Refractometer Flashcards

1
Q

When can refraction be observed?

A

incident ray striking a boundary surface (not perpendicular!) btw 2 different media

→ direction change of transmitted ray = refraction

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2
Q

What is the absolute refractive index?

A

considers only 1 medium, thus ratio of the speed of light in vacuum (c) to that in the medium (c1)

n1 = c/c1

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3
Q

What is the relative refractive index?

A

explains how much the incident light ray is refracted, thus the ratio of the indices of refraction of the 2 media

n21 = n2/n1

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4
Q

Explain the relationship btw frequency, wavelength and speed of light in vacuum and in the medium.

How do they change?

On what else does the refractive index depend?

A
  1. due to different indices of refraction: change in c
    * *BUT:** f remains constant
  2. because c = λ * f: change in λ

⇒ larger index of refraction → smaller wavelength

ALSO: dependend on temperature

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5
Q

What does Snell’s law describe?

A

describes the relationship btw angles of incidence and refraction, when light passes through a boundary between 2 different media

sin α/sin β = c1/c2 = n2/n1 = n21

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6
Q

What is the consequence of Snell’s law of refraction?

How does the refracted ray behave when the angle of the incident ray changes?

A

from less dense to more dense medium

increasing angle of incidence α → increasing angle of refraction β

⇒ largest angle of incidence (grazing ray) → largest angle of refraction (critical angle)

BUT always: α > β

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7
Q

What is the grazing ray?

A

angle of incidence traveling along the boundary surface of the 2 media (~ 90°)

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8
Q

What is the critical angle?

Formula.

A

largest angle of refraction (βc) corresponding to the grazing ray

n21 = n2/n1 = 1/sin βc

⇒ dependent on ratio of refractive indices (= relative refractive index)

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9
Q

What is dispersion?

Why does it happen?

A

decomposition of white light due to change in wavelength

→ rays of different colors are refracted at different angles (e.g. on prisms, and lenses)

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10
Q

What is an Amici prism?

A

compound prism that restores white light from the light that was spread out into colors

→ causing smear of the rim of the Snell’s window

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11
Q

What is Snell’s window?

A

when diffuse light is refracted → rays form a light cone in the denser medium of half-aperture angle equal to βc

(REMEMBER: βc depends on relative refractive index of the 2 media)

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12
Q

How can the refractive index of a solution be calculated?

A

refractive index depends on concentration

nsolution = n0 + constant * conc.

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13
Q

What is a Abbe refractometer used for?

What are its components?

A

measurement of the index of refraction (hence concentration) of a transparent liquid

components:

  • mirror
  • measuring + illuminating prism
  • turnable Amici prism with a knob for color comp.
  • telescope
  • microscope with scale

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14
Q

What are the conditions for a refractometer to work?

A
  • nmeasuring solution < nmeasuring prism
  • transparent liquid
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15
Q

How does an Abbe refractometer work?

A
  1. ​measuring solution put into slit btw 2 prisms
  2. illuminating white light projected to illuminating prism by a mirror
  3. diffused on rough surface of illuminating prism → grazing rays produced in solution
  4. Amici prism adjusted by color compensator knob → sharp shadowline
  5. shadowline centered in telescope
  6. scale calibrated in microscope→ refractive index can be read
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