sac 1 Flashcards
carbon-based fuels & measuring changes in chemical reactions
define fuel
a fuel is a substance with stored energy that can be released relatively easily for use as heat or power.
define a renewable energy source
a source of energy that can be used indefinitely as the source can be replaced using natural processes in a short amount of time.
examples of renewable energy sources
biofuels (bioethanol, biogas, biodiesal), solar power, hydroelectricity, etc
define a nonrenewable energy source
a source of energy that cannot be replenished by natural processes faster than it is consumed and is in limited supply
examples of nonrenewable energy sources
fossil fuels (crude oil, coal, natural gas)
define photosynthesis
photosynthesis is a process that converts light energy to chemical energy as a source of glucose and oxygen for respiration in living things.
what is the photosynthesis equation
6CO2(g)+6H20(l) -(sunlight)> C6H12O6(aq)+6O2(g)
what is the equation of cellular respiration
6O2(g)+C6H12O6(aq) -> 6CO2(g)+6H2O(l)
compare exothermic and endothermic reactions
endothermic reactions absorb energy (in the form of heat) from surroundings, while exothermic reactions release heat energy to surroundings.
compare the chemical energy of the products and reactions in endothermic and exothermic reactions
endothermic reactions: the reactants have less chemical energy than the products
exothermic reactions: the reactants have more chemical energy than the products
compare the energy required to break bonds in the reactants and the energy released when products are formed in exothermic and endothermic reactions
exothermic reactions: the energy released when the bonds in the products form is greater than that of the energy required to break bonds in the reactants.
endothermic reactions: the energy released when the bonds in the products form is less than that of the energy required to break bonds.
compare enthalpy change in exothermic and endothermic reactions
endothermic reactions: enthalpy change is positive
exothermic reactions: enthalpy change is negative
how do you determine the limiting reactant/reagent
- calculate the moles of both reactants
- divide the moles of each reactant by the coefficient (requires balanced equation to do this)
- whichever reactant has the lower number is the limiting reagent
how is bioethanol produced
- produced from glucose and other sugars in a process called fermentation
- enzymes & microorganisms catalyse (facilitate) the reaction at 35 degrees celsius (any higher, and the enzymes & microorganisms will die)
reaction of fermentation of bioethanol
C6H12O6 (aq) -(yeast)> 2CH3CH2OH (aq) + 2CO2 (g)
what are the three main bioethanol feedstocks in Australia
- sugar cane
- wheat
- forest waste
what is distillation
a process that uses the different boiling points of liquids to separate them
is bioethanol carbon-neutral
- not completely, but more than ethanol that is obtained from crude oil
- a lot of energy is required to distil the ethanol solution, making its production not a carbon-neutral process
how is coal used to generate energy
- combustion of coal produces energy
C (s) + O2 (g) -> CO2 (g) - thermal energy produced from combustion heats a boiler, boiler produces steam, steam turns a turbine which generates electrical energy
how is petrol produced
- produced from crude oil
- use of distillation to produce petrol (octanes and other alkanes)
how is natural gas produced
- natural gas is found in deposits in the Earth’s crust
- naturally occurring in the Earth’s crust, but in limited quantities
what is the difference between complete and incomplete combustion
complete combustion:
- occurs when oxygen is plentiful
- only produces co2 and water
incomplete combustion:
- occurs when oxygen supply is limited
- when less oxygen is available, not all the carbon available can be converted into co2
- carbon monoxide (co) (and sometimes carbon) is produced instead of co2
what is heat of combustion of a fuel
the heat energy released when a specified amount of a substance burns completely in oxygen.
it is always a positive value.
what is enthalpy of combustion
found in thermochem eqns. always a neg value to reflect the nature of a combustion reaction (heat is released)