Simple Models 1 Flashcards
What are the sources and sinks in a one box model?
Sources: Flow in (F_in), Emissions (E), Chemical Production (P)
Sinks: Flow out (F_out), Deposition (D), Chemical Loss(L)
Define lifetime/residence time
The average time that a compound remains in the atmosphere
define lifetime in terms of mass and its sinks
Lifetime = m/ F_out + D + L
What are sink specific lifetimes
𝜏_out= m/F_out
𝜏_c = m/L
𝜏_d= m/D
Define Fraction of removal, literally and mathematically.
The fraction of the total removal of a compound specific to one sink.
f_out= F_out/ F_out + L + D = 𝜏/𝜏_out
Lifetimes in Parallel
1/𝜏 = 1/𝜏_ out + 1/𝜏_c + 1/𝜏_d
Define Reaction Rate
the speed at which a specific reaction/process occurs
What is a first order reaction rate constant?
L= K_c M
D=K_d M
F_out=K_out M
the Ks are reaction rate constants
K is a proportionality constant that expresses the relationship between the reaction rate and the concentration of that compound
What is the relationship between the reaction rate constant and lifetime tau.
k_c = 1/𝜏_c
k_d= 1/𝜏_d
k_out= 1/𝜏_out
Define Total Loss Rate
F_out+L+D = (k_out+k_c+k_d)M = kM
overall loss rate: k
k= k_out + k_c + k_d = 1/𝜏
what does dm/dt indicate.
Change in mass of X with respect to time
what does dm/dt equal to.
dm/dt= Sources - Sinks
dm/dt= F_in + E + P - F_out - L - D
dm/dt= S-kM
define Steady State
with enough time a system tends towards equillibrium.
Rate of formation = Rate of Destruction
steady state formula
dm/dt = 0
S=kM
dm/dt = S-kM = 0