Solubility and the Solubility Product Constant (Ksp) Flashcards

1
Q

Salts dissolve more readily in solvents with ____________ like water.

A

electrostatic dipoles

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2
Q

These two energies are opposing and compete with each other, thus telling whether a salt forms ions effectively in solution or not.

A

Solvation and lattice energy

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3
Q

For a substance to be readily soluble, the ______ energy must be greater in magnitude than ______ energy.

A

solvation/ lattice

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4
Q

❑ When the ions are in solution, they are surrounded by water molecules, and the ions are said to be _______.

A

solvated

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5
Q

The lattice energies of difficulty soluble salts are comparatively _____ than their energies of solvation

A

larger

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6
Q

They produce only few ions in solution, thus making the reaction reversible.

A

slightly/sparingly soluble salts

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7
Q

In a _______solution, an equilibrium is established between ions in solution and undissolved solutes.

A

saturated

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8
Q

In slightly/sparingly soluble salts the ________ exist between ions detaching from the crystals and ions depositing back to the crystal salt.

A

equilibrium

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9
Q

The ______ of a substance is the amount of that substance that will dissolve in a given amount of solvent usually expressed in grams/Liter or g/100mL

A

solubility

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10
Q

Although most compounds dissolve in water to some extent, many are so slightly soluble that they are called

A

“insoluble compounds

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11
Q

As a rule of thumb, compounds that dissolve in water to the extent of ___________ or more are classified as soluble (Molar Solubility

A

0.020 mole/liter

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12
Q

may be considered to be in equilibrium; the equilibrium is between solid and ions in solution.

A

Solubility

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13
Q

Any _____ solid is 100% ionized in an aqueous solution; once it actually dissolves.

A

ionic solid

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14
Q
  • an expression that has the same form as the equilibrium constant expression but whose concentration values are not necessarily those at equilibrium.
A

Reaction Quotient

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15
Q

Reaction quotient denoted as

A

Qsp

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16
Q

Qsp < Ksp

A

– Forward process is favored

17
Q

• Qsp < Ksp

A

– No precipitation occurs, if solid is present, more solid can dissolve

18
Q

Qsp > Ksp (The minimum factor is at 1000)

A

Reverse process (backward) is favored

19
Q

Precipitation occurs to form more solid

A

• Qsp > Ksp

20
Q

• Qsp > Ksp

A

Precipitation occurs to form more solid

21
Q

Qsp = Ksp

A

– Solution is just saturated

22
Q

– Solid and solution are in equilibrium; neither forward nor reverse process is favored

A

• Qsp = Ksp