soap and detergents Flashcards
definition,micelles,saponification,manufacture of soap,preparation of soap,advantages and disadvantages of soap , detergents,preparation of detergents,ingredients in detergents, advantages and dis advantages of detergents of soap
what is soap
sodium and potassium salt of long chain of fatty acids is called soap
soap is acidic or basic in nature
it is salt of strong base and weak acid (carboxylic acid ) therefore it is basic in nature
soap has large number of ………… hydrocarbon and small number of ………….. group ?
soap has large number of non ionic hydrocarbon and small number of ionic group(COO- Na+) that is soap.
/\/\/\/\/\/\/=OONa
first terminal is ionic or non ionic
first—-non ionic ….. hydrocarbon
second—–ionic…. soap molecule
what is micelles
soap molecule has 2 ends or terminals with different properties
long chain of hydrocarbon is ……
hydrophobic (insoluble in water)
short ionic part is ……
hydrophilic ( soluble in water)
short ionic part contain in soap is
COO-Na+ and COO-K+
O~~~~~
HYDROPHILIC OR HYDROPHOBIC
O =HYDROPHILIC SOLUBLE IN WATER
~~~~~ =HYDROPHOBIC INSOLUBLE IN WATER
properties hydrocarbon chain is
non polar ,hydrophobic ,repel water
properties of ionic part
polar,soluble in water,hydrophilic
hydrophobic part dissolve
grease dust oil
hydrophilic part dissolve
water
define saponification
process of making soap by hydrolysis of fats or oil with alkali is called saponification
soap is formed
by heating animal fats and vegetable oil with concentrated KOH
FATS /OIL——>
soap + glycerol
glycerol is a type of
alcohol
manufacture of soap
a) hot process
i. batch or kettle process: old technique,small scale industries, time consuming
ii. continuous process:new modern technique, large scale
b) cold process
preparation of soap
1-melting of fats
2-blending of melted fat through catalyst (ZnO/ MgO)
3-Hydrolysis :smooth paste is heated through steam as result fatty acid and glycerin and glycerol were separated.
4-distillation of glycerin and fatty acids(to make it pure)
5-neutralization: fatty acid neutralize by 50% of Na OH to obtain soap
6-heating and cooling to improve quality of soap
7-additive <color perfumes, anti germs agents, builders>
advantages of soap
Eco friendly biodegradable
disadvantages of soap
not suitable in hard water
weaker cleaning properties than detergents
*c why detergents are better cleaning agents than soap
because thy can use even with hard water . when soap react with hard water it react with Ca and Mg ions of hard water to form insoluble participate called scum*
what are detergents
they are sodium salt of long chain of benzene sulfonic acid.
detergents are primary or secondary surfactants
they are primary surfactants which could be easily produced petrochemical surfactants.