Separate Chemistry 2 (Topic 9) Flashcards
What is a cation
A positively charged ion, nearly all metal ions
What are the two tests for cations
- Flame test
- Metal hydroxide test
Steps of the flame test
- Take a platinum or nichrome wire loop, and dip it in dilute hydrochloric acid and heat over a bunsen burner
- Dip the loop in the compound you want to test
- Hold the wire loop in the clear blue part of the bunsen flame (hottest)
- See what colour flame the compound burns
What colour does lithium burn
Red
What colour does sodium burn
Yellow
What colour does potassium burn
Liliac
What colour does calcium burn
Orange - red
What colour does copper burn
green - blue
How do you perform the metal hydroxide test
Mix the metal ion with a solution of sodium hydroxide and see what colour the solution turns
What colour precipitate does Copper(II) form when reacting with hydroxide ions
A blue precipitate of copper hydroxide
What colour precipitate does calcium form
A white precipitate
What colour precipitate does Iron(II) form
A green precipitate
What colour precipitate does Iron(III) form
A brown precipitate
What colour precipitate does Aluminium form
A white precipitate
How to differentiate between aluminium and calcium
If you add excess sodium hydroxide, aluminium’s white precipitate will redissolve to form a colourless solution
What colour precipitate does Magnesium form
A white precipitate
What is an anion
A negatively charged ion
How to test for carbonate ions
- React the substance with Hydrochloric acid
- If the substance contains carbonate ions, carbon dioxide gas will bubble out of the solution
- Collect the gas and bubble it through limewater
- If the limewater turns cloudy, carbon dioxide is present
- therefore if it contained carbon dioxide it contained carbonate ions
When testing for carbonate ions how can the gas be collected
- attaching the top of the test tube to a gas syringe
- Place an upside down measuring cylinder over the test tube to trap the gas
How to test for sulfate ions
- React the solution with hydrochloric acid to remove any carbonate ions
- Add barium chloride solution
- if sulfate ions are present, it will form a white precipitate of barium sulfate
How to test for halide ions
- React the solution with nitric acid to remove any carbonate or sulfate ions
- Add silver nitrate to the solution
If the precipitate is white, chloride ions are present
If the precipitate is cream, bromide ions are present
If the precipitate is yellow, iodide ions are present
How does flame emission spectroscopy work
- Metal ions are heated until they emit light
- The light is detected by a spectroscope which can distinguish between the individual wavelengths of light emitted
- As each metal ion emits a unique combination of wavelengths it will produce a unique line spectrum
- this allows us to identify an unknown metal cation by comparing its line spectrum to those of known metal cations in a data bank
What does the intensity of a line spectrum tell us about the metal cation
Its concentration
What are the main benefits of instrumental methods of chemical analysis over manual methods
- Higher sensitivity
- Higher accuracy
- Faster test
As the number of carbon atoms in an alkane increase, what happens to the viscosity
It increases
As the number of carbon atoms in an alkane increases, what happens to its flammability
It decreases
As the number of carbon atoms in a alkane increases, what happens to its melting and boiling points
They increase
Word equation for complete combustion of a hydrocarbon
hydrocarbon + oxygen –> carbon dioxide + water