Section 1 Flashcards

1
Q

What happens to the system when the concentration has increased/decreased?

A

Increase - system consumes some of the added components
Decrease - system produces some of the removed components

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2
Q

What are the three ways to change pressure?

A

1) changing the conc of the gaseous element
2) adding an inert gas
3) changing the volume of a vessel

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3
Q

T/F - change in temperature is the only way to change the constant

A

True

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4
Q

What is necessary for a process to be spontaneous?

A

Suniv > o

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5
Q

What is a chemical equilibrium?

A

When the concentrations of the reactants and products have reached constant values

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6
Q

Qc is greater than Kc?

A

Reverse direction

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7
Q

Qc is less than Kc

A

Forward direction

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8
Q

What equilibrium constant reflects the solubility of compound?

A

Ksp

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9
Q

When Change of Free Energy<0 is spontaneous, what direction is it favouring?

A

Forward direction to form more products

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10
Q

When Change of Free energy>0, reaction is spontaneous and goes which direction?

A

Reverse direction

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11
Q

What is the common ion effect

A

Adding an ion “common” to an equilibrium system, causes reaction mixture to change

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12
Q

Boyle’s law

A

V = constant/p

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13
Q

Ideal gas law

A

PV=nRT

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14
Q

Charles’ law

A

V=constant x T

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15
Q

Avogadros law

A

V= constant x n

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16
Q

What is potential energy

A

Energy due to the position of the object relative to other objects

17
Q

Kinetic energy

A

Energy due to the motion of an object

18
Q

What is an open system

A

Exchanges both matter and energy with surroundings

19
Q

What is a closed system

A

Cannot exchange matter but can energy with surrounding

20
Q

What is an isolated system

A

Cannot exchange matter or energy with the surrounding

21
Q

Change of a Usys> 0

A

System ends up with more energy

22
Q

Change of Usys < 0

A

System lose energy

23
Q

Two ways the volume would expand in a system

A
  1. Increase the temp
  2. Decrease pressure
24
Q

What is the standard enthalpy of formation of a compound

A

^Hf’ - enthalpy change for the reaction that produces one mole of the compound in it’s standard state

25
Do question on page 41
26
What is intermolecular attraction?
Force between two molecules
27
Strength of molecules attractions depends on?
Size: larger molecules experience stronger forces/more interactions Shape:+ long thin experience stronger attraction
28
Kinetic model of gases
Explain macroscopic gas behaviour
29
Interparticle attractions is stronger when? (Real gases)
High pressure, low temp
30
Phase transition is?
Substance changes its phase without changing the chemical composition
31
Thermal energy is
Energy transferred between objects because of the potential and kinetic energy of particles
32
What is spontaneous change?
It can only occur under specific conditions without the continuous input of energy
33
What is Boltzmann constant
1.38x10-23 jkL-1
34
Entropy: phase changes
Increase in entropy
35
Entropy: dissolving solid to liquid
Increasing in entropy
36
Entropy: dissolving gas to liquid
Decrease in entropy
37
What is the r gas constant value
8.314jk-1mol-1