REACTIONS Flashcards

1
Q

R-OH + Y ==== ____

A

R-OH + HCL/HBR/PCL3/PCL5 === R-CL
R-OH + SOCL2 === R-Cl + SO2g + HCLg

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

CH4 + Cl2 + Y ======= ______

A

CH4 + CL2 == CH3CL2 + HCL
CH2CL2 + CL2 ==== CHCL + HCL

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

WHAT IS NAME OF THE FOLLOWING RECATION? AND ALSO GIVE THE NAME OF THE REAGENT Y
R-X + NaI + Y ======
AND WITH R WHAT CAN BE THE X

A

FINKELSTEIN RECATION
R-X + NaI + dry acetone === R-I + NAX

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

WHAT IS NAME OF THE FOLLOWING RECATION?
R-X +HgF2 ======
AND WITH R WHAT CAN BE THE X

A

R-F + HgX2 WE CAN ALSO use AgX x =cl,br

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

CH3 - CH=CH-CH3 + Y ===

A

CH3-CH2-CH-CH3
I
X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

CH3-CH=CH2 +HX===

A

CH3-CH-CH3
I
X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

CH3-CH=CH2 + Y + Z =====

A

Y= HBR Z=PEROXIDE
CH3-CH2-CH2-BR

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

CH3-CH=CH2 + Y + NO UV===

A

Y = X2
CH3-CH-CH2
I I
X X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

CH3-CH=CH2 + Y + UV===

A

CH2-CH==CH + HEAT

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

C6H6 + X + Y() ===

A

X = X2
Y= FECL3(ANHYD.)
C6H6-X +HX

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

GIVE THE PREPARATION OF DIAZONIUM SALT

A

C6H5-NH2 + NANO2, HCL (0-5 C) === R-N2X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

C6H5CH3 + X + UV
C6H5CH3 + X + NO UV

A

X = X2
1. C6H5-CH2X
2. C6H5-CH3
I
X SYMM + UNSYMM

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

R-N2X + CU2X2 ====
GIVE THE NAME IF THE REACTION

A

C6H5-X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

R-N2X + CU/HX ====
GIVE THE NAME OF THE REACTION

A

C6H5-X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

R-N2X + HBF4/-HX ====
GIVE THE NAME OF THE REACTION

A

C6H5-X

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

R-N2X + KI/ -HX ====
GIVE THE NAME OF THE REACTION

A

C6H5-X

17
Q

CHEMICAL PROPERTIES OF HALOALKANES
1. ELIMNATION RECATION :
CH3-CH2-Cl + x() ====
2. Satzeff Rule:
CH3-CH2-CH - CH3 + X() =====
I
X
3. Recation with metals
=> With Na: (GIVE NAME OF
THE REACTION)
2R-X + 2Na + Y===
=> With Mg :(What is it called?)
R-X + Mg =====
4. Substituion Reaction:
R-X + Y() ==
5. Nucleophilic Reaction:
CH3
I
CH3-C-X +Y ====
I
CH3

A
  1. CH2=CH2 + KOH AL
  2. KOH AL - CH3-CH=CH-CH3
    -CH3-CH2-CH=CH2
    3.DRY ETHER 1ST = R-R +2NaX
    2ns ==R-Mg + X : Grignard’s reagent
  3. R-OH +KX Y== KOH (AQ)
    5.
    CH3
    I
    CH3-C-OH+KX Y =KOH AQ====
    I
    CH3
18
Q

Nucleophilic Substitution recations of Haloarenes:
1. C6H5-CL + Y(A) +TEMP + PRESSURE ==
2.GIVE MASKING DEMASKING RECATION

A
  1. NAOH ALC, 623K, 300ATM
    C6H5OH
  2. C6H(NO)3OH
19
Q

ELectrophillic substitution Reaction of Haloarenes
1. Halogenation :
C6H5-X + CL2 + Y ====
2. NITRATION
C6H5-CL + Y+Z ===
3. SULPHONATION
4

A

SYMMETRIC AND UNSYMMETRIC C6H4CLX
ATTACH NO2

20
Q

FRIEDAL CRAFTS RECATION HALOARENES
1. ALKYLATION
C6H5-X + Y + Z
2. ACETYLATION
C6H5-X + Y + Z

A

TAKE A LOOK AT NOTEBOOK

21
Q

2C6H5-X + 2Na + Y ===
Give the name of the reaction

A

y = dry acetone , C6H5-C6H5 + 2 NaX

22
Q

R-X + 2 NA + C6H5-X + Y==
GIVE THE NAME OF THE RECATION

A

Y = DRY ETHER, C6H5-R + 2 NAX

23
Q
A