Reactions Flashcards
1
Q
A
E1 elimination
2
Q
A
E2 elimination
3
Q
A
Substitution
4
Q
A
Addition
5
Q
A
Dehydrohalogenation of akyl halides
6
Q
A
cyclopropanation
7
Q
A
elimination
8
Q
A
epoxidation
9
Q
A
Halogenation
10
Q
A
Halohydrin formation
11
Q
A
HX addition
12
Q
A
Hydration
13
Q
A
Hydrogenation
14
Q
A
Hydroxylation
15
Q
A
oxidative cleavage
16
Q
A
Polymerization of alkenes
17
Q
A
polymerization of isobutylene
18
Q
Alkadienes bond type
A
cumulated
19
Q
Alkadienes bond type
A
conjugated
20
Q
Alkadienes bond type
A
isolated
21
Q
Alkadienes group
A
Allyl group
22
Q
Alkadienes group
A
Vinyl group
23
Q
A
Primary alcohol
24
Q
A
Secondary alcohol
25
Tertiary alcohol
26
Phenol
27
Which category do these belong to? (alcohols and phenols)
Phenols
28
Which category do these belong to? (alcohols and phenols)
Primary alcohols
29
Which category do these belong to? (alcohols and phenols)
Secondary alcohols
30
Which category do these belong to? (alcohols and phenols)
Tertiary alcohols
31
CH3 OH
CH3 CH2 OH
CH2 OH CH2 OH
Methanol
Ethanol
Ethylene glycol
32
Alcohol forming alkoxide ion
33
Phenol forming alkoxide ion
34
dehydration of alcohol
35
Reduction of an alkene (hydrogenation)
36
Reduction of a ketone/aldehyde to an alcohol
37
Oxidation of an aldehyde to a carboxylic acid
38
Reduction of a carboxylic acid to an alcohol
39
oxidation of alcohol to a ketone
40
thiol oxidized to disulfide
41
R- and Ar- for?
R- alkyl group
Ar- aryl group (aromatic ring)
42
Ketone, ends in -CO
43
Aldehyde, ends in -CHO
44
base-catalyzed keto-enol tautomerism
45
acid-catalyzed keto-enol tautomerism
46
Aldol reaction
47
Addition of nucleophile to carbonyl groups
48
Formation of acetals, in the case of the ketone -> common name = ketal
49
HCO2H
CH3 CH2 H
CH3 CH2 CO2 H
CH3 (CH2)2 CO2 H
Carboxylic acids
Common: - IUPAC:
Formic acid - methanoic acid
Acetic acid - ethanoic acid
propionic acid - propanoic acid
butyric acid - butanoic acid
50
HOOC - COOH
HOOC - CH2 - COOH
HOOC - CH2 - CH2 - COOH
HOOC - CH2 - CH2 - CH2 - COOH
HOOC - CH = CH - COOH (cis)
HOOC - CH = CH - COOH (trans)
dicarboxylic acids
oxalic
malonic
succinic
glutaric
maleic
fumaric
51
Acyl groups
Formyl
acetyl
propionyl
52
Nucleophilic acyl substitution
53
esterification
54
Hydroxyl-carboxylic acids
1. Lactic acid
2. tartaric acid
3. citric acid
55
b-lactam ring
56
what are all these?
Lactones
