reagents Flashcards by Natasha Martino

Q

1) BH3, THF 2) H2O2/NaOH

A

makes alkenes into alcohols (add OH anti Mark and H)

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

1) KMNO4 2) NaOH cold

A

add 2 OH (not with alkynes)

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

alkenes to alkanes

A

Pd/C, H2

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

m-CPBA

A

alkenes to epoxides

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

Hg(OAc)2, H2O + NaBH4

A

add OH to most substit. C

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

add OH to most substit. C

A

Hg(OAc)2, H2O + NaBH4

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

alkyne to trans alkenes

A

NaNH3

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

1) O3 2) H2O2

A

ketones or aldehydes (every C-H = C-OH)

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

deprotonates

A

NaH

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

forms chlorides by Sn2

A

SOCl2 and pyridine

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

NaNH3

A

alkyne to trans alkenes

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

Pd/C, H2

A

alkenes to alkanes

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

alkenes to epoxides

A

m-CPBA

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

SOCl2 and pyridine

A

forms chlorides by Sn2

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

OsO4

A

add 2 OH groups

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

add 2 OH groups

A

OsO4

Q

alkynes to alkenes

A

lindlar’s catalyst and H2

Q

lindlar’s catalyst and H2

A

alkynes to alkenes

Q

makes alkenes into alcohols (add OH anti Mark and H)

A

1) BH3, THF 2) H2O2/NaOH

Q

NaH

A

deprotonates

Q

1) HBr 2) KOtBu/HOtBu

A

alcohol to alkene

Q

ketones or aldehydes (every C-H = C-OH)

A

1) O3 2) H2O2

Q

alcohol to alkene

A

1) HBr 2) KotBu/HOtBu

Q

TsCl pyridine

A

swap OH with OTs

Q

DMSO, NaCN

A

swap X with CN (reverse stereochem)

Q

1) KMNO4 2) acid heat

A

cleaves alkenes to ketones and carboxylic acids

Q

swap OH with OTs

A

TsCl pyridine

Q

swap X with CN (reverse stereochem)

A

DMSO, NaCN

Q

cleaves alkenes to ketones and carboxylic acids

A

1) KMNO4 2) acid heat