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CHEM 266 > Reagents > Flashcards

Reagents Flashcards

1
Q

HBr

A

Hydrohalogenation

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1
Q

dilute H2SO4

A

Hydration

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2
Q

Hg(OAc)2

A

Oxymercuration-Demercuration

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3
Q

BH3, H2O2, NaOH

A

Hydroboration-Oxidation

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4
Q

Cl2, CCl4

A

Halogenation (Alkene)
Halogention, amount must be specified (Alkyne)

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5
Q

Cl2, H2O

A

Halohydrin Formation

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6
Q

mCPBA, CH2Cl2

A

Epoxidation

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7
Q

H2, Pt

A

Hydrogenation (Alkene)
Hydrogenation to Alkane (Alkyne)

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8
Q

OsO4, Na2SO3, H2O

A

Dihydroxylation

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9
Q

HBr, H2O2

A

Anti-Markovnikov Hydrohalogenation (Radical)

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10
Q

O3 or KMnO4, H2O2

A

Oxidative Cleavage (Oxidative) (Alkene)

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11
Q

O3 or KMnO4, Zn/HOAc

A

Oxidative Cleavage (Reductive) (Alkene)

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12
Q

H2, Lindlar’s Catalyst

A

Hydrogenation to Cis-Alkene

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13
Q

H2, Na2NH3

A

Hydrogenation to Trans-Alkene

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14
Q

O3 or KMnO4

A

Oxidative Cleavage (Alkyne)

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15
Q

Mg, Et2O

A

Grignard Formation

16
Q

H2 (excess), Pt

A

Reduction of ketones and aldehydes to carboxylic acid

17
Q

NaBH4 or LiAlH4, MeOH

A

Reduction of ketones and aldehydes to carboxylic acid

18
Q

KMnO4 or K2Cr2O7 (Jones), NaOH (heat)

A

Oxidation of Alcohol to Carboxylic Acid or Ketone

19
Q

PCC, CH2Cl2

A

Oxidation of Alcohol to Aldehyde or Ketone

20
Q

ZnCl2, HCl

A

Conversion of Alcohol into better leaving group

21
Q

TsCl, Pyridine

A

Conversion of Alcohol into better leaving group

22
Q

PBr3 or SOCl2

A

Alcohol converted to halide

23
Q

-OCH3 or NaOH/halide or NaH/DMSO/halide

A

Ether Synthesis

24
Q

NaOH, H2O

A

Cyclic Ether Synthesis

25
Q

1) NaCN, 2) H3O+

A

Epoxide Reaction (Basic Conditions)

26
Q

1)MeOH, H2SO4

A

Epoxide Reaction (Acidic Conditions)

27
Q

HBr (Excess)

A

Ether Cleavage

28
Q

Br2, hv

A

Radical Reaction

CHEM 266 (2 decks)

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