revision Flashcards
what is phase creation + example
creation of a second phase which is immiscible with the feed e.g. distillation
what is phase addition?
for a homogeneous mixture, a second immiscible phase must be developed, MSA
disadvantages of MSA?
additional separator needed, contamination, MSA needs making up, difficult design
what is separation by barrier + example
use of a microporous or non-porous membrane e.g. osmosis
what is separation by a solid agent + example
uses a solid mass-separating agent e.g silica gel
what is separation by force field/gradient + example
makes use of the response of different molecules/ions to force fields e.g. gravity
what things do we consider when choosing a separation method?
feed + product conditions, property differences, characteristics of operation, economics
a light key product has…?
high relative volatility, low boiling point
a high key product has…?
low relative volatility, high boiling point
percentage recovery =
amount of i in product / amount of i in feed
percentage purity =
amount of desired product / total amount of product
split fraction =
amount of first product in product stream / amount of desired product in feed stream
split ratio =
amount of product 1 / amount of product 2
split ratio for 2 product streams =
SF / (1 - SF)
separation factor (or power) =
(conc i in product 1 / conc i in product 2) / (conc of j in product 1 / conc of j in product 2)