Redox reactions Flashcards
What are the 3 most electronegative elements?
- Fluorine
- Oxygen
- Nitrogen
Which atom in a compound is electronegative and which is electropositive?
Non-metals tend to be more electronegative while metals tend to be more electropositive.
In a compound which atom has the negative/positive oxidation number?
More electronegative atom -negative
Less electronegative atom
-positive
How to tell which element is more electronegative?
Electronegativity increases from left to right across a period and decreases down the group. (more electronegative, more strongly the atom is able to attract bonding electrons towards itself)
Define oxidation in terms of electron transfer.
Oxidation is the loss of electrons from an element, compound or ion.
Define oxidation in terms of oxidation state.
Oxidation is the increase in oxidation state of an element, compound or ion.
Define reduction in terms of transfer of electrons.
Reduction is the gain of electrons from an element, compound or ion.
Define reduction in terms of oxidation state.
Reduction is the decrease in oxidation state of an element, compound or ion.
What equations are not redox equations?
- Neutralisation
- Precipitation
- Thermal decomposition of carbonates
- Acid + carbonate
How does H2O2 function as an agent (oxidising/reducing)?
With a strong oxidising agent (MnO4^-), H2O2 is a reducing agent.
With a strong reducing agent (I^-), H2O2 is an oxidising agent.
Reaction of iodine with sodium thiosulfate.
I2 + 2S2O3^2- –> 2I^- + S4O6^2-
Reaction of iodine ion solution with potassium iodide.
2MnO4^- + 16H^+ + 10I^- –> 2Mn^2+ + 8H2O + 5I2