Reactions of metal ions in aqueous solution Flashcards

1
Q

What is the aqueous ion with iron (II) and its colour?

A

[Fe(H2O)6]2+ / green solution

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2
Q

What is the aqueous ion with iron (III) and its colour?

A

[Fe(H2O)6]3+ / purple solution

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3
Q

Why might the iron (III) aqueous ion change colour - from what to what?

A

[Fe(H2O)6]3+ / purple solution to [Fe(H2O)5(OH)]2+ / yellow-brown

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4
Q

What is the aqueous ion with copper (II) and its colour?

A

[Cu(H2O)6]2+ / blue solution

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5
Q

What is the aqueous ion with aluminium (II) and its colour?

A

[Al(H2O)6]3+ / colourless solution

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6
Q

What happens when [Fe(H2O)6]2+ reacts with a little NaOH? Complex and colour?

A

Fe(H2O)4(OH)2(s) /

green ppt goes brown on standing in air

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7
Q

What happens when [Fe(H2O)6]3+ reacts with a little NaOH? Complex and colour?

A

Fe(H2O)3(OH)3(s) /

brown ppt

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8
Q

What happens when [Cu(H2O)6]2+ reacts with a little NaOH? Complex and colour?

A

Cu(H2O)4(OH)2(s) /

blue ppt

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9
Q

What happens when [Al(H2O)6]3+ reacts with a little NaOH? Complex and colour?

A

Al(H2O)3(OH)3(s) /

white ppt

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10
Q

What happens when [Fe(H2O)6]2+ reacts with a little NH3? Complex and colour?

A

Fe(H2O)4(OH)2(s) /

green ppt goes brown on standing in air

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11
Q

What happens when [Fe(H2O)6]3+ reacts with a little NH3? Complex and colour?

A

Fe(H2O)3(OH)3(s) /

brown ppt

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12
Q

What happens when [Cu(H2O)6]2+ reacts with a little NH3? Complex and colour?

A

Cu(H2O)4(OH)2(s) /

blue ppt

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13
Q

What happens when [Al(H2O)6]3+ reacts with a little NH3? Complex and colour?

A

Al(H2O)3(OH)3(s) /

white ppt

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14
Q

What happens when [Fe(H2O)6]2+ reacts with CO3^2-? Complex and colour?

A

FeCO3(s) /

green ppt

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15
Q

What happens when [Fe(H2O)6]3+ reacts with CO3^2-? Complex and colour?

A

Fe(H2O)3(OH)3(s)
brown ppt
and CO2 gas evolved

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16
Q

What happens when [Cu(H2O)6]2+ reacts with CO3^2-? Complex and colour?

A

CuCO3(s) /

blue-green ppt

17
Q

What happens when [Al(H2O)6]3+ reacts with CO3^2-? Complex and colour?

A

Al(H2O)3(OH)3(s)
white ppt
and CO2 gas evolved