SQUAREDEL REVIEWER 2019 ORGCHEM Flashcards
- Which of the following structures represents a molecule different from the others?
I. /\/°\/\ III. /\/°\/°\/
| |
°\ \
II. /\/°\/°\ IV. /\/°\/\
| /\
\ H OMe
A. I
B. IV
C. II
D. III
D. III
- Which is the correct molecular formula of the following molecule?
/
///
//\//\/
I. C8H8
Il. C8H10
III. C7H8
IV. C7H10
A. II
B. IV
C. I
D. III
A. II
- Which of the following compounds has an ionic bond?
I. H2O
II. NH4Cl
III. CH3Cl
IV. CH3Li
A. II
B. IV
C. I
D. III
A. II
- How many hydrogen atoms are in one molecule of propene?
A. 4
B. 3
C. 6
D. 8
C. 6
- Which is the correct IUPAC name of the following compound?
Br CH2CH3 | | CH3CH2CHCH=CCH2CH3
A. 5-bromo-3-ethylhept-3-ene
B. 3-ethyl-5-bromohept-3-ene
C. 3-bromo-5-ethylhept-4-ene
D. 1,1-diethyl-3-bromopent-1-ene
A. 5-bromo-3-ethylhept-3-ene
- In which species are all the carbon atoms considered to be sp2 hybridized?
I. C2H2 II. C2H4 III. C3H8 IV. C4H10
A. IV
B. II
C. I
D. III
B. II
- For which compound are the empirical and molecular formulas the same?
I. C6H5COOH
II. C6H4(COOH)2
III. HOOCCOOH
IV. CH3COOH
A. III
B. I
C. IV
D. II
B. I
- How many different compounds have the formula C5H12?
A. 5
B. 2
C. 4
D. 3
D. 3
- In which species is the carbon-nitrogen bond the shortest?
I. CH3NH2
II. CH2NH
III (CH3)4N^+
IV CH3CN
A. II
B. I
C. IV
D. III
C. IV
- What is the hybridization of the carbon atom in a carboxyl group?
A. sp
B. sp^3
C. sp^2
D. dsp^3
C. sp^2
- Which compound is an aldehyde?
I. /\/\ III. /\/
OH OO II. /\\/ \ O || IV. /\\/ \
A. II
B. III
C. IV
D. I
B. III
- Which compound is NOT an ether?
I. CH.CH.OCH.CH III. CHCOCH.CH
O II. //\/ \/ IV. //\/\ / | || | ||O \\/ \\/
A. IV
B. I
C. II
D. III
D. III
- Which compound is a tertiary amine?
I. (CH)CNH III. (CH.CH)NH
CH3 CH3
| |
II. CH3.CH2.CNH2 IV. CH3.CH2.NCH3
|
CH3
A. II
B. III
C. I
D. IV
D. IV
- Which of the following hydrocarbon has the lowest boiling point?
I. C4H10
II. CH4
III. C6H6
IV. C2H6
A. IV
B. II
C. I
D. III
B. II
- Which compound is a tertiary alcohol?
I. (CH)COH III. (CH.CH.) CHOHOH H | | II. CH3.CH2.CH.CH3 IV. CH3.CH2.O.CH3
A. III
B. IV
C. II
D. I
D. I
- How many different alcohols have the molecular formula C4.H10.O?
A. 2
B. 4
C. 3
D. 5
B. 4
- Which compound is expected to be most soluble in water at 25 °C
I. N2 (g)
II. O2 (g)
III. (C2H5)2.NH (l)
IV. C2H5.O.C2H5 (l)
A. III
B. IV
C. I
D. II
B. IV
- The gentle oxidation of ethanol, CH3.CH2.OH, produces
I. ethanal, CH3.CHO
Il. ethanoic acid, CH3.CO2.H
Ill. carbon monoxide, CO
IV. carbon dioxide, CO2
A. IV
B. I
C. II
D. III
B. I
- The following compounds have very similar molar masses. What would be the correct order when they are arranged in order of increasing strength of their intermolecular forces.
I. C3H8
II. CH3.O.CH3
Ill. CH3.CH2.OH
A. II < I < III
B. III < I < II
C. I<II<III
D. III < II < I
C. I<II<III
- A reaction in which a carboxylic acid reacts with an alcohol to form an organic compound and
water is called
A. saponification
B. esterification
C. neutralization
D. hydrolysis
B. esterification
- Which class of compounds consists exclusively of saturated hydrocarbons?
A. alkenes
B. aromatics
C. alkynes
D. alkanes
D. alkanes
- What is the position of the bromine atom relative to the methyl group in 3-bromotoluene?
A. meta
B. para
C. ortho
D. trans
A. meta
- The smell of rancid butter is due to the presence of butyric (butanoic) acid. What is the formula for this compound?
I. C4H8.O2
Il C4H10.O
Il. C5H10.O2
IV. C5H12.O
A. IV
B. II
C. III
D. I
D. I
- Which compound has the highest boiling point?
I. CH3.CH2.CH3 III. CH3.OCH2.CH3
II. CH3–C–CH3 IV. CH3.CH2.CH2.OH
||
O
A. I
B. III
C. II
D. IV
D. IV
- Which combination of reactants produces an ester?
A. aldehyde and potassium permanganate
B. acid and alcohol
C. acid and aldehyde
D. alcohol and aldehyde
B. acid and alcohol
- In crystallization, the solution which is obtained after filtration is the ___________.
A. clear solution
B. colloidal solution
C. suspended solution
D. None of the given answers
A. clear solution
- In crystallization, the crystal phases can be inter-converted by varying ____________
A. temperature
B. pressure
C. viscosity
D. size
A. temperature
- Which separation technique is based on differences in the volatility of the compounds to be
separated?
A. solvent extraction
B. distillation
C. paper chromatography
D. filtration
B. distillation
- Fractional distillation is different from distillation because of the presence of a
A. Fractionating column
B. Condenser
C. Conical flask
D. Distillation flask
A. Fractionating column
- The process of heating a liquid mixture to form vapors and then cooling the vapors to get a pure component is called
A. Distillation
B. Chromatography
C. Crystallization
D. Sublimation
A. Distillation
- A common measure of efficiency in a fractionating column is the
A. length of the condenser used in the setup
B. number of distillation types
C. number of components in the solution
D. number of theoretical plates in the column
D. number of theoretical plates in the column
- Five grams of an organic solid was dissolved in 100 mL of distilled water. Which of the following extraction methods can remove the largest amount of organic solid from an aqueous solution?
A. Extract the aqueous solution with a 150-mL portion of ether.
B: Extract the aqueous solution with three 50-mL portions of ether.
C. Extract the aqueous solution with a 150-mL portion of acetic acid.
D. Extract the aqueous solution with three 50-mL portions of acetic acid.
B. Extract the aqueous solution with three 50-mL portions of ether.
- Which of the following funnels should be used to filter hot mother liquor during recrystallization?
A. Buchner funnel
B. Hirsch funnel
C. Long stem funnel
D. Short stem funnel
D. Short stem funnel
- What is the key step in a recrystallization process?
A. Taking the melting point of wet crystals
B. Dissolving the solid in a large quantity of cold solvent
C. Allowing the hot solution to cool slowly and let crystals grow
D. Removing the soluble impurities by vacuum filtration
C. Allowing the hot solution to cool slowly and let crystals grow
- Which of the following is the example of crystallisation process?
A. Purification of alum
B. None of the given answers
C. Separation of gases from air
D. Purification of sea water
A. Purification of alum
- A constant boiling mixture of two or more components in a solution is called a/an
A. azeotrope
B. Ideal solution
C. non-ideal solution
D. eutectic mixture
A. azeotrope
- A compound is known to decompose at its boiling point. Which of the following methods can be used to purify this substance?
A. Steam distillation
B. Fractional distillation
C. Liquid-liquid extraction
D. Vacuum distillation
A. Steam distillation
- When the solid and liquid phases are in equilibrium, the temperature of the system
A. decreases gradually
B. none of the given answers
C. increases gradually
D. remains constant
D. remains constant
- Which is the INCORRECT statement among the following?
A. An impure sample of the substance has a different melting point.
B. Two different pure substances have the same melting points.
C. Melting point serves as the criterion of purity of a solid substance.
D. Every pure solid crystalline substance has a characteristic and unique melting point.
B. Two different pure substances have the same melting points.
- The boiling point of a liquid is the temperature at which the vapor pressure is
A. lesser than internal pressure
B. equal to internal pressure
C. equal to external pressure
D. greater than internal pressure
C. equal to external pressure