redox and electrolysis Flashcards
define the term “redox reaction”
a reaction where both oxidation and reduction take place
define the term ‘oxidation’
gain of oxygen
loss of electrons
loss of hydrogen
define the term ‘reduction’
loss of oxygen
gain of electrons
gain of hydrogen
define the term ‘oxidant’ and mention an example
oxidizing agent ( a substance which itself is reduced)
KMnO4 (potassium manganate) purple to colourless
define the term ‘reducing agent’ and mention a few examples
a substance which itself is oxidized
CO, CO2, H2, KI (colourless to orange brown)
define the term ‘electrolysis’
the breakdown of an ionic compound (1)
when molten or aqueous (1)
by the passage of electricity (1)
in an electrolysis cell, which two components are part of the ‘external circuit’
wire and electrodes
the cathode represents the ___ charge whereas the ____ represents the opposing charge
negative (1)
anode (1)
electrodes are…
rods that carry charge
or
rods that allow the passage of electricity
why must the electrolyte be molten or aqueous?
to have free moving ions to carry the charge
why must electrodes be made of graphite or platinum?
due to them being inert and good conductors
fluorine is _____ in colour at gas state
pale yellow
bromine is _____ in colour in gas state
orange brown
iodine is ____ in colour in gas state
purple
chlorine is ____ in colour in gas state
yellowish green
oxygen, hydrogen and nitrogen are ___ in colour in gas state
colourless
copper is a ___ metal (colour)
reddish brown
gold is a ___ metal (colour)
yellow
negatively charged ions move towards the ___
anode
positively charged ions move towards the ____
cathode
the current in electrolyte are (ions/electrons)
ions
the current in electrodes are (ions/electrons)
electrodes
why can ionic compounds conduct electricity when molten or aqueous?
due to free moving ions which carry charges
products of electrolysis of molten lead bromide
cathode: lead metal
anode: bromine gas
electrolyte: used up
products of the electrolysis of molten calcium iodide
cathode: calcium metal
anode: iodine gas
electrolyte: used up
give the observations seen after the electrolysis of molten zinc chloride
deposition of silvery grey metal at cathode
bubbles of yellowish green gas at anode
bulb lights up
give the products of the electrolysis of conc. aqueous sodium chloride
cathode: hydrogen gas
anode: chlorine gas
electrolyte: sodium hydroxide
give the products and observations of the electrolysis of dilute copper sulfate
products
cathode: copper metal
anode: oxygen gas
electrolyte: sulfuric acid
observations
deposition of reddish brown metal at cathode
bubbles of colourless gas at anode
bulb lights up
blue colour of electrolyte fades
define the term ‘electroplating’
a process where a thin layer of one metal is put on top of another object by electrolysis
give two uses of electrolysis
- protects metal from corrosion (rusting)
- gives an attractive and shiny appearance