Reagents Flashcards

1
Q

What can make a triple bond go to a single bond adds amine

A

H2/Pd/Pt

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What can turn OH into ketone can form carboxylic acids and form ketones

A

KMnO4, NaOH, H2O, heat
2) H3O+, H20

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What removes double bond cleavage and dehydrate the reaction

A

H2SO4/heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is syn addition of OH
takes a double bond cleaves and adds an OH

A

(1)OsO4
Pyridine
(2) NaHSO3
H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What converts Single bond to triple bond

A

3eq NaNaH2 NH4Cl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is a Strong acid to deprotonate the OH

A

H3PO4,H20

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is an anti-markovnikov addition of OH cleaves double bonds and gives OH to the structure

A

BH3, THF, H2O2, NaOH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Splits the molecule into two molecule and makes ketones and aldehydes

A

O3,CH2Cl2, Zn HOAc

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What replaces OH with Cl

A

SOCl2, pyridine

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Goes from single to double bond

A

H2/NiB

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is a molecule that replaces OH with Br in an Sn2 style reaction

A

PBr3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

replaces halogen with NH2

A

NaNH2 and NH3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What cleaves double bond and gives an OH molecule?

A

1) Hg(OAc)2,H2O,THF
2) NaBH4, NaOH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Breaks a bond down from triple to double

A

H2, Lindlar’s catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What eliminates and degrades down a bond

A

1) H2SO4
2) CH2=C(CH3)2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Acid base reactions to break down bonds

A

1) NaNH2 3eq NH3
2) NH4Cl

17
Q

breaks double bonds and creates OH groups

A

nBu4NF, THF

18
Q

Breaks off substituents and goes from single bond to double bond

A

LDA

19
Q

Can make a double bond to an ester

A

mCPBA

20
Q

Breaks bond with bromine to make double bond

A

1)Na or Li in NH3
2) NH4Cl

21
Q

Breaks an OH and makes an ester plus a Si or breaks an OH bond to OTES

A

TESCl and a 3^degrees amine

22
Q

Subs substituents and gives Br

A

HBr,H2O2

23
Q

Can be used to convert an alcohol into an alkyl chloride

A

HCl, ZnCl2

24
Q

goes from double bond to a Br and an OH group

A

Br2, H2O

25
Q

Goes from a double bond to have a I substituents

A

HI

26
Q

Can change single bonds to one double bonds

A

t-BuO

27
Q

removes H from OH group

A

NaH

28
Q

Changes stuff to have 2 Br’s

A

Br2, CCL4

29
Q

Adds an aldehyde and removes a double bond

A

O3,CH2Cl
Zn HOAc

30
Q

Changes 2 aldehydes to 2 OH groups

A

LiAlH4
H3O+

31
Q

changes only one aldehyde group to OH

A

NABH4, Ethanol

32
Q

Changes OH to an aldehyde

A

PCC

33
Q

adds the metal to the substituent

A

Mg,Et2O, heat

34
Q

Reduction from ketone to OH

A

NaBH4,EtOH

35
Q

Oxidative Cleavage

A

KMnO4,HO-,H2O

36
Q

eliminates substituent and gives double bond

A

NH2