Section 1.2 Flashcards

1
Q

Element

A

Simplest type of matter that has unique chemical properties
- made up of one type of atom
- each element is unique
Ex. H,C, He, O, etc.

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2
Q

Molecule

A

Independent structures made up of at least 2 atoms BONDED together

Ex. H2, CH4, CH3OH

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3
Q

Compound

A

Occur when at least 2 different molecules or elements are bonded together

Ex. NaCl, NH4Cl

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4
Q

Mixture

A

2 or more chemical substances that are physically mixed/combined but NOT bonded together

Ex. Air → ~78% N2, ~20% O2, ~2% other

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5
Q

Chemical Reactions

A

Process that lead to a transformation (change) or chemical substance
→ New bonding
Ex. C + O2 → CO2

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6
Q

Atomic theory → Four important postulates (assumed existence or truth):

A

1) All matter consists of atom: atoms cannot be created or destroyed

2) Atoms of one element cannot be changed into atoms of another element (Pb → Ae - NOT possible)

3) Atoms of a given element are all the same (same mass and same internal structure)

4) compounds tended to form molecules in chemical reactions with specific ratios: N2 + 3H2 → 2NH3

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7
Q

Mass laws

A

Mass is conserved (cannot be created or destroyed)

A specific compound is composed of the same element in the same parts (fractions) by mass

Specific elements react to form compounds that combine with fixed masses that can be expressed as a ratio of small whole numbers

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8
Q

The Nuclear Atom Model

A

The process of uncovering the components that make up an atom involved a series of historical experiments:

Cathode Ray: electrical discharge consists of negatively charged particles
“Cathode ray particles” = electrons
- electrons can be generated from many different types of matter (electrons are a components in all matter)

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9
Q

Mass/Charge Ratio:

A

The mass of an electron is 1/1600 the mass of the lightest elements (H)

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10
Q

Charge of an Electron: determined by Millikan oil-drop experiment (1909)

A

1) Fine mist of oil spayed into apparatus
2) Oil droplets fall through hole in positively charged plate
3) X-ray knock electrons from surrounding air, which stick to droplets
4) Electrically charged plates influence droplet’s motion
5) Observer times droplet’s motion and controls electric field

The total charge on the oil droplets is always integer number of electron on the particle
Charge of electron = -1.602 x 10^-19C

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11
Q

Atomic Nucleus: Rutherford (1910) contradicted the “plum-pudding” model for atoms

A

Most of the atom is empty space
Nucleus is positively charged, diffuse in the center of the atom

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12
Q

Proton

A

P+
positively charged +1.602 x 10^-19 C
Weight: 1.673 x 10^-24 g = 1 AMU

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13
Q

Neutron

A

n
no charge
Weight: Weight: 1.675 x 10^-24 g = 1 AMU

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14
Q

Electron

A

e-
negatively charged particle
Weight: 9.109 x 10^-28 g =n 0 AMU

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15
Q

Atomic Number

A

Z
number of protons in an atom
defines the element

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16
Q

Mass Number

A

A
Number of protons + number of neutrons in AMU

17
Q

Elements are composed of…

A

single types of atoms, defined by a number of neutrons

18
Q

Anions

A

Gains electrons

19
Q

Cations

A

Losses Electrons

20
Q

Isotopes

A

if atoms have the same number of protons, but different number of neutrons

21
Q

Periodic Table

A

Arranged based on increasing Z, grouped together based on chemical properties

Can use the periodic table to predict properties and reactivity based on the electronic structure

22
Q

Chemical properties, structures, and reactivity

A

Determined by the behaviour of electrons

Bonding interactions, repulsive forces

23
Q

Classical mechanics

A

waves and particles behave differently, describing large objects

F=ma, p=mv

24
Q

Quantum Mechanics

A

small particles behave as both waves and particles (duality)
- Uncertainty about momentum and position
- Describe bases on probability

25
Q

Wave length

A

distance over which the wave repeats

26
Q

Frequency (v)

A

number of cycles the wave makes over unit of time

27
Q

Electromagnetic spectrum

A

As Wavelength increases, Frequency decreases