Redox reactions Flashcards

1
Q

Define Oxidation

A
  1. gain of oxygen or electronegativity element
  2. Loss of elements
  3. Increase in O.S
  4. Loss of hydrogen or electropositive element
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2
Q

Define Reduction

A
  1. loss of oxygen or electronegativity element
  2. gain of elements
  3. decrease in O.S
  4. gain of hydrogen or electropositive element
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3
Q

What is oxidation number ?

A

denotation of oxidation state in a compound of a given element

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4
Q

What are the rules for oxidation number?

A
  1. Alkali metals = +1
    Alkali earth metals = +2
  2. Oxygen = -2
    peroxide = -1
    superoxide = +1
  3. Hydrogen =+1
    with metals =-1
  4. Florine = -1
  5. Sum of all O.S = 0 in compounds
    Sum of all O.S = Charge in ions
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5
Q

How can you find the highest O.S of any compound?

A

Group number - 10

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6
Q

What is/are the conditions for an combination reaction to be a redox reaction?

A

For a reaction to be combination as well as redox at least one of the element need to be in their elemental state

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7
Q

How is decomposition reaction different from combination reaction

A

Decomposition reaction involves in breaking down of compounds. It Produced an elemental compound

Combination is the formation of compound from one or more elemental compound

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8
Q

Define displacement reaction

A

Displacement reaction replacement of ions or atoms in the compound to form a new compound
1. metal displacement
2. Non-metals displacement

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9
Q

Why does F not show disproportionation reaction?

A

F doesn’t show disproportionation reaction because it has only one oxidation state that is -1

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10
Q

What is disproportionation reaction?

A

disproportionation reaction is where the same element undergoes oxidation are reduction at the same time

H2O2 = H2 = O2

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11
Q

What is the oxidation state for the following molecules
1. S in H2S4O6
2. Br in Br3O8
3. O in H2O2
4. O in HO2F
5. S in H2SO5
6. Cr in CrO5

A
  1. +5,0
  2. +6,+4
  3. -1
  4. -1,+1
  5. +6
  6. +6
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12
Q

How to balance redox reaction with half electron method?

A
  1. identify oxidation and reduction half reaction
  2. Balance all other atoms
  3. Balance O by adding H20
  4. Balance H by adding H+
  5. Balance the charge by adding electron
  6. All the reaction (make sure that he electrons get canceled )
  7. Add OH- on both sides for basic medium
    no of OH- = no of H+
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13
Q

How to balance redox reaction with oxidation number method?

A
  1. identify oxidation and reduction reaction
    2.Balance the charge
  2. Balance all other atoms
  3. Balance O by adding H20
  4. Balance H by adding H+
  5. Add OH- on both sides for basic medium
    no of OH- = no of H+
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14
Q

What are the application of Redox reaction?

A

There are two applications of redox reaction :
1. Titration
2. Cells

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15
Q

How is redox reaction used in Titration?

A

It can used to find the end point of the reaction:
1. Self indicators : like MnO4- tell the end point by losing their colour
2.The solution getting coloured by getting colour at end point like Cr2O7-
3. Use of I- in the reaction that gives a dark Blue colour

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16
Q

What is a salt bridge? What are its uses?

A

A us shape tube that is placed between the beakers containing jelly like sustenance .
Uses:
1. Provides a medium of contact
2. Provides a potential difference
3. Maintain neutrality in the system

17
Q

What is a redox couple?

A

Redox couple is where the oxidising and reducing form take part in the reaction
Zn2+|Zn||Cu2+|Cu

18
Q

Equivalence point

A

A point where oxidant and Reductant are equal by mole stoichiometry

19
Q

Electrode potential

A

potential associated with each electrode

At 297K becomes standard electrode potential

20
Q

Increasing order of reduction

A

Li, K, Ba,Ca Mg, Al , Zn , Cr, Fe, Co, Ni, Pb, H, Cu, Hg, Ag, Au, Pt, I2, Br2, Cl2, F2

21
Q

How are you convert F- into F2?

A

By the use of electrolysis

22
Q

Reducing agent

A

itself gets oxidized

23
Q

Oxidation agent

A

itself gets reduced