Seds - Diagenesis Flashcards
Diagenesis
The physical, chemical or biological alteration of sediments into sedimentary rock at relatively low temperatures and pressures that can result in changes to the rock’s original mineralogy and texture
Diagenetic Process stages
- Compaction
- Burial
- Decomposition
- Alteration
- Dissolution
- Precipitation
- Lithification
Diagenesis in sandstones:
- Chemical and physical compaction
- Decomposition – feldspars, micas
- Dissolution – internal structures lost (such as feldspars) and will turn to clay
- Partially dissolving a quartz crystal – causes rich silica around it – will precipitate later
- Initial compaction is mechanical compaction – fast but can only take you so far – about 22% porosity
- 80-90 degrees centigrade – quartz will begin to dissolve and fill the pore space – causing more compaction
Mechanical compaction
• Goes from point contacts to long contacts to convex-concave compaction which is the most compaction – will lead to suturing – loss of material
• Early cementation will stop mechanical compaction – rocks unable to rearrange and push into eachother
• More compaction = minerals pushed together
o Quartz is hard so contact points will change (point, long, convex, concave, sutured)
o When too deep, the quartz will shatter and fracture (not common)
o Can bend micas
Chemical compaction
Essentially movement of minerals to make space
o Minerals can be reprecipitated outside of crystals
• Pressure dissolution of long contacts – minerals dissolve into eachother – stylolites – dissolution surfaces
• Overgrowths
• Cements – reprecipitation of minerals from surrounding crystals
• For quartz = 90-120 degrees – 2-4km – chemical compaction
• Quartz cement overgrowth can reduce the porosity (90-130°C) – macroquartz
• Detrital and authigenic grain coatings can inhibit quartz cement overgrowth
• Microquartz coatings from biogenic silica (sponge spicules) (60-80°C) Authigenic clay mineral coatings grow at temperatures of
• 60-100°C for chlorite
• 70-90°C for illite
Clastics vs Carbonates
Clastics – smooth curve of porosity loss to depth – inflection point at around 2km when chemical compaction kicks in
Carbonates – sharp change, loss a lot of porosity quickly
• Carbonates is soft, so they deform so stress is spread over a wide area so a reduction in compaction that is fairly severe occurs. Get a bit stronger as long contacts seen.
• 800m till chemical compaction
• For carbonates its temperature that’s important not depth
Controls
- Depth Pressure + Temperature
- Initial sediment composition + texture
- Tectonic stresses Can cause increases in pressure that are not due to depth
- Pore fluid
Mechanical Compaction pressure:
Driven by vertical effective stress (VES)
Pore fluid pressure can reduce this stress - reduces compaction
Grain framework strengthening framework reduces VES - reduces compaction - calcite
Controls on mechanical compaction ref
Grain size, shape and sorting, both in sandstones and mudstones, play an important role in determining the mechanical compaction prior to chemical compaction
Bjørlykke 2013