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organic chem > Reactions > Flashcards

Reactions Flashcards

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1
Q

Alkene>Alcohol

A

Addition
H20/H+
Hydration

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2
Q

Alkene>Alkane

A

Addition
H2/Pt
Hydrogenation

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3
Q

Alkene>Haloalkane

A

Addition
HCL/HBR/CL2/BR2
Hydrohalegenation (HCl or HBr)

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4
Q

Alkane>Haloalkane

A

Substitution

BR2/CL2

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5
Q

Alcohol>Haloalkane

A

Substitution

PCL3/PCL5/SOCL2

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6
Q

Haloalkane>Amide

A

Substitution

NH3 conc

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7
Q

Haloalkane>Alcohol

A

Substitution

KOH (aq)

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8
Q

Alcohol>Alkene

A

Elimination

H2SO4 conc

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9
Q

Haloalkane>alkene

A

Elimination

KOH (alc)

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10
Q

Primary Alcohol>?

A

Aldehyde>Carboxylic acid
Oxidisation
MnO4-/Cr207 2-

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11
Q

Secondary Alcohol>?

A

Ketone
Oxidisation
MnO4-/Cr207 2-

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12
Q

Alkane>Alcohol

A

Oxidisation

MnO4-/Cr207 2-

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13
Q

Alkene>Diol

A

Oxidisation

MnO4- only

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14
Q

Acyl Chloride>Carboxylic Acid

A 
Hydrolysis reaction
Nucleophilic substitution
H20
Fumes in damp air
Blue litmus paper>red
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15
Q

Acyl Chloride>Ester

A

Condensation reaction
Nucleophilic substitution
Alcohol

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16
Q

Acyl Chloride>Primary amide

A

Nucleophilic substitution

NH3(alc)

17
Q

Acyl Chloride>Secondary amide

A

Nucleophilic substitution

Primary amine

18
Q

Ester>Amide

A

Substitution
NH3
(Slow)

19
Q

Ester>Carboxylic acid

A 
Substitution
Acid hydrolisis
acid/H2O (under acidic conditions)
slow 
requires heat
20
Q

Ester>Carboxylic acid salt

A

Substitution
Base hydrolysis/saponification
Base/H2O (basic conditions)
Requires heat

21
Q

Amide>Carboxylic acid

A

Substitution
Acid hydrolysis
acid/H2O (acidic conditions)
requires heat

22
Q

Amide>carboxylic acid salt

A

Substitution
base hydrolysis
aqueous base/H2O (basic conditions)
heat

23
Q

carboxylic acid>ester

A

substitution
condensation/esterfication
alcohol
strong acid (catalyst)

24
Q

carboxylic acid>acyl chloride

A

substitution

SOCL2,PCL3,PCL5

25
Q

aldehyde>primary alcohol

A

NaBH4

Elimination

26
Q

ketone>secondary alcohol

A

NaBH4

elimination

organic chem (2 decks)

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