Relative atomic and molecular masses, the mole and the Avogadro constant Flashcards

1
Q

Concentration (the amount of solute in moles dissolved per 1dm3 of solution) =

A

Moles/Volume

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2
Q

Number of Moles Calc =

A

mass/Mr

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3
Q

1 Moles. concentration (mol/dm1)

A

moles (mol) / volume (dm3)

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4
Q
  1. cm3 - dm3
A

/1000

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5
Q
  1. moles (mol)=
A

Mass (g) / Mr (Ar)

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6
Q
  1. 1 mole of an atom =
A

Ar in g

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7
Q
  1. 1 mol of a molecule =
A

Mr in grams

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8
Q
  1. it takes 32.10cm3 of HCl, concentration of 0.0150 mol dm-3, to complete react with 25.00cm3 of sodium hydroxide solution. Calc the conc of NaOH solution.

HCl +NaOH

A

c = mol/vol.

moles HCl = 0.150 x (32.10/1000) = 4.815 x 10-3
therefore moles of NaOH = 0.004815
Conc of NaOH = 0.004815 / (25/1000) = 0.193 moldm-3

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9
Q
  1. (NH4)2SO4 + 2NaOH
    3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH

a. Moles in (NH4)2SO4 in 3.14g

A

3.14/Mr (132.1) = 0.0237698 = 0.0238

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10
Q
  1. (NH4)2SO4 + 2NaOH
    3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH

b. Moles in NaOH

A

ratio= 1:2
moles 0.0238x2= 0.0476

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11
Q
  1. (NH4)2SO4 + 2NaOH
    3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH

c. Conc of NaOH used

A

conc= moles/vol = 0.0476/(39.3/1000) = 1.21 mol dm-3

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12
Q

1.Zn0+2HCl
0.0830 of ZnO added to 100cm3 of 1.20 mol dm-3 HCl. Calc maximum mass of ZnCl

A

mols HCl = conc x vol = 1.20 x 100/1000 = 0.12 therefore moles of ZnCl2 = 0.06
mass ZnCl2 = moles x Mr = 0.06 x (65.4+(35.5x2))
=8.184=8.18g

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13
Q

2 Ideal Gas.

A

One Mole of Any Gas = 24dm3 (100KPa, 298K)

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14
Q
  1. Formula
A

p(pressure Pa) V (Volume m3)=n (no.mols)R(Gas constant)T(K)

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15
Q
  1. How do you convert Celsius to Kelvin formula?
A

Celsius to Kelvin: Kelvin = Celsius + 273

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16
Q
  1. 4NH3+502 - 4NO + 6H2O
    total volume of 4.31m3 at 25C and 100kPa
    Calc Moles of NO produced
    (R= 8.31J K-1mol-1)
A

Pv=nRT therefore n = Pv/rt = 100000(100KPa x1000)x4.31/8.31x(25+273) = 174
Moles = 174 = total gasses
Moles of NO= (174/10(4+6)) X 4 = 69.6 Of NO

17
Q
  1. B203 + 3C + 3Cl2 - 2BCl3 + 3CO
    Boron oxid reacted completely with C and Cl. Two Gases total volume of 5000cm3 at pressure of 100kPa and Temp of 298K. Calc Mass. (R=8.31J)
A

cm3 - dm3 = divide by 1000
pV=nRT therefore pv/RT= 100000(x1000 to Pa)x(5000/1000000) / 8.13 x 298 = 0.2019
Moles of B2O3 = 0.2019/5 = 0.0403815
Moles=Mass/Mr - Mass of B2O3: moles x Mr = 0.040 x ((10.8x2)+(16x3)) = 2.81g

18
Q
  1. MgNO3 secomposed to produce 0.402mol of gas. Calc volume thats would occupy at 333K and 1.00x105Pa. (R=8.31J)
A

Pv=nRT therefore v = nRT/P = 0.402 x 8.31 x 333 / 1x10^5 = 0.0111242 m3 x 1000 = 11.1dm3

19
Q
  1. cm3 - dm3 - m3 =
A

divide by 1000

20
Q
  1. Theoretical And percentage yield
A

Percentage yield - what we actually get
Theoretical - Max we could get if the experiment was 100% perfect

21
Q

30g of C3H8 burns in the air to produce 70g OF CO2. calc theoretical and % of CO2.

A

1C3H8 (limiting)+ 3O2 (excess) - 4H20 + 3C02
1. Identify Limiting and Excess
C3H8 - 3C + 8H
= 3(12)+8(1) = 44.094g/mol
30g C3H8/1 x 1mol C3H8/44.094gC3H8 x 3moCO2/1molC3H8

22
Q

Percentage yield =

A

Actual / theoretical x 100%

find no of moles
then divide them both
x 100

23
Q

Moles in Masses =

A

use Moles = n/Mr and Vol (dm3) = n x 24 dm3 (“Molecular Gas Volume”)

24
Q

triangles

A

mass = mol x Mr
Volume = mol x 24 dm3
conc = n/v

25
Q

Empirical and molecular

A

mass:
divide by Mr = moles
divide by smallest no.

26
Q

1 mole

A

contains 6.02 x 10^23

27
Q

Calculate the mass of sodium hydroxide, NaOH, required to prepare 250 cm3 of a 0.200 mol dm-3 solution

A

Step 1: Find the number of moles of NaOH needed from the concentration and volume:

number of moles = concentration (mol dm-3) x volume (dm3)
n = 0.200 mol dm-3 x 0.250 dm3
n = 0.0500 mol
Step 2: Find the molar mass of NaOH

M = 22.99 + 16.00 + 1.01 = 40.00 g mol-1
Step 3: Calculate the mass required

mass = moles x molar mass
mass = 0.0500 mol x 40.00 g mol-1 = 2.00 g

28
Q

volumetric solutions

A

1- Weigh out a precise amount of the solid
2- Add to a small volume of water & pre - dissolve the solid (glass rode)
3-

29
Q

How to make a standard solution

A
30
Q

Concentration is usually expressed in one of three ways:

A

moles per unit volume
mass per unit volume
parts per million

31
Q

The concentration of a solution is the amount of solute dissolved in a solvent to make 1 dm3 of solution
The solute is the substance that dissolves in a solvent to form a solution
The solvent is often water
A concentrated solution is a solution that has a high concentration of solute

A
32
Q

A dilute solution is ?

A

a solution with a low concentration of solute

33
Q

A concentrated solution?

A

is a solution that has a high concentration of solute

34
Q

The concentration of a solution is?
The solvent is often water

A

the amount of solute dissolved in a solvent to make 1 dm3 of solution
The solute is the substance that dissolves in a solvent to form a solution