Reactions Flashcards

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1
Q

Haloalkane to Alkene

A
  • Elimination
  • KOH or NaOH
  • Heat under reflux
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2
Q

Haloalkane to alcohol

A
  • Nucleophilic Substitution
  • KOH or NaOH
  • Aqueous
  • Heat under reflux
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3
Q

Alcohol to Alkene

A
  • Elimination (dehydration)
  • Concentrated H2SO4 or H3PO4 catalyst
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4
Q

Alkene to alcohol

A
  • Electrophilic Addition
  • Aqueous (steam)
  • H2SO4 or H3PO4 catalyst
  • Warm
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5
Q

Aldehyde to Alcohol

A
  • Nucleophilic Addition
  • NaBH4
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6
Q

Alcohol to aldehyde

A
  • Oxidation
  • Potassium dichromate
  • Heat and distill
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7
Q

Alcohol to Ketone

A
  • Oxidation
  • Potassium dichromate
  • Heat under reflux
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8
Q

Alcohol to Carboxylic Acid

A
  • Oxidation
  • Heat under reflux
  • Excess [O] Agent
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9
Q

Carboxylic Acid to Ester

A
  • Esterification
  • Alcohol
  • Aqueous (H2O)
  • Heat
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10
Q

Alkene to Alkane

A
  • Electrophilic Addition
  • Pt / Ni Catalsyt
  • H2
  • Heat
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11
Q

Alkene to Haloalkane

A
  • Electrophilic Addition
  • HX
  • Room temp
  • Major and minor products to be considered
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12
Q

Alkane to haloalkane

A
  • Free Radical Substitution
  • UV Light
  • Halogen
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13
Q

Haloalkane to Nitrile

A
  • Nucleophilic Substitution
  • KCN
  • Ethanol
  • Aqueous
  • Heat under reflux
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14
Q

Haloalkane to Amine

A
  • Nucleophilic Substitution
  • Heat under reflux
  • Ethanol
  • NH3
  • Pressure
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15
Q

Alcohol to Ester

A
  • Nucleophilic Substitution
  • NaBH4
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16
Q

Halogenation of Arenes

A
  • Cl2 / Br2
  • AlCl3 / AlBr3 catalyst
  • Forms aryl halide
17
Q

Nitration of arenes

A
  • HNO3 + H2SO4 (concentrated) generates NO2+ electrophile
  • Heat (25-60 degrees)
  • Nitroarene
18
Q

Friedel Crafts alkylation / acylation

A
  • Haloalkane / Acyl Chloride
  • Anhydrous AlCl3 catalyst
  • Acyl / alkyl benzene
19
Q

Oxidation of arenes

A
  • Hot
  • Alkaline KMnO4
  • Dilute acid
  • Benzoic acid
20
Q
A