sac 1 Flashcards

carbon-based fuels & measuring changes in chemical reactions

1
Q

define fuel

A

a fuel is a substance with stored energy that can be released relatively easily for use as heat or power.

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2
Q

define a renewable energy source

A

a source of energy that can be used indefinitely as the source can be replaced using natural processes in a short amount of time.

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3
Q

examples of renewable energy sources

A

biofuels (bioethanol, biogas, biodiesal), solar power, hydroelectricity, etc

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4
Q

define a nonrenewable energy source

A

a source of energy that cannot be replenished by natural processes faster than it is consumed and is in limited supply

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5
Q

examples of nonrenewable energy sources

A

fossil fuels (crude oil, coal, natural gas)

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6
Q

define photosynthesis

A

photosynthesis is a process that converts light energy to chemical energy as a source of glucose and oxygen for respiration in living things.

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7
Q

what is the photosynthesis equation

A

6CO2(g)+6H20(l) -(sunlight)> C6H12O6(aq)+6O2(g)

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8
Q

what is the equation of cellular respiration

A

6O2(g)+C6H12O6(aq) -> 6CO2(g)+6H2O(l)

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9
Q

compare exothermic and endothermic reactions

A

endothermic reactions absorb energy (in the form of heat) from surroundings, while exothermic reactions release heat energy to surroundings.

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10
Q

compare the chemical energy of the products and reactions in endothermic and exothermic reactions

A

endothermic reactions: the reactants have less chemical energy than the products

exothermic reactions: the reactants have more chemical energy than the products

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11
Q

compare the energy required to break bonds in the reactants and the energy released when products are formed in exothermic and endothermic reactions

A

exothermic reactions: the energy released when the bonds in the products form is greater than that of the energy required to break bonds in the reactants.

endothermic reactions: the energy released when the bonds in the products form is less than that of the energy required to break bonds.

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12
Q

compare enthalpy change in exothermic and endothermic reactions

A

endothermic reactions: enthalpy change is positive

exothermic reactions: enthalpy change is negative

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13
Q

how do you determine the limiting reactant/reagent

A
  1. calculate the moles of both reactants
  2. divide the moles of each reactant by the coefficient (requires balanced equation to do this)
  3. whichever reactant has the lower number is the limiting reagent
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14
Q

how is bioethanol produced

A
  • produced from glucose and other sugars in a process called fermentation
  • enzymes & microorganisms catalyse (facilitate) the reaction at 35 degrees celsius (any higher, and the enzymes & microorganisms will die)
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15
Q

reaction of fermentation of bioethanol

A

C6H12O6 (aq) -(yeast)> 2CH3CH2OH (aq) + 2CO2 (g)

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16
Q

what are the three main bioethanol feedstocks in Australia

A
  • sugar cane
  • wheat
  • forest waste
17
Q

what is distillation

A

a process that uses the different boiling points of liquids to separate them

18
Q

is bioethanol carbon-neutral

A
  • not completely, but more than ethanol that is obtained from crude oil
  • a lot of energy is required to distil the ethanol solution, making its production not a carbon-neutral process
19
Q

how is coal used to generate energy

A
  • combustion of coal produces energy
    C (s) + O2 (g) -> CO2 (g)
  • thermal energy produced from combustion heats a boiler, boiler produces steam, steam turns a turbine which generates electrical energy
20
Q

how is petrol produced

A
  • produced from crude oil
  • use of distillation to produce petrol (octanes and other alkanes)
21
Q

how is natural gas produced

A
  • natural gas is found in deposits in the Earth’s crust
  • naturally occurring in the Earth’s crust, but in limited quantities
22
Q

what is the difference between complete and incomplete combustion

A

complete combustion:
- occurs when oxygen is plentiful
- only produces co2 and water

incomplete combustion:
- occurs when oxygen supply is limited
- when less oxygen is available, not all the carbon available can be converted into co2
- carbon monoxide (co) (and sometimes carbon) is produced instead of co2

23
Q

what is heat of combustion of a fuel

A

the heat energy released when a specified amount of a substance burns completely in oxygen.
it is always a positive value.

24
Q

what is enthalpy of combustion

A

found in thermochem eqns. always a neg value to reflect the nature of a combustion reaction (heat is released)

25
% eff formula
% efficiency = (q into water/q into fuel) * 100
26
advantages of bioethanol
- able to be replaced in short amounts of time with natural processes (renewable) - more carbon neutral than fossil fuels as co2 is absorbed when plants photosynthesise - can be produced from some waste material (such as forest waste)
27
disadvantages of bioethanol
- bioethanol can't be used on its own as a fuel, so it needs to be blended with fossil fuels - some food stocks are used to produce bioethanol (wheat, sugarcane), this could cause food shortages - lower energy content than regular petrol due to ethanol already being partially oxidised
28
what is biogas
- gas produced via anaerobic digestion of waste from bacteria
29
what is the composition of biogas
mostly methane, then carbon dioxide, then everything else