Reagents Flashcards
What can make a triple bond go to a single bond adds amine
H2/Pd/Pt
What can turn OH into ketone can form carboxylic acids and form ketones
KMnO4, NaOH, H2O, heat
2) H3O+, H20
What removes double bond cleavage and dehydrate the reaction
H2SO4/heat
What is syn addition of OH
takes a double bond cleaves and adds an OH
(1)OsO4
Pyridine
(2) NaHSO3
H2O
What converts Single bond to triple bond
3eq NaNaH2 NH4Cl
What is a Strong acid to deprotonate the OH
H3PO4,H20
What is an anti-markovnikov addition of OH cleaves double bonds and gives OH to the structure
BH3, THF, H2O2, NaOH
Splits the molecule into two molecule and makes ketones and aldehydes
O3,CH2Cl2, Zn HOAc
What replaces OH with Cl
SOCl2, pyridine
Goes from single to double bond
H2/NiB
What is a molecule that replaces OH with Br in an Sn2 style reaction
PBr3
replaces halogen with NH2
NaNH2 and NH3
What cleaves double bond and gives an OH molecule?
1) Hg(OAc)2,H2O,THF
2) NaBH4, NaOH
Breaks a bond down from triple to double
H2, Lindlar’s catalyst
What eliminates and degrades down a bond
1) H2SO4
2) CH2=C(CH3)2
Acid base reactions to break down bonds
1) NaNH2 3eq NH3
2) NH4Cl
breaks double bonds and creates OH groups
nBu4NF, THF
Breaks off substituents and goes from single bond to double bond
LDA
Can make a double bond to an ester
mCPBA
Breaks bond with bromine to make double bond
1)Na or Li in NH3
2) NH4Cl
Breaks an OH and makes an ester plus a Si or breaks an OH bond to OTES
TESCl and a 3^degrees amine
Subs substituents and gives Br
HBr,H2O2
Can be used to convert an alcohol into an alkyl chloride
HCl, ZnCl2
goes from double bond to a Br and an OH group
Br2, H2O
Goes from a double bond to have a I substituents
HI
Can change single bonds to one double bonds
t-BuO
removes H from OH group
NaH
Changes stuff to have 2 Br’s
Br2, CCL4
Adds an aldehyde and removes a double bond
O3,CH2Cl
Zn HOAc
Changes 2 aldehydes to 2 OH groups
LiAlH4
H3O+
changes only one aldehyde group to OH
NABH4, Ethanol
Changes OH to an aldehyde
PCC
adds the metal to the substituent
Mg,Et2O, heat
Reduction from ketone to OH
NaBH4,EtOH
Oxidative Cleavage
KMnO4,HO-,H2O
eliminates substituent and gives double bond
NH2
