Rxns & Reagents Flashcards
1
Q
Alcohol + H2SO4
A
alkene + H2O
E2
2
Q
Alcohol + NaH
A
O- Na+ + H2
3
Q
Alcohol + HCl in ZnCl2
A
R-Cl + H2O
SN1: 2* and 3* ROH
SN2: methyl and 1* ROH
4
Q
Alcohol + HBr
A
R-Br + H2O
SN1: 2* and 3* ROH
SN2: methyl and 1* ROH
5
Q
Alcohol + SOCl2 in pyridine
A
R-Cl
SN2
6
Q
Alcohol + PBr3
A
R-Br
SN2
7
Q
Alcohol + TsCl in Pyridine
A
R-OTs
8
Q
Alcohol +
[1]NaH
[2]CH3CH2Br
A
[1]R-O- Na+
[2]R-O-CH2CH3
9
Q
Alcohol +
[1]TsCl
[2]NaSH
A
[1]R-OTs
[2]R-SH
10
Q
Alcohol + NaCl
A
no reaction
11
Q
Alcohol + NaHCO3
A
no reaction
12
Q
Alcohol + POCl3 in pyridine
A
alkene
13
Q
CH-C-OTs + :Nu-
A
OTs -> Nu
14
Q
CH-C-OTs + B:
A
alkene + TsO-
15
Q
Ether + H-X(2 equiv)
[X=Br or I]
A
R-X + R’-X + H2O
SN1: 2* and 3* R
SN2: CH3 and 1* R
