Shapes Of Molecules And Intermolecular Forces Flashcards

1
Q

2 bonding clouds, 0 lone pair clouds

A

Linear

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2
Q

3 bonding clouds, 0 lone pair cloud

A

Trigonal planar

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3
Q

2 bonding clouds, 1 lone pair cloud

A

Bent

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4
Q

4 bonding clouds, 0 lone pair clouds

A

Tetrahedral

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5
Q

3 bonding clouds, 1 lone pair cloud

A

Pyramidal

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6
Q

2 bonding clouds, 2 lone pair clouds

A

V shaped

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7
Q

5 bonding clouds, 0 lone pair clouds

A

Trigonal bipyramidal

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8
Q

6 bonding clouds, 0 lone pair clouds

A

Octahedral

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9
Q

4 bonding clouds, 2 lone pair clouds

A

Square planar

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10
Q

Linear

A

180°

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11
Q

Trigonal planar

A

120°

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12
Q

Bent

A

Roughly 118°

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13
Q

Tetrahedral

A

109.5°

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14
Q

Pyramidal

A

Roughly 107°

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15
Q

V shaped

A

Roughly 104.5°

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16
Q

Trigonal bipyramidal

A

90°,120°,180°

17
Q

Octahedral

A

90°

18
Q

Square planar

A

90°

19
Q

Define ionic bonding

A

A multi-directional electrostatic attraction between ions of opposite charge

20
Q

Why do ionic compounds have high melting and boiling points

A

Giant ionic lattice. Electrostatic attraction between positive and negative ions are numerous and strong so lots of heat energy is required to overcome the attractions

21
Q

Which ionic compounds conduct electricity and why

A

Solids don’t conduct because charged particles are not free to move. Molten or aqueous compounds do conduct because ions are free to move and carry the charge

22
Q

What do ionic compounds dissolve in and why

A

Ionic compounds dissolve in water (a polar solvent) because charges in the water can attract the ions in the ionic solid causing the ions to break off and the water molecules surround the ions causing the solid to dissolve. They do not dissolve in non polar solvents because there is no attraction between the ions and the solvent molecules

23
Q

Why is a giant ionic lattice formed

A

Oppositely charged ions that are strongly attracted in all directions

24
Q

Define covalent bonding

A

A directional, electrostatic attraction between the 2 positive nuclei of the atoms in the bond and one or more pairs of electrons shared between them

25
Q

What bonds does hydrogen form

A

1 single bond

26
Q

What bonds do group 7 form

A

1 single bond

27
Q

What bonds does group 6 form

A

2 single bonds or 1 double bond

28
Q

What bonds does group 5 form

A

3 single bonds or 1 double and 1 single bond or 1 triple bond

29
Q

What bonds does group 4 form

A

4 single bonds or 1 double and 2 single bonds or 2 double bonds or 1 single and 1 triple bond

30
Q

How do we measure the strength of a covalent bond

A

Average bond enthalpy

31
Q

Lone pair definition

A

A pair of electrons in the outer shell of an atom that is not involved in bonding

32
Q

Define electronegativity

A

A measure of the ability of an atom in a covalent bond to attract the bonding electron density towards itself

33
Q

How do you get bond polarisation

A

When atoms of different electronegativity are joined together

34
Q

Define London forces

A

The attractions between temporary, flickering dipoles and induced dipoles

35
Q

What does the strength of London forces depend on

A

The number of electrons- more electrons= stronger London forces and the symmetry/shape of molecules

36
Q

Define dipole dipole attractions

A

The attractions between permanent dipoles in separate molecules

37
Q

What is needed to form a dipole dipole attraction

A

Polar molecules- molecules that have a permanent dipole. To have a permanent dipole you need bond polarisation and a separation of charge

38
Q

Define a hydrogen bond

A

An attraction between a hydrogen atom bonded to nitrogen, oxygen or fluorine in one molecule and a lone pair of electrons on an atom in an adjacent molecule