redox reactions Flashcards

1
Q

describe reduction in terms of electrons

A

gain of electrons

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2
Q

describe reduction in terms of oxidation number

A

decrease in oxidation number

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3
Q

describe oxidation in terms of electrons

A

loss of electrons

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4
Q

describe oxidation in terms of oxidation number

A

increase in oxidation number

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5
Q

state the oxidation number for an element

A

0

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6
Q

state the oxidation number for combined H

A

+1

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7
Q

state the oxidation number for combined O

A

-2

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8
Q

state the oxidation number for an ion

A

equal to the ion’s charge

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9
Q

describe an oxidising agent

A
  • takes electrons from another species (oxidises it)
  • is reduced
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10
Q

describe a reducing agent

A
  • adds electrons to another species (reduces it)
  • is oxidised
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11
Q

state the oxidising and reducing agent in the following equation:

2Ag+ + Cu –> Cu2+ + 2Ag

A

Ag = oxidising agent
Cu = reducing agent

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12
Q

how are redox equations balanced?

A

by balancing the electrons across both equations

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13
Q

balance the following redox equations

H2O2 + 2e- –> 2OH-
Cr3+ + 8OH- –> CrO4 2- + 4H2O + 3e-

A

3H2O2 + 6e- –> 6OH-

2Cr3+ + 16OH –> 2CrO4 2- + 8H2O + 6e-

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14
Q

describe the process for balancing half equations

A
  1. write species before and after reaction
  2. balance atoms except O and H
  3. balance O with H2O and H with H+
  4. balance charges with e-
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15
Q

balance the following equation

Fe2+ –> Fe3+

A

Fe2+ –> Fe3+ + e-

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16
Q

balance the following equation

MnO4- –> Mn2+

A
  1. MnO4- –> Mn2+
  2. MnO4- –> Mn2+ + 4H2O
    MnO4- + 8H+ –> Mn2+ + 4H2O
  3. MnO4- + 8H+ + 5e- –> Mn2+ + 4H2O
17
Q

in a redox half equation, where are the electrons positioned for reduction

A

on the left

18
Q

in a redox half equation, where are the electrons positioned for oxidation

A

on the right

19
Q

describe the process for combining half equations into a full ionic equation

A
  • balance electrons
  • cancel electrons
  • combine
20
Q

state the oxidation number for oxygen in fluorides

A

+2

21
Q

state the oxidation number for oxygen in peroxides

A

-1

22
Q

state the oxidation number for hydrogen in metal hydrides

A

-1

23
Q

define oxidation number

A

the charge that a molecule would have, if the electrons in each bond belonged to the more electronegative element