Solid State (Class 12th) Flashcards

1
Q

packing efficiency of simple cubic unit cell

A

52.4

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2
Q

packing efficiency of FCC

A

74

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3
Q

packing efficiency of BCC

A

68

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4
Q

packing efficiency of HCP - 3D

A

74

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5
Q

packing efficiency of HCP - 2D

A

90.4

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6
Q

packing efficiency of Square Close Packing

A

78.4

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7
Q

packing efficiency of diamond

A

34

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8
Q

relation between edge length and radius in simple cubic unit cell

A

a=2r,d=a

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9
Q

relation between edge length and radius in FCC

A

a=2root2r d=a/root2

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10
Q

relation between edge length and radius in BCC

A

a=4r/√3 d=√t3 a /2

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11
Q

Density of unit cell (g/cm^3)

A

z*M/ Avag. no. * a^3

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12
Q

z(no of atoms in lattice) value for FCC,BCC and ECC

A

4,2,2

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13
Q

z value for HCP-3d

A

6

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14
Q

z value for diamond

A

8

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15
Q

Nacl type, Zns type, CaF2 type , Na2O type z=

A

4

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16
Q

CsCl z=

A

1

17
Q

(sum of radius of cation and anion of NaCl) * 2

A

a

18
Q

(sum of radius of cation and anion of CsCl) * 2

A

√3 a

19
Q

what is radius ratio?

A

radius of cation/ radius of anion

20
Q

significance of radius ratio

A

directly proportional to cation radius and coordination number

21
Q

what are the ranges of radius ratio,C.N and type of void

A
  1. 155 - 0.225 (3) triangular
  2. 255- 0.414 (4) tetrahedral
  3. 414 - 0.732 (6) octahedral
  4. 732 - 1 (8) cubic
22
Q

eg of cn = 3

A

triangular void - b2o3

23
Q

eg of cn = 4

A

ZnS CuCl CuBr CuI HgS

24
Q

eg of cn = 6

A

NaCl, MgO, CaO

25
Q

eg of cn = 8

A

CsCl , NH4Br

26
Q

Octahedral void radius

A

0.414 * R (radius of atom)

27
Q

Tetrahedral void radius

A

0.225 * R

28
Q

Ionic solids table

A

pg 27 ntbk