Soil Colloids Flashcards
Most chemically active portion of the soil
Soil Colloids
Soil particles [____] or [_____] in diameter
<1μ, 0.001 mm
Types of Soil Colloids
- Inorganic
(______)
(______)
(______) - Organic
(______)
Silicate clays
Oxides of Fe and Al
Allophanes
Humus
A silicate clay crystal
Micelle
Types of Silicate clays
1:1
2:1 non expanding type
2:1 expanding type
2:1:1 or 2:2
One tetrahedral sheet attached to one side of an octahedral sheet
- Represented by the mineral kaolinite
- Other 1:1 include halloysite, nacrite, dickite
1:1 Silicate clay
If a trivalent is the central cation, two-thirds of the available cation sites are filled
Dioctahedral
- Symmetrical arrangement of two tetrahedral sheets and a central octahedral sheet
- Represented by montmorillonite or smectite group of clay; also by vermiculite
- Isomorphous substitution is common (Al3+ to Si4+, Mg2+ to Al3+)
- Expand or contract as water molecules are added or removed
2:1 Expanding Silicate Clay
- Same composition/structure as the
other 2:1 type but doesn’t expand
due to the presence of K+ ions
“bridging” the silicate clays - Represented by muscovite (mica)
2:1 Non expanding silicate clay
- Structure: two silica tetrahedral sheet and two Mg-dominated octahedral sheet
- Represented by chlorites
2:1:1 or 2:2 Silicate clay
Commonly dominant in the highly weathered soils of tropics and subtropics
Hydrous oxide of Fe and Al
A colloidal matter that is either amorphous or the crystalline structure is not sufficiently ordered to be detected by x-rays
Allophanes and other amorphous minerals
Composed of C, H and O, that is non crystalline
Humus
Prevalent in soils developed from volcanic ash (Andisols)
Allophanes and other amorphous minerals
Sources of negative charges
Dissociation of exposed OH groups at the broken edges of the mineral
Dissociation of functional groups in organic colloids