Reactions with Alkenes Flashcards
1
Q
formation of an alkene from a halogen
A
strong base
2
Q
C=C——–X
A
HX, adds markovnikov
3
Q
C=C——X,X
A
X2, Anti
4
Q
C=C——X2,OH
A
X2,H2O, markovnikov, anti
5
Q
C=C——X, OR
A
X2, ROH, markovnikov, anti
6
Q
C=C——OH
A
H2O,H2SO4……Hg(OAc)2,H2O and NaBH4…….BH3 and NaOH, H2O2
BH3=non-mark.
7
Q
C=C——OH,OH
A
KMnO4,NaOH,H2O……….OsO4 and NaHSO3,H2O
8
Q
C=C—C=O(oxidative cleavage)
A
O3 and Zn, H3O+……..KMnO4,H2O or H3O+
9
Q
Alkene to Alkane
A
H2, Pd/C
10
Q
C=C—–cyclopropane
A
CH2N2…..CHCl3,KOH……CH2I2,Zn(Cu)
11
Q
Formation of an Alkene from an alcohol
A
H2SO4 or H3PO4 and heat