Reading Flashcards

1
Q

What can a mismatch of thermal expansivity lead to?

A

Internal residual stresses -> strong effects of mechanical behaviour

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2
Q

What is hardness dependent on that stiffness and density is not?

A

Microstructure

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3
Q

Name common reinforcements for PMC, MMC and CMC

A

PMC - Carbon, glass, aramid
MMC - ceramics
CMC - metallic + ceramic

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4
Q

Why is tensile strength data v.approximate espec in ceramic materials?

A

Ceramics are sensitive to presence of flaws ∴ higher values of strength measured = due to fibres containing few large flaws

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5
Q

Why is axial stiffness and strength high in CF

A

Graphene has a very strong bonding within the plane so alignment in carbon fibres -> stiffness and strength

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6
Q

Describe CF anisotropic behaviours in terms of thermal expansivity and conductivity

A

Higher expansivity in transverse

Higher conductivity in axial direction

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7
Q

Why are composites usually bad under transverse loading?

A

Uniaxial nature means that in transverse loading, the matrix which is usually weak is taking most of the load

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8
Q

Describe how processing temperature affects the property of CF

A
  • lower temp —> less dense, less stiff but strong

- higher temp —> more dense, stiff

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9
Q

Describe the effects that adding ‘network-modifying’ (lower valence) oxides e.g. Na2O to a quartz will have

A

1) reduces Tg = easier to deform/draw at low temps
BUT reduces max use temp?

2) stiffness is affected

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10
Q

What is a quartz?

A

Pure silica glass

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11
Q

Where are flaws predominantly located in brittle materials?

A

Surface

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12
Q

How can dimensions of brittle fibres affect strength?

A

Reduction in diameter —> stronger ∵ finer flaws

But practicality difficulties can arise if D is too small

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13
Q

Does the toughness of a composite depend on the toughness of the fibre and/or the matrix?

A

No

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14
Q

What are some limitations of polymeric fibres?

A
  • relatively low stiffness

- limited tolerance of heat

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15
Q

Describe attractive properties of SiC

A
  • low density
  • High stiffness
  • good thermal conductivity + stability
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16
Q

Describe oxide fibres generally (alumina and silica)

A
  • good resistance to oxidative degradation (problem for other fibres when used @ High temp)
  • used for High temp insulation @ 50/50
  • alumina fibres w/lower silica content = greater resistance to high temp, higher stiffness + strength
17
Q

What are whiskers?

A

Elongated single crystals

18
Q

Why do whiskers have v. High strengths?

A

∵ there are soo fine and have no GB

19
Q

What are some disadvantages to whiskers?

A
  • expensive to produce
  • difficult to handle ∵ = readily become airborne = health hazard
  • difficult to disperse within a matrix
  • despite high tensile strength, toughness likely to be v.low
20
Q

What’s the difference between particles and whiskers?

A
  • cheaper
  • easier to process and handle
  • can be used as a density reduction
21
Q

What are the main mechanisms of interfacial bonding

A

1) wetting (van der Waals forces)
2) diffusional processes
3) chemical reactions
4) mechanical keying