Section 2 - Essential Plant Nutrients Flashcards
List three ways to make Se fertilization acceptable.
- Se topdressing is not applied
- High Se levels in edible animal tissue are prevented
- Protection against Se deficiency is provided for at least one grazing season following application during the dormant season
S is absorbed by plant roots almost exclusively as ___.
sulfate (SO4‐2)
Name four ways Mg is found in soil solution.
- lost in percolating water
- absorbed by microorganisms
- adsorbed on the CEC
- reprecipitated as a secondary mineral
P tends to stay where it’s applied and not move through the soil, unlike N and K which can be lost from the soil solution. P will accumulate thus N-P-K fertilizer ratios need to be adjusted to P=0.
True
Rates of reaction with P are ___ therefore plants have a chance to take it up
slow
As organic P is mineralized to inorganic P or as P is added to soil, inorganic P in solution (H2PO4‐/HPO4‐2) not absorbed by roots or immobilized by microorganisms can be adsorbed to mineral surfaces or precipitated as secondary P compounds
True
The concentration of the inorganic P in the soil solution is the most important single factor governing the availability of plants. Uptake of H2PO4- is more rapid than HPO4-2 with the former being most abundant at pH < 7.2.
True
Name 7 factors that affect P mineralization and immobilization
- Microbial activity
- Residues C/P ratio
- Soil temperature
- Soil aeration
- Soil pH
- Soil moisture
- P fertilization
What are the 5 available soil solutions for K Loss?
1) Adsorption
2) Leaching
3) Plant removal
4) Erosion
5) Fixation
P concentrations in plants range between 0.1 and 0.5%, considerably ___ than N and K. Plants absorb either H2PO4‐ or HPO4‐2 (orthophosphate) depending on soil pH.
lower
Organic P represents about __% of total soil P and typically varies between 15 and 80%.
50
Solution K+ in ___‐textured soils may be much lower than in ___‐textured soils at any given level of exchangeable K.
fine
course
Soil moisture: Mo deficiency is accentuated under ___ ___.
dry conditions
K is absorbed by plant roots as __ and tissue concentration ranges from _ to _% in dry matter.
K+
1 to 5%
___ soils need to be limed first before adding K
Acidic
The soil pH of maximum availability for P is pH _._.
6.5
Soils containing ___, ___, or ___ have more K than soils containing mainly kaolinitic clays, common in highly weathered soils.
vermiculite, montmorillonite, or mica
Excessive Water and Poor Aeration: Any compact, fine-textured, calcareous soil can be Fe ___.
deficient
Excessive Water and Poor Aeration: Waterlogged soils exhibit ___ O2 and lower redox potential, which increases soluble Mn+2. Mn availability can be ___ by poor aeration in compact soils and by local accumulation of CO2 around roots and other soil microsites.
reduced
increased
___ is a major component of bones and teeth and is important for lactating animals.
P
The addition of residues low in P may ____ immobilization if there is not enough P to degrade residues.
stimulate
Typical K deficiency symptoms in alfalfa consist of ___ ___ on the leaf edges, whereas ___ and ___ of the leaf edges are observed with corn and other grasses.
white spots
chlorosis and necrosis
Organic Cu: Most of the soluble Cu+2 in surface soils is ___ ___ and is more strongly bound to OM than any other micronutrient.
organically complexed
S in Earth’s crust averages ≈ _.__%, comparable to P.
0.05
K in primary mineral structure is ___
unavailable
Soils do have a lot of P (top 50 cm) but are mostly unavailable due to ___
fixation
The extent ___ _ fixation depends on many factors, most importantly on soil minerals.
inorganic K
What are eight factors influencing inorganic P fixation in soils?
- Soil minerals
- Soil pH
- Cation and anion effects (NH4+/NO3-)
- Soil OM
- Time and temperature
- Soil moisture
- Fertilizer P management
- Considerations (rate, time, type, method)
What are the six most important factors in determining Ca+2 availability to plants?
- Total Ca supply
- Soil pH
- CEC
- % Ca+2 saturation on CEC
- Type of soil clay
- The ratio of solution Ca+2 to other cations
Exchangeable K is highly correlated to K availability to plants as exchangeable K ___, fertilizer K recommendations ___.
increases
decreases
Soil Solution Mn: ___ is the common form in solution; its concentration decreases ___ ___ for each unit increase in pH.
Mn+2
one hundredfold
Organic wastes are excellent sources of ___-___ P, with manure accounting for __% of organic P applied to cropland
plant-available
98
Surface adsorption and precipitation reactions are collectively called ___ ___ or retention
P fixation
Name eight nutrients that are immobile in plants. Deficiency symptoms show up on ___ leaves first
- Ca
- Cu
- Mn
- Zn
- Fe
- Mo
- B
- S
younger
Sulfur is essential for ___
protein
Which of the following is not true about liming acid soils by applying CaCO3?
A) It supplies Ca to plants
B) It corrects soil acidity
C) It increases crop yield
D) It increases acidic cations saturation of soil colloids
D) It increases acidic cations saturation of soil colloids
What are the three Secondary Macronutrients?
- S
- Ca
- Mg
K is important for many crop quality characteristics due to its involvement in the ___ and ___ of ___ to plant reproductive and storage organs and subsequent conversion into carbohydrates, proteins, oils, and other products.
synthesis and transport of photosynthates
Soil Texture: Coarse-textured, well-drained soils are ___ in B, and crops with a ___ requirement respond to B applications. Sandy soils ___ respond in the same manner.
low
high
don’t
The quantity of K transported to the root surface by ___ and ___ ___ is related to K intensity.
diffusion and mass flow
Adequate ___ increases straw strength in cereals and increases N2‐fixation capacity of legumes.
P
Texture: The potential for Cu deficiency is high in ___ leached, ___-textured soils.
excessively
course
Which of the following does not affect Fe availability in soil solution?
A) crop removal
B) soil organic matter
C) soil pH
D) soil N2 gas
D) soil N2 gas
Co in Soils: Average total Co concentration in Earth’s crust is ≈ __ ppm. Co in soils typically range from 1 to 70 ppm and average about 8 ppm.
40
Cu Deficiency and Toxicity: Although not as common as with other micronutrients, Cu deficiencies do occur in sensitive crops on low Cu soils. Cu toxicity symptoms include reduced ___ ___, poorly developed and discolored root systems, and ___ ___.
shoot vigor
leaf chlorosis
Soil S is present in organic and inorganic forms, although ≈ ___% of total S in noncalcareous surface soils exists as ___ __.
90%
organic S
Soil texture: In sandy, low OM soils, MoO4-2 retention is ___.
low
Mineral Mo: The average Mo concentration in the earth’s crust is __ ppm, and typically ranges from 0.2 to 5 ppm in soils. Soil minerals controlling solution MoO4-2 concentration are PbMoO4 and CaMoO4. CaMoO4 predominates in both acidic and calcareous soils.
62
The percentage of P2O5 in Ca3(PO4)2 is: (use Ca=40, P=31, and O=16 g molecular weights)
A) 20
B) Impossible to calculate since there is no P2O5 in the formula.
C) 23
D) 46
D) 46
Soil OM: Although lime-induced Fe deficiency occurs in ___ soils, low-OM ___ soils are often in plant-available Fe.
wet
calcareous
Mg constitutes ~_% of Earth’s crust; however, total soil Mg content ranges from 0.1% in coarse, humid-region soils to 4% in fine-textured, arid, or semiarid soils formed from high-Mg minerals.
2%
K is essential for photosynthesis for the production and activity of specific ___ ___.
photosynthetic enzymes
Na in Plants: Na is essential for ___ plants that accumulate salts in vacuoles to maintain turgor and growth. Na+ concentration in ___ ___ varies from 0.01 to 10%. Many C4 plants require Na, which is specifically involved in water relations. Many C4 plants occur naturally in arid, semiarid, and tropical conditions.
halophytic
leaf tissue
Name five porphyrin molecules Fe is used for in structural components.
- cytochromes
- hemes
- hematin
- Ferrichrome
- leghemoglobin
The greatest world P resources are in ___ & ___.
Morocco & Western Sahara
A soil contains 2% OM with a 2% loss each year (SOM 58:5 C:N). The farmer wanted to increase OM to 3%. How many years will it take if she produces 10,000 lb crop residue/a (residue contains 44% C and 1% N and 70% of the residue is lost by oxidation /a/year). (Hint see page 144 Estimating Soil OM Production and SOM = 58% C, 5% N.)
___ P: Available/exchangeable
Labile
Co is essential for the growth of some ___ ___. Plant concentration ranges from ___ to ___ ppm.
symbiotic microorganisms
0.02 to 0.5
___ ___ generally contains low Mg, although, at rates applied to meet N or other macronutrient needs, sufficient Mg to meet most crop needs can be applied.
Organic biosolids
Cl- is absorbed by plants through ___ and ___ . Active transport of Cl- across ___ ___ occurs through other anion transporters.
roots and leaves
plasma membranes
Soil OM: ___ forms stable complexes with high molecular-weight organic compounds (i.e., lignin, humic, and fulvic acids) that exist as soluble or insoluble complexes.
Zn+2
Soil solution Cu and plant available Cu are governed predominantly by solution pH and Cu adsorbed on clay and OM surfaces. Primary and secondary minerals dissolve to initially supply solution Cu, which is then adsorbed, incorporated into microorganisms, and complexed by soluble organic compounds.
True
Most of the K used for fertilizer comes from:
A) mining K rich ores
B) natural gas
C) Western Sahara (Morocco)
D) particulate deposits
A) mining K rich ores
A significant “pool” of organically complexed Cu in equilibrium with solution Cu contributes to ___ ___ to plant roots.
Cu+2 diffusion
Interactions with Other Nutrients: ___ ___ can interact with Fe to induce Fe deficiency. (high Cu, Mn, P, induce low Fe)
Metal cations
Name four ways P ions are removed from the soil solution.
1) Precipitation reactions
2) Anion exchange reactions (outer sphere) – will be plant available
3) Reactions with Al or Fe oxide surfaces (inner-sphere) – fixation has taken place
4) Bond strength Ion
Ni is the latest nutrient to be established (in ____) as an essential nutrient to higher plants since the recognition of Cl- in 1954.
1987
Mainland ___ consumes the most P worldwide as of 2021
China
Organic Fe: Most animal wastes contain small quantities of ___-___ Fe. The major benefit of an organic waste application is increased OM and associated ___ effects.
plant-available
chelation
Plants take up P in the form of ___ & ___, sometimes as Soil organic phosphate as well. Mostly dependent upon pH of the soil will determine how P will be taken up.
H2PO4‐ (Low pH)
HPO4‐2(High pH)
Solution P is governed by the solubility of P minerals in the soil (Fig. 5.12). In acid soils Al and Fe phosphate minerals control solution P, while in neutral and calcareous soils Ca phosphate minerals are important. Availability of soluble phosphates is reduced by precipitation of insoluble Fe/Al or Ca phosphates.
True
Another K deficiency symptom is the ___ of stalks or stems, which causes ___ in small grains and stalk ___ in corn and sorghum.
weakening
lodging
breakage
P solution ___ in the presence of Fe, Al, Ca, K binding with P.
decreases
Mineral Zn content of the lithosphere is ≈ __ ppm, and Zn in soil ranges from 10 to 300 ppm (50 ppm average).
70
List five forms of Se present in soils.
- Selenides
- Elemental Se
- Selenites
- Selenates
- Organic Se
Inorganic Cu: The most common source is CuSO4. CuSO4 is soluble in water and is compatible with most fertilizers. Soil and foliar applications are both effective, but soil applications are more common. Effectiveness is increased by thoroughly mixing Cu fertilizers into the root zone or by banding near the seed row.
True
If a plant residue contains 5000 kg N and 10 kg P, how many grams of H2PO4- do you need to add to your soil to avoid net immobilization of P? (Hint: Assume C/P = 250 is taken as no net mineralization or immobilization)
5000 kg N/(10+X) kg P = 250
5000 = (250) (10+X)
5000 = 2500 + 250X
2500 = 250X
⸫ X = 10 kg P x (97/31) = 31.29
Organic Zn: Most animal wastes contain small quantities of plant-available Zn, especially ranging from ___% to ___%. With large manure-application rates, sufficient plant-available Zn can be provided.
0.01% to 0.05%
___ ___ is suspended phosphorus attached to particles that are filterable. A portion of this particulate P is also reactive orthophosphate and is typically analyzed along with the soluble orthophosphate.
Particulate phosphorus
The extent of inorganic ___ ___ depends on many factors, most importantly on soil pH
P fixation
Ni-deficient plants accumulate toxic levels of ___ in leaf tips because of reduced urease activity.
urea
Plant available Fe is governed primarily through ___ and ___ fractions in soils.
mineral and organic
S ___ is the conversion of organic S to inorganic SO4-2
mineralization
Ni has been demonstrated as essential to ___-___ crops.
small-grain
Plants absorb Ca+2 from the ___ ___, where mass flow and root interception are the primary mechanisms of Ca transport to the ___ ___.
soil solution
root surface
Soil pH: Solution Cu ___ with ___ pH due to decreased mineral solubility and increased adsorption.
decreases with increasing
Soil Solution Cu: Solution Cu concentration is usually low, ranging between ___ and ___ M.
10-6 and 10-8
Soil Solution Zn+2 is ___ (2-70 ppb), with more than half complexed by OM. Above pH 7.7, ZnOH+ becomes the most abundant species.
low
Exchangeable K on soil colloids is ___ ___.
readily available
P is active and mostly reactive that _______ to form compounds
phosphorylates
Soil solution K+ concentration optimum plant growth ranges from _ to __ ppm, depending on crop yield level.
1 to 10
___ Ca can also be foliar applied to crops.
Chelated
What are the three abundant minerals that are not mineral?
- C
- O
- H
Excess Mg occurs in soils formed from ___ ___ or influenced by ___ high in Mg.
serpentine minerals
groundwaters
Because of the mobility of plant Mg+2 and its ready translocation from ___ to ___ plant parts, deficiency symptoms often appear first on ___ leaves.
older to younger
lower
___ ___ ___(DIP): P desorbed from oxides or secondary minerals.
Dissolved inorganic P
K is essential for photosynthesis ___ ___ through leaf stomata
CO2 absorption
K is part of many plant cell components such as proteins and chlorophyll.
False
K deficiency symptom for corn leaf is identical to N. The chlorosis that appears on older leaves makes it impossible to differentiate.
False
Adsorbed Cu: ___ is chemically adsorbed to surfaces of clays; OM; and Fe, Al, or Mn oxides.
Cu+2
Solute Concentration in ___: For plants to absorb and use nutrients efficiently, nutrients accumulate in ___ until transported to growing plant organs.
Vacuoles
vacuoles
P content in biosolids ranges from 2 to 7%, with most present as ___ ___.
inorganic P
K in solution is ___
available
The eutrophication blamed on P in water bodies is highly exaggerated and scientifically false. Nitrogen is the cause of it all.
False
K is added to the soil solution by the ___ of ___ and cation exchange reactions as K+.
dissolution of minerals
Soil B exists in ___, adsorbed on ___ and Fe/Al ___ surfaces, combined with OM, and in soil solution.
minerals
clay
oxide
Organic B: B content in animal fertilizers ___ and may not provide ___ plant-available B to plants.
varies
sufficient
___ ___ is an important fraction is highly weathered, humid region soils containing large amounts of Al/Fe oxides.
Adsorbed SO4-2
The two dominant P species at normal soil pH are:
A) H2PO4-1 and PO4-3
B) H3PO4 and HPO4-2
C) H2PO4-1 and H2PO4-2
D) H3PO4 and H2PO4-1
C) H2PO4-1 and H2PO4-2
Name four nutrients in the soil that are immobile.
- P
- Fe+2
- Zn+2
- Mo
P mineralization from organic matter - (4‐10 lb/a/y) mineralized and plants need 10‐40 lb/a)
True
What are two methods of producing elemental Sulfur?
- By-byproduct from H2S gas
- By traditional mining
Name three plant benefits Co has for plants.
(1) acid, highly leached, sandy soils with low total Co
(2) highly calcareous soils
(3) some peaty soils
Plants absorb Mn+2 and ___ molecular weight organically complexed Mn.
low
Name 4 ways the soil solution is replenished?
- Dissolution
- Cation/Anion Exchange
- Desorption
- Organic Mineralization
___ leaf color is also associated with P deficiency
Purple
___, ___, ___, ___, ___ are the P forms in soil solution.
Adsorption, Absorption, Precipitation, Dissolution, Sorption
Name six symptoms Zn deficiencies that are widespread throughout the world and are identified.
- light green, yellow, or white areas between leaf veins
- eventual tissue necrosis in chlorotic leaf areas
- shortening of stem or stalk internodes
- small, narrow, thickened leaves
- premature foliage loss
- malformation of fruit, often with little or no yield
Diammonium phosphate (DAP) is produced by reacting 2 moles ___ with 1 mole of ___ ___.
ammonia
phosphoric acid
B is one of the ___ widely applied micronutrients.
most
K is essential for photosynthesis for the maintenance of electroneutrality during ___ in ___.
photophosphorylation in chloroplasts
In addition to most inorganic Mg salts, other materials containing synthetic Mg chelates (2-4% Mg) and natural organic complexing substances (4-9%) are suited for application as foliar sprays.
True
Buffer capacity is the resistance to change, therefore Soil P in solution is buffered as well. These are all ___-___
pH-dependent
P fertilizer may be ___ on the soil surface (liquid or dry) or it can be placed in a ___ ___.
broadcast
concentrated band
Name 4 ways P mineralization occurs.
1) Conversion of organic P to inorganic P
2) Organic P -> H2PO4-
3) Precipitation
4) Adsorption
As a primary constituent of ___, Mg+2 is essential for ___.
chlorophyll
photosynthesis
If a soil has 2% OM content and mineralization rate is 1%, calculate the quantity of P mineralized (lb P/afs). Assume humus (OM) contains 58%C, 5% N and 0.5% P; C:N:P = 100:10:1
- OM is about 5% N, 0.5% P and only 1% OM is mineralized.
- Total OM in an acre = 2x106 x 0.02 = 40,000 lb OM
- Total OM 1% mineralized 40,000 x 0.01 = 400 lb OM
- 5% of mineralized OM is N = 400 x 0.05 = 20 lb N/a
- 0.5% of mineralized OM is P = 400 x 0.005 = 2.0 lb P/a
Name five chemical inorganic sources of Cl.
- Ammonium chloride (NH4Cl)
- Calcium chloride (CaCl2)
- Magnesium chloride (MgCl2)
- Potassium chloride (KCl)
- Sodium chloride (NaCl)
Soil OM: Unavailable chelated Mn+2 compounds form, causing low Mn+2 availability in high-OM ___ and ___ soils.
peats and muck
Se in Plants: Se is not essential for plants, but it is required by animals. Plant species differ in Se uptake.
True
___ in crops grown on coarse-textured soils are generally more susceptible to S deficiency because these soils often have low OM contents.
Immobilization
Animal and municipal wastes contain ~_-_% Ca by dry weight and are excellent Ca sources.
2-5%
P at High pH – fixation mostly as ___ ___
calcium phosphates
Too much P is not good due to environmental impacts such as ___ from surface water runoff
eutrophication
___ (S2O3‐2), which can also be absorbed by plants, requires less energy by the plant in ___ to S‐2 and cysteine.
Thiosulfate
conversion
Organic P exists as inositol P, phospholipids, nucleic acids, and other compounds.
True