Reactions and their catalysts Flashcards
Reagents and conditions of halogenation of benzene?
Halogen carrier e.g. AlCl3 catalyst, Cl2, room temp, in the dark
What are the reagents and conditions for the nitration of benzene?
Conc nitric acid, conc sulphuric acid, 50*degrees
Oxidation of alcohols?
K2Cr2O7/H+ acid catalyst
Reduction of aldehydes and ketones
NaBH4 in water
Esterification?
Carboxylate acid+water===>ester+ water H2SO4 catalyst
Ester hydrolysis?
Acid
HCl heated under reflux +water
Ester hydrolysis?
Alkaline A?
NaOH heated under reflux
Preparation of primary aliphatic amine?
Warm halogenoalkanes with excess ammonia using ethanol.
CH3CH2Cl+NH3=====>CH3CH2CH2NH2 +HCl
NH3+HCl=====>NH4+Cl~
Preparing aromatic amines?
Nitrobenzene scan be reduced.
Tin,conc HCl,heated under reflux, followed by neutralisation of excess HCl
Industrial production of dyestuff?
NaNO2 + HCl====>HNO2 +NaCl
Phenyl amine + HNO2 +HCl below 10*degrees