Reactions and their catalysts Flashcards

0
Q

Reagents and conditions of halogenation of benzene?

A

Halogen carrier e.g. AlCl3 catalyst, Cl2, room temp, in the dark

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1
Q

What are the reagents and conditions for the nitration of benzene?

A

Conc nitric acid, conc sulphuric acid, 50*degrees

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2
Q

Oxidation of alcohols?

A

K2Cr2O7/H+ acid catalyst

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3
Q

Reduction of aldehydes and ketones

A

NaBH4 in water

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4
Q

Esterification?

A

Carboxylate acid+water===>ester+ water H2SO4 catalyst

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5
Q

Ester hydrolysis?

Acid

A

HCl heated under reflux +water

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6
Q

Ester hydrolysis?

Alkaline A?

A

NaOH heated under reflux

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7
Q

Preparation of primary aliphatic amine?

A

Warm halogenoalkanes with excess ammonia using ethanol.
CH3CH2Cl+NH3=====>CH3CH2CH2NH2 +HCl
NH3+HCl=====>NH4+Cl~

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8
Q

Preparing aromatic amines?

A

Nitrobenzene scan be reduced.

Tin,conc HCl,heated under reflux, followed by neutralisation of excess HCl

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9
Q

Industrial production of dyestuff?

A

NaNO2 + HCl====>HNO2 +NaCl

Phenyl amine + HNO2 +HCl below 10*degrees

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