess’ Law

A

Hess’s Law states that the enthalpy change of a reaction is independent of the path taken in converting reactants into products, provided the initial and final conditions are identical.

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3
Q

the standard state of an element is the form in which it exists at the

A

specified temperature, usually 298K and a pressure of 100kPa

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4
Q

the equation which shows the standard enthalpy change of formation of gaseous carbon dioxide is

A

C(s, graphite) + O2(g) = CO2(g)

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5
Q

the equation which shows the standard enthalpy change for the formation of liquid ethanol is

A

2C(s, graphite) + 3H2(g) + 1/2 O2(g) = C2H5OH(l)

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6
Q

most standard enthalpy changes of formation are

A

impossible to determine experimentally

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7
Q

in general terms, the enthalpy cycle which is used to calculate enthalpy change of formation of a compound from the relevant enthalpy changes of combustion is:

A

ΔfH
component elements → compound
→ →
sum of ΔcH of elements sum of ΔcH of compound
combustion products

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