Second Law of Thermodynamics Flashcards

1
Q

Thermal energy reservoir

A

A hypothetical body with a relatively large thermal energy capacity that can supply or absorb finite amounts of heat without undergoing any change in temperature

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2
Q

Thermal source

A

A reservoir that supplies energy in the form of heat

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3
Q

Thermal sink

A

A reservoir that absorbs energy in the form of heat

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4
Q

Heat engines

A

Devices that convert heat to work

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5
Q

Heat engines typically: (4)

A
  1. Receive heat from a high-temperature source
  2. Convert part of this heat to work
  3. Reject the remaining waste heat to a low temperature sink
  4. Operate on a cycle
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6
Q

Thermal efficiency (heat engine)

A
  • A measure of performance for the heat engine

- Represents the fraction of heat input that is converted to net work output

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7
Q

Working fluid

A

The fluid to and from which heat is transferred to while undergoing a cycle

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8
Q

Second Law of Thermodynamics

A
  • A heat engine cannot operate by exchanging heat with a single reservoir (KP)
  • A refrigerator cannot operate without a net work input from an external sources (C)
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9
Q

Second Law (follow-ons)

A
  1. No heat engine can have a thermal efficiency of 100%
  2. For a power plant to operate in a cycle, the working fluid must exchange heat with the furnace (source) and the environment (sink)
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10
Q

Refrigerator

A

A device that transfers heat from a low-temp source to a high-temp sink
-heat engine in reverse

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11
Q

Coefficient of performance

A

Provides a measure of the efficiency of a refrigerator or heat pump

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12
Q

Heat pump

A
  • Device that transfers heat from a low-temp source to a high-temp sink
  • Operates on same cycle as refrigerator, but differs in objective
  • Objective: maintain a heated space at a high temp
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13
Q

Reversible process

A
  • A process that can be reversed without leaving a trace on the surroundings
  • Possible only when net heat and net work exchange between system and surroundings is zero
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14
Q

Types of reversible processes

A
  • Internally reversible
  • Externally reversible
  • Totally reversible
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15
Q

The Carnot Principles

A
  1. The efficiency of an irreversible heat engine is always less than a reversible one, operating between the same two reservoirs
  2. The efficiencies of all reversible heat engines operating between the same two reservoirs is the same
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