Refrigeration Flashcards
3 types of Refrigeration
Chilling and freezing
- final temperature
- type of heat removed.
Chilling
0°C to 8°C
sensible heat
Freezing
~ below freezing point often -18°C.
~ crystallisation of water
~ latent heat
~ more energy and time
Refrigeration – Why?
molecular mobility depressed
- chemical reactions slow
- biological processes slow
microorganisms or enzymes
* depresses their activity
Retards spoilage
* But cannot improve initial quality
Not permanent preservation
* definite shelf life
Reliable cold chain and Hurdle principle
Refrigeration and Food Quality
Temperature influence enzymatic spoilage
- Enzyme activity strongly slowed by refrigeration
- but not totally eliminated
- Inactivate enzymes -> blanching
- Enzymatic activity considerable technological
significance - Desirable?
- Undesirable
Temperature influence microorganisms’ growth
[i.e. mesophiles optimal 30 - 45C minimium 5- 10C]
*Effect of storage temperature on microbial load of food
Temperature and biologically active tissue
* Respiration
Respiration rate
estimated using rates of O2 consumption and CO2 evolution. Oxidation of Glucose:
C6 H12 O6 + 6O2 –> 6CO2 + 6H2O +Q
[Q= heat of respiration]
relationship between temperature and biologically active tissue [at 2 stages]
Most important cause of deterioration of fruits &
vegetables during storage:
- ‘Shelf life of fresh produce inversely related to rate of
respiration’ - Rate of respiration closely related to temperature
[10°C increase -> 2- to 4-fold increase rate of respiration] - chill injury
- Post-harvest ripening [Ethylene]
- Control the rate of ripening with refrigeration
- Exothermic process
- Refrigeration load required
respiration of fruit & veg
avacado/ berries/ aspargus/ cauliflower [High respiration]
> Banana/ tomato/ carrot
> Nuts/ grapes/ apple/ citrus [low respiration]
Sensible heat
the heat when added or subtracted from material changes their temperature and it can be sensed
Latent heat
the heat required to change the physical state of materials at constant temperature
[food mostly consists of water and also contains lots of soluble materials]
Soluble materials effects on freezing?
- Soluble materials slow down the movement of water molecules, and the freezing occurs at lower temperature
- 1 mol of soluble matter will decrease (lower) the freezing point by ~1°C
Freezing points for Fruits and vegetables & Meat and fish
Fruits and vegetables = -0.8 to -2.8 °C
Meat and fish = -0.6 to -2.8 °C
Freezing processing principle
change in sensible heat (& heat respiration) to lower the temperature of a food to the freezing point.
A substantial amount of energy is needed to remove latent heat, form ice crystals and hence to freeze foods.
Freezing curve
If the temperature is monitored at the thermal centre of a food as heat is removed, a characteristic curve is btained [slide 19]
- AS – food cooled to below its freezing point θf . At S the water remains liquid: super-cooling may up to 10ºC below freezing point.
- SB - temperature rises rapidly to the freezing point as ice crystals begin to form and latent heat of crystallization is released.
- BC – Heat removed from food at same rate as before, but it is latent heat being removed as ice forms and temperature remains almost constant. The freezing pt depressed by increasing solute concentration in unfrozen liquor & temperature falls slightly. major part of the ice is formed
- CD - One of the solutes becomes supersaturated and
crystallizes out. The latent heat of crystallization is released and the temperature rises to the eutectic temperature for that solute. - DE - Crystallization of water and solutes continues. The total time tf taken (the freezing plateau) is determined by the rate at which heat is removed.
- EF - The temperature of the ice–water mixture falls to the temperature of the freezer. A proportion of the water remains unfrozen at the temperatures used in commercial freezing; the amount depends on the type and composition of the food and the temperature
eutecticum
When the concentration of the solute in the non-frozen portion reaches a certain level, that entire portion solidifies as though it were a pure substance. This new solid phase is called ‘ eutecticum’.
freezing point
temperature at which a minute crystal of ice exists in equilibrium with the surrounding water
Freezing: Theory for Ice Crystal Form
~freezing point
~ Nucleus of water molecules must be present
~ Nucleation
[ Homogeneous nucleation ; heterogeneous nucleation]
~ Supercooling
~High rates of heat transfer
[Large number of small ice crystals]
~ Different for types of food and different pre-freezing treatments.
~ Rate controlled by the rate of heat transfer for the
majority of the freezing plateau
Freezing Theory for Solute Concentration
Increase in solute:
- by changes in the pH, viscosity, surface tension, redox
potential of the unfrozen liquor
- Eventually individual solutes reach saturation point
EUTECTIC TEMPERATURE
- Lowest Temp at which a crystals of individual
solute exists in equilibrium with the unfrozen liquor and
ice
[ Meat -50 to -60ºC; Bread -70ºC]
No further concentration of solutes as solution freezes
Lowest eutectic temperature for food
Commercial foods not frozen to such low temperatures so unfrozen water is therefore always present.
Below point E
- glass transition
- glass encompassing ice crystals
- protection
Freezing: Effect on Food
Cell damage by ice crystal growth
Negligible changes to pigments, flavours or nutritionally important components (preparation / storage)
Plant v Animal Origin:
~ Meats -> flexible fibrous structure
~ Fruits & vegetables -> rigid cell structure
~ Extent damage -> size of the crystals
Raw material quality, pre-freezing treatments
Rate of freezing effects on Food
Slow freezing allows large size crystal formed and damaged food cell
rapid freezing allows equal size crystal contribution formed, less damage for food
Frozen Storage: Effect on Food
Enzymes not inactivated
Variable effect on micro-organisms:
[-4ºC to -10ºC]: greater lethal effect on microorganisms
[-15ºC to -30ºC]: lesser lethal effect on microorganisms
Varying resistance:
~ vegetative cells of yeasts, moulds and gram negative bacteria
~ gram-positive bacteria and mould spores
~ bacterial spores
Vegetables blanched
lower temp allow better colour and flavour preservation:
~ colour change detected sooner [for same storage temp] than flavour
~ colour change detected at lower storage temp [for same storage time] than flavour
Main Effect on Frozen Stored Food
Degradation of pigments
- chlorophyll -> pheophytin (Veg)
- Precipitation salts -> pH change -> anthocyanins (fruit)
Loss of vitamins
- Water-soluble vitamins lost at sub-freezing temperatures (fruit/veg)
- Drip loss (meat/fish)
Residual enzyme activity:
- Polyphenoloxidase activity -> browning (Fruit & Veg)
- Lipoxygenases -> off-flavours and off-odours, degrades of carotene (Fruit & Veg)
- Proteolytic and lipolytic activity -> texture and flavour (meat)
Oxidation of lipids:
- slowly at -18ºC
- off-odours and off-flavours
Recrystallisation Effect on Frozen Stored Food
-> Quality loss
Physical changes to ice crystals
~ Shape/ Size / Orientation
Migratory recrystallisation
~ Increase in average size & reduction in the number of crystals
~ Growth of larger crystals at expense of smaller crystals.
↑ Temp -> melts ice crystals -> ↓ size -> ↑ water vapour pressure:
~ moisture moves to area lower vapour pressure
~ Area dehydrated
~ No new nuclei formed – larger ice crystals
!! Avoid unstable temp change !!
Plank’s Equation limitation
This equation works well for freezing of pure water but can result in large errors for freezing time of food materials