Refractometer Flashcards
When can refraction be observed?
incident ray striking a boundary surface (not perpendicular!) btw 2 different media
→ direction change of transmitted ray = refraction
What is the absolute refractive index?
considers only 1 medium, thus ratio of the speed of light in vacuum (c) to that in the medium (c1)
n1 = c/c1
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What is the relative refractive index?
explains how much the incident light ray is refracted, thus the ratio of the indices of refraction of the 2 media
n21 = n2/n1
Explain the relationship btw frequency, wavelength and speed of light in vacuum and in the medium.
How do they change?
On what else does the refractive index depend?
- due to different indices of refraction: change in c
* *BUT:** f remains constant - because c = λ * f: change in λ
⇒ larger index of refraction → smaller wavelength
ALSO: dependend on temperature
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What does Snell’s law describe?
describes the relationship btw angles of incidence and refraction, when light passes through a boundary between 2 different media
sin α/sin β = c1/c2 = n2/n1 = n21
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What is the consequence of Snell’s law of refraction?
How does the refracted ray behave when the angle of the incident ray changes?
from less dense to more dense medium
increasing angle of incidence α → increasing angle of refraction β
⇒ largest angle of incidence (grazing ray) → largest angle of refraction (critical angle)
BUT always: α > β
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What is the grazing ray?
angle of incidence traveling along the boundary surface of the 2 media (~ 90°)
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What is the critical angle?
Formula.
largest angle of refraction (βc) corresponding to the grazing ray
n21 = n2/n1 = 1/sin βc
⇒ dependent on ratio of refractive indices (= relative refractive index)
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What is dispersion?
Why does it happen?
decomposition of white light due to change in wavelength
→ rays of different colors are refracted at different angles (e.g. on prisms, and lenses)
What is an Amici prism?
compound prism that restores white light from the light that was spread out into colors
→ causing smear of the rim of the Snell’s window
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What is Snell’s window?
when diffuse light is refracted → rays form a light cone in the denser medium of half-aperture angle equal to βc
(REMEMBER: βc depends on relative refractive index of the 2 media)
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How can the refractive index of a solution be calculated?
refractive index depends on concentration
nsolution = n0 + constant * conc.
What is a Abbe refractometer used for?
What are its components?
⇒ measurement of the index of refraction (hence concentration) of a transparent liquid
components:
- mirror
- measuring + illuminating prism
- turnable Amici prism with a knob for color comp.
- telescope
- microscope with scale
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What are the conditions for a refractometer to work?
- nmeasuring solution < nmeasuring prism
- transparent liquid
How does an Abbe refractometer work?
- measuring solution put into slit btw 2 prisms
- illuminating white light projected to illuminating prism by a mirror
- diffused on rough surface of illuminating prism → grazing rays produced in solution
- Amici prism adjusted by color compensator knob → sharp shadowline
- shadowline centered in telescope
- scale calibrated in microscope→ refractive index can be read
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