shapes Flashcards
what does VSEPR stand for?
valence shell electron pair repulsion
what is the VSEPR theory?
pairs of electrons that have a negative charge will repel each other to the maximum angle possible to minimise the total repulsion in the molecule
where are lone pairs?
close to the nucleus => only attracted to the positive nucleus of an atom
what are bonding pairs?
spread out between two bonded atoms => attracted to the nucleus of both atoms they join
order of repulsion size?
LP-LP > LP-BP > BP-BP
- Linear
> 2BP, 0LP
bond angle: 180º
examples: BeCl2, BeH2, CO2
- Bent
> 2BP, 2LP
104.5º
examples: H2O, H2S
- trigonal planar
> 3BP, 0LP
120º
examples: BF3, AlCl3, BCl3
- tetrahedral
> 4BP, 0LP
109.5º
examples: CH4, SIH4, NH4+, SiF4, CCl4
- pyramidal
> 3BP, 1LP
107º
examples: NH3, PH3, PCl3, H3O+
- octahedral
> 6BP, 0LP
90º
examples: SF6