Redox II Flashcards

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1
Q

why do electrochemical cells use redox reaction

A

the electron transfer between products creates a flow of electrons.

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2
Q

what is the flow of charged particles called

A

an electrical current that flows between electrodes in the cell

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3
Q

what do most electrochemical cell consist of

A

two solutions, metal electrodes and a salt bridge

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4
Q

what is a salt bridge

A

a tube of unreactive ions that move between solutions to carry the flow of charge

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5
Q

what does each half cell have

A

cell potential which indicate how it will react

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6
Q

What is SHE

A

measuring standard for half cell potential as it has a cell potential of 0.00v

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7
Q

what are cell potentials measured compared to

A

to SHE under standard conditions

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8
Q

what does positive potential mean

A

substance more easily reduced and will gain electrons

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9
Q

what does negative potential mean

A

substance more easily oxidised and lose electrons become more stable

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10
Q

what are the standard conditions

A

solutions of 1.0mol dm-3 conc
a temperature of 298k
100 kPa pressure

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11
Q

what does a cell consists

A

HCl, Hydrogen gas, platinum electrodes

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12
Q

why are plantium electrodes used

A

metallic, so conduct electricity, but inert so doesn’t interfere with reaction

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13
Q

how should you represent cell in simplified way

A

The half-cell with the most negative potential goes on the left.

The most oxidised species from each half-cell goes next to the salt bridge.

A salt bridge is shown using a double line.

State symbols are always included.

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14
Q

How do you calculate Emf

A

E(right) - E(left)

most positive potential minus the most negative potential

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15
Q

what does it mean if overall cell potential is positive

A

more spontaneous and favourable

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16
Q

what does increasing concentration do to emf

what does increasing pressure do to emf

A

more positive as fewer electrons are produced

more negative as more electrons are produced

17
Q

limitations of using SHE is

A

does not take kinetics into account
may be feasible but occur at such a slow rate that doesn’t even occur.

18
Q

what do electrode potentials that are very positive mean

A

better oxidising agents

19
Q

when is a disproportionation reaction feasible

A

overall E(cell) is positive

20
Q

what does a fuel undergo in fuel cells

A

combustion in oxygen and energy released generate a voltage

21
Q

what does hydrogen fuel cells do

A

uses continuous supply of hydrogen and oxygen from air to generate a continuous current

22
Q

waste product of hydrogen fuel cell

A

water so environmentally friendly

23
Q

downside of hydrogen fuel cell

A

high flammability of hydrogen and expensive to produce

24
Q

why do negative standard electrode potentials exist use mg as an example

A

magnesium atoms in metal will lose electrons and break away into the solution as Mg2+

the electrons will be left behind on magnesium giving it a negative charge attracting magnesium ions from solution to recombine with electrons and re form magnesium atoms. Mg is reactive so leave excess electrons

equilibrium reached

25
Q

what does a very positive electrode potential value suggest

A

very good reducing agent as release electrons readily

26
Q
A
27
Q
A