S1.4 Flashcards

the mole

1
Q

1 mole = ?

A
  • = 6.02⋅10^-23 elementary entities (atoms, ions, …)
  • equal to the number of atoms in a 12g of 12C ⇒ M(C) = 12 g/mol
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2
Q

Avogadro constant

A

NA = 6.02 ⋅ 10^-23 mol^-1
= number of constituent particles in one mole of a substance

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3
Q

amount of substance

A

fixed number of particles ⇒ n = [mol]

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4
Q

relative atomic mass

A
  • weighted average of the atomic masses and their relative abundances of an isotope
  • ratio of the mass of a certain atom to 1/12 of the mass of a 12C atom
  • Ar = [/]
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5
Q

relative molecular mass

A
  • combination of Ar values for individual atoms or ions
  • the ratio of the mass of a molecule or other multiatomic species to 1/12 of the mass of a 12C atom
  • Mr = [/]
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6
Q

why was the 12C isotope used to find Ar?

A

because it is highly stable and C does not appear in many isotopes

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7
Q

what is 1 amu?

A

= atomic mass unit
= m(C)/12

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8
Q

molar mass

A

mass of one mole of a substance
M = [g/mol]

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9
Q

calculating amount of substance

formulas (mass, number of particles)

A

n = m/M = N/NA

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10
Q

empirical vs molecular formula

A
  • empirical formula ⇒ the simplest ratio of atoms of the different elements that are present in the substance
  • molecular formula ⇒ simple multiple of the empirical formula, specifies the actual number of atoms of each element in one molecule or formula unit of the substance
  • molecular formula = n(empirical formula)
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11
Q

hydrate vs anhydrate

A

Hydrate = an ionic compound that contains water molecules in its structure (X ⋅ yH2O)
Anhydrate = the substance that remains after the water is removed from a hydrate (X)

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12
Q

solution

def

A

= homogeneous mixtures of two or more components, consisting of a solvent (dissolver) and one or more solutes (dissolves)

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13
Q

concentrated vs diluted solution

A

concentrated solution ⇒ ratio of solute to solvent is high
dilute solution ⇒ ratio of solute to solvent is low

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14
Q

molar concentration

A

[solute] = n(solute) : V(solution) = [mol/dm3 = M]

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15
Q

mass concentration

A

γ(solute) = c(solute) = m(solute) : V(solution) = [g/dm3]

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16
Q

mass percent

A

w(solute) = m(solute) : m(solution) = [%]

17
Q

volume percent

A

vol% = V(solute) : V(solution) = [%]

18
Q

stock vs standard solution

A

Stock solution = prepared concentration solutions kept for future dilutions
Standard solution = solution with a known and precise concentration, used for analytical purposes

19
Q

dilution

A

w1m1 = w2m2
[X]1V1 = [X]2V2
m(solute)1 = m(solute)2

20
Q

spectrophotometry

A
  • T = I : IO
  • A = log10 (IO : I) = log10 (T-1)

T (transmittance), A (absorbance), I (transmitted light - input), IO (incident light - output)

21
Q

Beer-Lambert law

A

A = εlc

A (absorbance), ε (absorptivity), l (optical path length), c (molar concentration)