Second Law of Thermodynamics Flashcards
Thermal energy reservoir
A hypothetical body with a relatively large thermal energy capacity that can supply or absorb finite amounts of heat without undergoing any change in temperature
Thermal source
A reservoir that supplies energy in the form of heat
Thermal sink
A reservoir that absorbs energy in the form of heat
Heat engines
Devices that convert heat to work
Heat engines typically: (4)
- Receive heat from a high-temperature source
- Convert part of this heat to work
- Reject the remaining waste heat to a low temperature sink
- Operate on a cycle
Thermal efficiency (heat engine)
- A measure of performance for the heat engine
- Represents the fraction of heat input that is converted to net work output
Working fluid
The fluid to and from which heat is transferred to while undergoing a cycle
Second Law of Thermodynamics
- A heat engine cannot operate by exchanging heat with a single reservoir (KP)
- A refrigerator cannot operate without a net work input from an external sources (C)
Second Law (follow-ons)
- No heat engine can have a thermal efficiency of 100%
- For a power plant to operate in a cycle, the working fluid must exchange heat with the furnace (source) and the environment (sink)
Refrigerator
A device that transfers heat from a low-temp source to a high-temp sink
-heat engine in reverse
Coefficient of performance
Provides a measure of the efficiency of a refrigerator or heat pump
Heat pump
- Device that transfers heat from a low-temp source to a high-temp sink
- Operates on same cycle as refrigerator, but differs in objective
- Objective: maintain a heated space at a high temp
Reversible process
- A process that can be reversed without leaving a trace on the surroundings
- Possible only when net heat and net work exchange between system and surroundings is zero
Types of reversible processes
- Internally reversible
- Externally reversible
- Totally reversible
The Carnot Principles
- The efficiency of an irreversible heat engine is always less than a reversible one, operating between the same two reservoirs
- The efficiencies of all reversible heat engines operating between the same two reservoirs is the same