Reactions Flashcards
Learn reactions for the synthesis of metal organic derivatives
1
Q
M + R-X -> ?
A
RM + MX or RMX (Direct Synthesis)
2
Q
2 Li + Bu-Br -> ?
A
BuLi + LiBr (Direct Synthesis)
3
Q
Mg + Ph-Br -> ?
A
Ph-Mg-Br (Direct Synthesis)
4
Q
2 Na/Hg + 2 Me-Br -> ?
A
Me2Hg + NaBr (Alloy Procedure / Mixed Metal Synthesis)
5
Q
2 Na/Pb + Et-Cl -> ?
A
Et4Pb + 3 Pb + 4 NaCl (Alloy Procedure / Mixed Metal Synthesis)
6
Q
M + RM’ -> ?
A
M’ + RM (Transmetallation)
7
Q
Zn + Me2Hg -> ?
A
Me2Zn + Hg (Transmetallation)
8
Q
RM + R’M’ -> ?
A
R’M + RM’ (Metal Exchange)
9
Q
4 PhLi + (H2C=CH)4Sn -> ?
A
4 (H2C=CH)Li + Ph4Sn (Metal Exchange)
10
Q
RM + M’X -> ?
A
RM’ + MX (Methathesis)
11
Q
3 MeLi + SbCl3 -> ?
A
Me3Sb + LiCl (Methathesis)
12
Q
RM + R’X -> ?
A
RX + R’M (Metal-Halogen-Exchange)
13
Q
BuLi + Ph-X -> ?
A
Bu-X + PhLi (Metal-Halogen-Exchange)
14
Q
RM + R’H -> ?
A
RH + R’M (Metallation)
15
Q
PhNa + Ph-Me -> ?
A
Ph-H + PhCH2Na (Metallation)
