Relative atomic and molecular masses, the mole and the Avogadro constant Flashcards
Concentration (the amount of solute in moles dissolved per 1dm3 of solution) =
Moles/Volume
Number of Moles Calc =
mass/Mr
1 Moles. concentration (mol/dm1)
moles (mol) / volume (dm3)
- cm3 - dm3
/1000
- moles (mol)=
Mass (g) / Mr (Ar)
- 1 mole of an atom =
Ar in g
- 1 mol of a molecule =
Mr in grams
- it takes 32.10cm3 of HCl, concentration of 0.0150 mol dm-3, to complete react with 25.00cm3 of sodium hydroxide solution. Calc the conc of NaOH solution.
HCl +NaOH
c = mol/vol.
moles HCl = 0.150 x (32.10/1000) = 4.815 x 10-3
therefore moles of NaOH = 0.004815
Conc of NaOH = 0.004815 / (25/1000) = 0.193 moldm-3
- (NH4)2SO4 + 2NaOH
3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH
a. Moles in (NH4)2SO4 in 3.14g
3.14/Mr (132.1) = 0.0237698 = 0.0238
- (NH4)2SO4 + 2NaOH
3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH
b. Moles in NaOH
ratio= 1:2
moles 0.0238x2= 0.0476
- (NH4)2SO4 + 2NaOH
3.14g of ammonium sulphate reacted completely with 39.30cm3 of NaOH
c. Conc of NaOH used
conc= moles/vol = 0.0476/(39.3/1000) = 1.21 mol dm-3
1.Zn0+2HCl
0.0830 of ZnO added to 100cm3 of 1.20 mol dm-3 HCl. Calc maximum mass of ZnCl
mols HCl = conc x vol = 1.20 x 100/1000 = 0.12 therefore moles of ZnCl2 = 0.06
mass ZnCl2 = moles x Mr = 0.06 x (65.4+(35.5x2))
=8.184=8.18g
2 Ideal Gas.
One Mole of Any Gas = 24dm3 (100KPa, 298K)
- Formula
p(pressure Pa) V (Volume m3)=n (no.mols)R(Gas constant)T(K)
- How do you convert Celsius to Kelvin formula?
Celsius to Kelvin: Kelvin = Celsius + 273
- 4NH3+502 - 4NO + 6H2O
total volume of 4.31m3 at 25C and 100kPa
Calc Moles of NO produced
(R= 8.31J K-1mol-1)
Pv=nRT therefore n = Pv/rt = 100000(100KPa x1000)x4.31/8.31x(25+273) = 174
Moles = 174 = total gasses
Moles of NO= (174/10(4+6)) X 4 = 69.6 Of NO
- B203 + 3C + 3Cl2 - 2BCl3 + 3CO
Boron oxid reacted completely with C and Cl. Two Gases total volume of 5000cm3 at pressure of 100kPa and Temp of 298K. Calc Mass. (R=8.31J)
cm3 - dm3 = divide by 1000
pV=nRT therefore pv/RT= 100000(x1000 to Pa)x(5000/1000000) / 8.13 x 298 = 0.2019
Moles of B2O3 = 0.2019/5 = 0.0403815
Moles=Mass/Mr - Mass of B2O3: moles x Mr = 0.040 x ((10.8x2)+(16x3)) = 2.81g
- MgNO3 secomposed to produce 0.402mol of gas. Calc volume thats would occupy at 333K and 1.00x105Pa. (R=8.31J)
Pv=nRT therefore v = nRT/P = 0.402 x 8.31 x 333 / 1x10^5 = 0.0111242 m3 x 1000 = 11.1dm3
- cm3 - dm3 - m3 =
divide by 1000
- Theoretical And percentage yield
Percentage yield - what we actually get
Theoretical - Max we could get if the experiment was 100% perfect
30g of C3H8 burns in the air to produce 70g OF CO2. calc theoretical and % of CO2.
1C3H8 (limiting)+ 3O2 (excess) - 4H20 + 3C02
1. Identify Limiting and Excess
C3H8 - 3C + 8H
= 3(12)+8(1) = 44.094g/mol
30g C3H8/1 x 1mol C3H8/44.094gC3H8 x 3moCO2/1molC3H8
Percentage yield =
Actual / theoretical x 100%
find no of moles
then divide them both
x 100
Moles in Masses =
use Moles = n/Mr and Vol (dm3) = n x 24 dm3 (“Molecular Gas Volume”)
triangles
mass = mol x Mr
Volume = mol x 24 dm3
conc = n/v
Empirical and molecular
mass:
divide by Mr = moles
divide by smallest no.
1 mole
contains 6.02 x 10^23
Calculate the mass of sodium hydroxide, NaOH, required to prepare 250 cm3 of a 0.200 mol dm-3 solution
Step 1: Find the number of moles of NaOH needed from the concentration and volume:
number of moles = concentration (mol dm-3) x volume (dm3)
n = 0.200 mol dm-3 x 0.250 dm3
n = 0.0500 mol
Step 2: Find the molar mass of NaOH
M = 22.99 + 16.00 + 1.01 = 40.00 g mol-1
Step 3: Calculate the mass required
mass = moles x molar mass
mass = 0.0500 mol x 40.00 g mol-1 = 2.00 g
volumetric solutions
1- Weigh out a precise amount of the solid
2- Add to a small volume of water & pre - dissolve the solid (glass rode)
3-
How to make a standard solution
Concentration is usually expressed in one of three ways:
moles per unit volume
mass per unit volume
parts per million
The concentration of a solution is the amount of solute dissolved in a solvent to make 1 dm3 of solution
The solute is the substance that dissolves in a solvent to form a solution
The solvent is often water
A concentrated solution is a solution that has a high concentration of solute
A dilute solution is ?
a solution with a low concentration of solute
A concentrated solution?
is a solution that has a high concentration of solute
The concentration of a solution is?
The solvent is often water
the amount of solute dissolved in a solvent to make 1 dm3 of solution
The solute is the substance that dissolves in a solvent to form a solution