Reactions

Question 1

M + R-X -> ?

Answer 1

RM + MX or RMX (Direct Synthesis)

Question 2

2 Li + Bu-Br -> ?

Answer 2

BuLi + LiBr (Direct Synthesis)

Question 3

Mg + Ph-Br -> ?

Answer 3

Ph-Mg-Br (Direct Synthesis)

Question 4

2 Na/Hg + 2 Me-Br -> ?

Answer 4

Me2Hg + NaBr (Alloy Procedure / Mixed Metal Synthesis)

Question 5

2 Na/Pb + Et-Cl -> ?

Answer 5

Et4Pb + 3 Pb + 4 NaCl (Alloy Procedure / Mixed Metal Synthesis)

Question 6

M + RM’ -> ?

Answer 6

M’ + RM (Transmetallation)

Question 7

Zn + Me2Hg -> ?

Answer 7

Me2Zn + Hg (Transmetallation)

Question 8

RM + R’M’ -> ?

Answer 8

R’M + RM’ (Metal Exchange)

Question 9

4 PhLi + (H2C=CH)4Sn -> ?

Answer 9

4 (H2C=CH)Li + Ph4Sn (Metal Exchange)

Question 10

RM + M’X -> ?

Answer 10

RM’ + MX (Methathesis)

Question 11

3 MeLi + SbCl3 -> ?

Answer 11

Me3Sb + LiCl (Methathesis)

Question 12

RM + R’X -> ?

Answer 12

RX + R’M (Metal-Halogen-Exchange)

Question 13

BuLi + Ph-X -> ?

Answer 13

Bu-X + PhLi (Metal-Halogen-Exchange)

Question 14

RM + R’H -> ?

Answer 14

RH + R’M (Metallation)

Question 15

PhNa + Ph-Me -> ?

Answer 15

Ph-H + PhCH2Na (Metallation)

Question 16

2 C5H6 + 2 Na -> ?

Answer 16

2 C5H5Na + H2 (Metallation)

Question 17

M-H’ + H2C=CH2 -> ?

Answer 17

MH2C-CH2H’ (Hydrometallation)

Question 18

Et2AlH + H2C=CH2 -> ?

Answer 18

Et3Al (Hydrometallation)

Question 19

R-M + H2C=CH2 -> ?

Answer 19

MH2C-CH2R (Carbometallation)

Question 20

BuLi + Ph-C≡C-Ph -> ?

Answer 20

(Bu)(Ph)C=C(Ph)(H) (Carbometallation)

Question 21

PhSiH3 + CH2N2 -> ?

Answer 21

PhSiH2Me + N2 (Carbene Insertion)