RP4: Identification of cations and anions Flashcards

1
Q

How do you test for group 2 metal cations?

A
  1. Place 10 drops of a group 2 compound in a test tube (0.1moldm-3)
  2. Add 10 drops of 0.6 moldm-3 NaOH to test tube. Record any observations.
  3. Continue to add NaOH so it is in excess. Record any observations.
  4. Repeat with other group 2 compounds.
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2
Q

How would you distinguish between calcium bromide and strontium chloride?

A
  1. Place 10 drops of BaCl2 in a test tube.
  2. Add 10 drops of sulfuric acid and record observations.
  3. Continue to add sulfuric acid until in excess. Record observations.
  4. Repeat for other the group 2 compounds.
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3
Q

How do you test for ammonium ions?

A
  1. Place 10 drops of NH4Cl into a test tube.
  2. Add 10 drops of NaOH solution. Shake.
  3. Warm the solution in the test tube.
  4. Test the gas released with damp red litmus paper.
  5. It if goes blue, ammonium ions are present.
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4
Q

How do you test for Group 7 ions?

A
  1. Add nitric acid and silver nitrate. Record observations.

2. To samples of this solution,, add dilute and then concentrated ammonia.

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5
Q

How do you test hydroxide ions?

A
  1. Test a 1cm depth of solution in a test tube with red litmus paper or universal indicator.
  2. Record your observations.
  3. Sodium hydroxide will turn damp red litmus paper blue.
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6
Q

How do you test for carbonate ions?

A
  1. Put 2cm3 of Calcium Hydroxide into a test tube.
  2. Add 3cm2 of Sodium Carbonate into another test tube then add an equal volume of dilute HCl.
  3. Immediately put in delivery tube with open end into the Calcium Hydroxide test tube.
  4. If Calcium Hydroxide goes cloudy, carbonate ions were present in the other test tube.
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7
Q

How do you test for Sulfate ions?

A

Add HCl and BaCl2 to the suspected Sulfate solution.

Sulfate ions present = white precipitate of BaSO4 will form

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8
Q

What is the order of testing ions?

A

Carbonate, Sulfate, Halide

Prevents false positive results occurring.

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