Redox Potentials Flashcards

1
Q

Do reductants tend to have a more or less positive reduction potential than oxidants?

A

More negative

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2
Q

Which directions do electrons flow in?

A

The direction of increasingly positive reduction potential

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3
Q

What is redox potential?

A

The ability of a molecule or ion to donate electrons or accept electrons expressed quantatively

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4
Q

What represents redox potential?

A

E

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5
Q

What is Em?

A

The E where [oxidised]=[reduced]

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6
Q

What conditions are used in a standard hydrogen electrode?

A
  • 1 atm
  • 298k
  • 1M solutions
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7
Q

What pH is a standard hydrogen electrode measured at?

A

0

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8
Q

What is the redox potential of SHE?

A

0V

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9
Q

What pH are most standard reduction potentials measured at in biochemistry?

A

pH7

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10
Q

A hydrogen electrode at pH7 has a standard potential of what compared to SHE?

A

-0.43 V

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11
Q

If E0’ is negative which side of the equation is favoured?

A

Left side

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12
Q

If E0’ is positive which side of the half equation is favoured?

A

The right side

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13
Q

What type of reactions are half equations always written as?

A

Reductions

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14
Q

What is a redox pair?

A

The reactants in a redox reaction

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